Elements in Tap Water. Part 3. Effect of Sample Volume and Stagnation Time on the Concentration of the Element.

Abstract not availableJRC.H-Institute for environment and sustainability (Ispra

Integrated Water Resources Management in Cities in the World: Global Challenges

Water scarcity and accessibility remain persistently amongst the most prominent global challenges. Although there is a wide agreement among international organizations that Integrated Water Resources Management (IWRM) and water governance are key to overcome water-related challenges, global assessments of the progress made by cities is lacking. This paper for the first time analyses the challenges of water, wastewater, municipal solid waste and climate change in cities. We used empirical studies (125 cities) based on the City Blueprint Approach and developed a statistical estimation model to estimate IWRM performances of another 75 cities. These 200 cities in total represent more than 95% of the global urban population. This comprehensive global picture enables us to evaluate the existing gaps in achieving water-related Sustainable Development Goals (SDGs), in particular SDG 6 (clean water and sanitation) and SDG 11 (sustainable cities and communities). The best performing cities were Amsterdam and Singapore. Unfortunately, most cities do not yet manage their water resources wisely and are far from achieving the SDGs. For instance, targets regarding drinking water supply are still a challenge for many cities in Africa and Asia and challenges regarding sanitation are high in cities in Africa, Asia and Latin America. The same holds for solid waste management, climate adaptation, and people living in informal settlements. In another paper we will address the solution pathways to these global challenges

Published at Univ. of Calif

AbstrAct: New regulatory restrictions have been placed on the use of some second-generation anticoagulant rodenticides in the United States, and in some situations this action may be offset by expanded use of first-generation compounds. We have recently conducted several studies with captive adult American kestrels and eastern screech-owls examining the toxicity of diphacinone (DPN) using both acute oral and short-term dietary exposure regimens. Diphacinone evoked overt signs of intoxication and lethality in these raptors at exposure doses that were 20 to 30 times lower than reported for traditionally used wildlife test species (mallard and northern bobwhite). Sublethal exposure of kestrels and owls resulted in prolonged clotting time, reduced hematocrit, and/or gross and histological evidence of hemorrhage at daily doses as low as 0.16 mg DPN/kg body weight. Findings also demonstrated that DPN was far more potent in short-term 7-day dietary studies than in single-day acute oral exposure studies. Incorporating these kestrel and owl data into deterministic and probabilistic risk assessments indicated that the risks associated with DPN exposure for raptors are far greater than predicted in analyses using data from mallards and bobwhite. These findings can assist natural resource managers in weighing the costs and benefits of anticoagulant rodenticide use in pest control and eradication programs

Pathways of Carbon Assimilation and Ammonia Oxidation Suggested by Environmental Genomic Analyses of Marine Crenarchaeota

Marine Crenarchaeota represent an abundant component of oceanic microbiota with potential to significantly influence biogeochemical cycling in marine ecosystems. Prior studies using specific archaeal lipid biomarkers and isotopic analyses indicated that planktonic Crenarchaeota have the capacity for autotrophic growth, and more recent cultivation studies support an ammonia-based chemolithoautotrophic energy metabolism. We report here analysis of fosmid sequences derived from the uncultivated marine crenarchaeote, Cenarchaeum symbiosum, focused on the reconstruction of carbon and energy metabolism. Genes predicted to encode multiple components of a modified 3-hydroxypropionate cycle of autotrophic carbon assimilation were identified, consistent with utilization of carbon dioxide as a carbon source. Additionally, genes predicted to encode a near complete oxidative tricarboxylic acid cycle were also identified, consistent with the consumption of organic carbon and in the production of intermediates for amino acid and cofactor biosynthesis. Therefore, C. symbiosum has the potential to function either as a strict autotroph, or as a mixotroph utilizing both carbon dioxide and organic material as carbon sources. From the standpoint of energy metabolism, genes predicted to encode ammonia monooxygenase subunits, ammonia permease, urease, and urea transporters were identified, consistent with the use of reduced nitrogen compounds as energy sources fueling autotrophic metabolism. Homologues of these genes, recovered from ocean waters worldwide, demonstrate the conservation and ubiquity of crenarchaeal pathways for carbon assimilation and ammonia oxidation. These findings further substantiate the likely global metabolic importance of Crenarchaeota with respect to key steps in the biogeochemical transformation of carbon and nitrogen in marine ecosystems

Development of a computer-generated equilibrium model for the variation of iron and manganese in the hypolimnion of Lake Mendota

A computer-generated chemical equilibrium model has been developed to predict the unusual seasonal variation of iron and manganese in the hypolimnetic water above the sediments in Lake Mendota. Models for the detailed chemical speciation of Mn and Fe have been developed as functions of pH, redox level, adsorption, and organic complexation. Results indicate that pH is the primary variable controlling the preferential release of Mn due to simultaneous pH dependent dissolution of solid MnCO_3 and desorption of Mn(II) from oxide surfaces. Progressive appearance of Fe is predicted in terms of a pH-dependent dissolution of iron oxides as influenced by organic complexation. Using the maximum observed concentrations of major chemical components as input data, we have reproduced experimentally determined variations of Mn and Fe as a function of pH over the range 8.7-6.9