Studies in the Organic Chemistry of Sulphur Compounds

The original problem was the investigation of the exchange reaction (vide (3)). This thesis falls into three parts: (1) On Bisarylsulphonyl propanes. (2) The Micro-estimation of Sulphur and Halogen in Organic Compounds. (3) A Quantitative Investigation of the Exchange Reaction. The sulphonyl propanes were investigated because more of them appeared toexist than could be accounted for on the usual theories of isomerism. It was thought that the anomaly might be explained on the basis of the mobility of the sulphonyl group. It is shown below that this is not the case. Their isomerism is to be traced to quite a different cause, (vide (1)). Returning to the original problem of radical exchange it was evident that no quantitative idea of the exchange could be deduced from separating the products of the reaction as they were too similar in properties to be separated without serious loss. Accordingly it was decided to investigate the competition of two radicals containing such characteristic groups as could readily be estimated in the mixed final product. Thus if, in the above equation, 4-chlorophenyl sulphonyl acetone, reacts with methyl p.toluenethiol sulphonate the product will he either p.tolyl sulphonylmethyl-thioacetone or 4-chlorophenyl-sulphonylmethyl thioacetone or more prohahly a mixture of the two. A reaction of the above type goes practically to completion so far as the substitution of the methylthio grouping is concerned and so it is evident that an estimation of the halogen content will indicate the percentage composition of the mixed product. Accordingly the development and detailed testing of a rapid and accurate micro method for the estimation of chlorine and sulphur had to be undertaken (vide (2)).The application of this analytical procedure to the exchange reaction between 4-chlorophenylsulphonylacetone and methyl p.toluene thiolsulphonate has been worked out in detail (vide (3))

The Sensitive Artificial Listner: an induction technique for generating emotionally coloured conversation

The aim of the paper is to document and share an induction technique (The Sensitive Artificial Listener) that generates data that can be both tractable and reasonably naturalistic. The technique focuses on conversation between a human and an agent that either is or appears to be a machine. It is designed to capture a broad spectrum of emotional states, expressed in ‘emotionally coloured discourse’ of the type likely to be displayed in everyday conversation. The technique is based on the observation that it is possible for two people to have a conversation in which one pays little or no attention to the meaning of what the other says, and chooses responses on the basis of superficial cues. In SAL, system responses take the form of a repertoire of stock phrases keyed to the emotional colouring of what the user says. The technique has been used to collect data of sufficient quantity and quality to train machine recognition systems

"Korea" by John McGahern

This essay considers “Korea” as a work of narrative poetry. Both the story’s imagery and its many repetitions work to create an elegiac tone that conveys the intertwining themes of death. The death of the narrator’s youth and the death of rural Ireland become inextricably linked through the patterns of the working day, the story of the execution, and the memory of Luke Moran’s funeral. McGahern’s subtle manipulation of point of view and the physical locations of his protagonists creates shifts in the structural tension of the story, and lend extra force to its thematic concern

"Korea" by John McGahern

This essay considers “Korea” as a work of narrative poetry. Both the story’s imagery and its many repetitions work to create an elegiac tone that conveys the intertwining themes of death. The death of the narrator’s youth and the death of rural Ireland become inextricably linked through the patterns of the working day, the story of the execution, and the memory of Luke Moran’s funeral. McGahern’s subtle manipulation of point of view and the physical locations of his protagonists creates shifts in the structural tension of the story, and lend extra force to its thematic concern

AVEC 2011 – the first international Audio/Visual Emotion Challenge

Abstract. The Audio/Visual Emotion Challenge andWorkshop (AVEC 2011) is the first competition event aimed at comparison of multimedia processing and machine learning methods for automatic audio, visual and audiovisual emotion analysis, with all participants competing under strictly the same conditions. This paper first describes the challenge par-ticipation conditions. Next follows the data used – the SEMAINE corpus – and its partitioning into train, development, and test partitions for the challenge with labelling in four dimensions, namely activity, expectation, power, and valence. Further, audio and video baseline features are intro-duced as well as baseline results that use these features for the three sub-challenges of audio, video, and audiovisual emotion recognition

The structure of HI in galactic disks: Simulations vs observations

We generate synthetic HI Galactic plane surveys from spiral galaxy simulations which include stellar feedback processes. Compared to a model without feedback we find an increased scale height of HI emission (in better agreement with observations) and more realistic spatial structure (including supernova blown bubbles). The synthetic data show HI self-absorption with a morphology similar to that seen in observations. The density and temperature of the material responsible for HI self-absorption is consistent with observationally determined values, and is found to be only weakly dependent on absorption strength and star formation efficiency.Comment: 12 pages, 7 figures. Accepted for publication in MNRA

A comprehensive study of GRB 070125, a most energetic gamma ray burst

We present a comprehensive multiwavelength analysis of the bright, long duration gamma-ray burst GRB 070125, comprised of observations in $\gamma$-ray, X-ray, optical, millimeter and centimeter wavebands. Simultaneous fits to the optical and X-ray light curves favor a break on day 3.78, which we interpret as the jet break from a collimated outflow. Independent fits to optical and X-ray bands give similar results in the optical bands but shift the jet break to around day 10 in the X-ray light curve. We show that for the physical parameters derived for GRB 070125, inverse Compton scattering effects are important throughout the afterglow evolution. While inverse Compton scattering does not affect radio and optical bands, it may be a promising candidate to delay the jet break in the X-ray band. Radio light curves show rapid flux variations, which are interpreted as due to interstellar scintillation, and are used to derive an upper limit of $2.4 \times 10^{17}$ cm on the radius of the fireball in the lateral expansion phase of the jet. Radio light curves and spectra suggest a high synchrotron self absorption frequency indicative of the afterglow shock wave moving in a dense medium. Our broadband modeling favors a constant density profile for the circumburst medium over a wind-like profile ($R^{-2}$). However, keeping in mind the uncertainty of the parameters, it is difficult to unambiguously distinguish between the two density profiles. Our broadband fits suggest that \event is a burst with high radiative efficiency ($> 60$).Comment: 50 pages, 33 figures, sty file included, Appeared in 20 Aug 2008 edition of Astrophysical Journa

A search for molecules in damped Lyman-alpha absorbers occulting millimetre-loud quasars

We have used the SEST 15-metre and Onsala 20-metre telescopes to perform deep (r.m.s. >~ 30 mJy) integrations of various molecular rotational transitions towards damped Lyman-alpha absorption systems (DLAs) known to occult millimetre-loud quasars. We have observed 6 new systems and improved the existing limits for 11 transitions. These limits may be approaching the sensitivities required to detect new systems and we present a small number of candidate systems which we believe warrant further observation.Comment: 7 pages, 1 PS figure, 4 tables. Accepted by A&

Development and preliminary psychometric properties of the Care Experience Feedback Improvement Tool (CEFIT)

Objective To develop a structurally valid and reliable, yet brief measure of patient experience of hospital quality of care, the Care Experience Feedback Improvement Tool (CEFIT). Also, to examine aspects of utility of CEFIT. Background Measuring quality improvement at the clinical interface has become a necessary component of healthcare measurement and improvement plans, but the effectiveness of measuring such complexity is dependent on the purpose and utility of the instrument used. Methods CEFIT was designed from a theoretical model, derived from the literature and a content validity index (CVI) procedure. A telephone population surveyed 802 eligible participants (healthcare experience within the previous 12 months) to complete CEFIT. Internal consistency reliability was tested using Cronbach's α. Principal component analysis was conducted to examine the factor structure and determine structural validity. Quality criteria were applied to judge aspects of utility. Results CVI found a statistically significant proportion of agreement between patient and practitioner experts for CEFIT construction. 802 eligible participants answered the CEFIT questions. Cronbach's α coefficient for internal consistency indicated high reliability (0.78). Interitem (question) total correlations (0.28–0.73) were used to establish the final instrument. Principal component analysis identified one factor accounting for 57.3% variance. Quality critique rated CEFIT as fair for content validity, excellent for structural validity, good for cost, poor for acceptability and good for educational impact. Conclusions CEFIT offers a brief yet structurally sound measure of patient experience of quality of care. The briefness of the 5-item instrument arguably offers high utility in practice. Further studies are needed to explore the utility of CEFIT to provide a robust basis for feedback to local clinical teams and drive quality improvement in the provision of care experience for patients. Further development of aspects of utility is also required

Molecular Gas in the z=1.2 Ultraluminous Merger GOODS J123634.53+621241.3

We report the detection of CO(2-1) emission from the z=1.2 ultraluminous infrared galaxy (ULIRG) GOODS J123634.53+621241.3 (also known as the sub-millimeter galaxy GN26). These observations represent the first discovery of high-redshift CO emission using the new Combined Array for Research in Millimeter-Wave Astronomy (CARMA). Of all high-redshift (z>1) galaxies within the GOODS-North field, this source has the largest far-infrared (FIR) flux observed in the Spitzer 70um and 160um bands. The CO redshift confirms the optical identification of the source, and the bright CO(2-1) line suggests the presence of a large molecular gas reservoir of about 7x10^10 M(sun). The infrared-to-CO luminosity ratio of L(IR)/L'(CO) = 80+/-30 L(sun) (K Km/s pc^2)^-1 is slightly smaller than the average ratio found in local ULIRGs and high-redshift sub-millimeter galaxies. The short star-formation time scale of about 70 Myr is consistent with a starburst associated with the merger event and is much shorter than the time scales for spiral galaxies and estimates made for high-redshift galaxies selected on the basis of their B-z and z-K colors.Comment: Accepted for publication in ApJ Letter