Mass transfer characteristics in structured packing for CO2 emission reduction processes

Acid gas treating and CO2 capture from flue gas by absorption have gained wide importance over the past few decades. With the implementation of more stringent environmental regulations and the awareness of the greenhouse effect, the need for efficient removal of acid gases such as CO2 (carbon dioxide) has increased significantly. Therefore, additional effort for research in this field is inevitable. For flue gas processes the ratio of absorption solvent to gas throughput is very different compared to acid gas treating processes owing to the atmospheric pressures and the dilution effect of combustion air. Moreover, in flue gas applications pressure drop is a very important process parameter. Packing types are required that allow for low pressure drop in combination with high interfacial areas at low liquid loading per square meter. The determination of interfacial areas in gas-liquid contactors by means of the chemical method (Danckwerts, P. V. Gas-liquid reactions; McGraw-Hill: London, 1970) has been very frequently applied. Unfortunately, many of the model systems proposed in the literature are reversible and therefore this condition possibly is not met. Versteeg et al. (Versteeg, G. F.; Kuipers, J. A. M.; Beckum, F. P. H.; van Swaaij, W. P. M. Chem. Eng. Sci. 1989, 44, 2292) have demonstrated that for reversible reactions the conditions for the determination of the interfacial area by means of the chemical method are much more severe. In a study by Raynal et al. (Raynal, L.; Ballaguet, J. P.; Berrere-Tricca, C. Chem. Eng. Sci. 2004, 59, 5395), it has been shown that there is a dependency of the interfacial area on the packing height. Unfortunately, most model systems used, e.g., CO2-caustic soda (as used by Raynal et al.), are much more complex and consist of (a set of) reversible reaction(s). The natures of these systems make the conditions at which the interfacial area can be determined much more severe and put more limitations on the process conditions and experimental equipment than a priori can be expected. Therefore, an extended absorption model is required to determine the conditions at which the interfacial area can be measured without detailed knowledge of the values of the liquid-side mass transfer coefficient, k1, beforehand.

A Variational Approach to the Spinless Relativistic Coulomb Problem

By application of a straightforward variational procedure we derive a simple, analytic upper bound on the ground-state energy eigenvalue of a semirelativistic Hamiltonian for (one or two) spinless particles which experience some Coulomb-type interaction.Comment: 7 pages, HEPHY-PUB 606/9

Regularization of a three-body problem with zero-range potentials

We propose a coordinate-space regularization of the three-body problem with zero-range potentials. We include the effective range and the shape parameter in the boundary condition of the zero-range potential. The proposed extended zero-range model is tested against atomic helium trimers and is shown to provide an adequate quantitative description of these systems

Study of internal structures of 9,10Be and 10B in scattering of 4He from 9Be

A study of inelastic scattering and single-particle transfer reactions was performed by an alpha beam at 63 MeV on a 9$Be target. Angular distributions of the differential cross sections for the 9Be(4He,4He')9Be*, 9Be(4He,3He)10Be and 9Be(4He,t)10B reactions were measured. Experimental angular distributions of the differential cross sections for the ground state and a few low-lying states were analyzed in the framework of the optical model, coupled channels and distorted-wave Born approximation. An analysis of the obtained spectroscopic factors was performed.Comment: 16 pages, 7 figures, 3 tables, regular paper, mispritns are corrected in new versio

Strong Equivalence Relations for Iterated Models

The Iterated Immediate Snapshot model (IIS), due to its elegant geometrical representation, has become standard for applying topological reasoning to distributed computing. Its modular structure makes it easier to analyze than the more realistic (non-iterated) read-write Atomic-Snapshot memory model (AS). It is known that AS and IIS are equivalent with respect to \emph{wait-free task} computability: a distributed task is solvable in AS if and only if it solvable in IIS. We observe, however, that this equivalence is not sufficient in order to explore solvability of tasks in \emph{sub-models} of AS (i.e. proper subsets of its runs) or computability of \emph{long-lived} objects, and a stronger equivalence relation is needed. In this paper, we consider \emph{adversarial} sub-models of AS and IIS specified by the sets of processes that can be \emph{correct} in a model run. We show that AS and IIS are equivalent in a strong way: a (possibly long-lived) object is implementable in AS under a given adversary if and only if it is implementable in IIS under the same adversary. %This holds whether the object is one-shot or long-lived. Therefore, the computability of any object in shared memory under an adversarial AS scheduler can be equivalently investigated in IIS

Spatial distributions in static heavy-light mesons: a comparison of quark models with lattice QCD

Lattice measurements of spatial distributions of the light quark bilinear densities in static mesons allow to test directly and in detail the wave functions of quark models. These distributions are gauge invariant quantities directly related to the spatial distribution of wave functions. We make a detailed comparison of the recent lattice QCD results with our own quark models, formulated previously for quite different purposes. We find a striking agreement not only between our two quark models, but also with the lattice QCD data for the ground state in an important range of distances up to about 4/GeV. Moreover the agreement extends to the L=1 states [j^P=(1/2)^+]. An explanation of several particular features completely at odds with the non-relativistic approximation is provided. A rather direct, somewhat unexpected and of course approximate relation between wave functions of certain quark models and QCD has been established.Comment: 40 pages, 5 figures (version published in PRD

Distributed Slicing in Dynamic Systems

Peer to peer (P2P) systems are moving from application specific architectures to a generic service oriented design philosophy. This raises interesting problems in connection with providing useful P2P middleware services capable of dealing with resource assignment and management in a large-scale, heterogeneous and unreliable environment. The slicing service, has been proposed to allow for an automatic partitioning of P2P networks into groups (slices) that represent a controllable amount of some resource and that are also relatively homogeneous with respect to that resource. In this paper we propose two gossip-based algorithms to solve the distributed slicing problem. The first algorithm speeds up an existing algorithm sorting a set of uniform random numbers. The second algorithm statistically approximates the rank of nodes in the ordering. The scalability, efficiency and resilience to dynamics of both algorithms rely on their gossip-based models. These algorithms are proved viable theoretically and experimentally

Genetic and environmental drivers of colour and pattern in the Australian jacky dragon (Amphibolurus muricatus)

The underlying drivers of variation in the colouration (colour and pattern) of animals can be genetic, non-genetic, or more likely, a combination of both. Understanding the role of heritable genetic elements, as well as non-genetic factors such as age, habitat or temperature, in shaping colouration can provide insight into the evolution and function of these traits, as well as the speed of response to changing environments. This project examined the genetic and non-genetic drivers of continuous variation in colouration in a lizard, the jacky dragon (Amphibolurus muricatus). We leveraged a large captive experiment that manipulated parental and offspring thermal environment to simultaneously estimate the genetic and non-genetic drivers of variation in colouration. We found that the overall brightness, the elongation of the longitudinal stripes on the dorsum and the contrast between light and dark patches of the pattern were all heritable. Colouration varied according to the age of the hatchling; however, the thermal environment of neither the parents nor offspring contributed significantly to colouration. It appears that developmental plasticity and maternal effects associated with temperature are not important drivers of variation in our measures of colouration

The WAY theorem and the quantum resource theory of asymmetry

The WAY theorem establishes an important constraint that conservation laws impose on quantum mechanical measurements. We formulate the WAY theorem in the broader context of resource theories, where one is constrained to a subset of quantum mechanical operations described by a symmetry group. Establishing connections with the theory of quantum state discrimination we obtain optimal unitaries describing the measurement of arbitrary observables, explain how prior information can permit perfect measurements that circumvent the WAY constraint, and provide a framework that establishes a natural ordering on measurement apparatuses through a decomposition into asymmetry and charge subsystems.Comment: 11 pages, 3 figure