Cement stratigraphy: image probes of cathodoluminescent facies

Cement stratigraphy of carbonates aims to establish the chronology of processes involved in the rock diagenesis. Regional cement stratigraphy allows correlations and understanding of the petrological heterogeneities in reservoirs and aquifers, but is a long and rigorous approach. This article exposes a methodology of image analysis that facilitates the spatial correlation of diagenetic events in carbonate rocks. Based on the statistical comparison of signals extracted from the red spectrum emission of cathodoluminescence digital images, it gives via crosscorrelation a measure of similarity (values scaled from minimum −1 to maximum 1) between two cathodoluminescence facies. Cementation events and diagenetic chronologies can thus be quickly correlated without the support of a full chronology, the model normally established on cement morphologies, petrological analyses and cathodoluminescence zonation sequences. A case study from two Upper Kimmeridgian Mount Salève outcrops (France) illustrates this methodology. Their diagenetic sequences recorded in cathodoluminescent cements are presented and being compared. The final statistical similarity between the two outcrops reaches an index of R=0.78. This result is sustained by petrological and geochemical analyses such as alizarine-ferricyanure stained thin sections, X microfluorescence mapping of elements, and microthermometry of fluid inclusion

Hydrodynamic behaviour of Nummulites: implications for depositional models

Large benthic foraminifers are considered to be good indicators of shallow marine carbonate environments in fossil series. Over the last 50 years, the palaeoenvironment of Tertiary Nummulites accumulations has been a matter of debate, particularly because of difficulties in interpreting these deposits, and in this way, the absence of analogues in present-day seas does not help. The aim of this paper is to insight the different ways Nummulites tests and clasts may accumulate according to their hydrodynamic behaviour. Based on experimental measurements and on SEM observations, it appears that the high primary skeletal porosity of Nummulites made them easily transportable. The calculated threshold shear velocities confirm that large-sized Nummulites can be moved by weak wave-driven currents. This peculiar hydrodynamic behaviour of Nummulites could explain the diversity of depositional models. Depending on local hydrodynamic conditions, autochthonous Nummulites deposits can be preserved as in situ winnowed bioaccumulations or be accumulated offshore, onshore or alongshore, away from the original biotop

TEM study of Mg distribution in micrite crystals from the Mishrif reservoir Formation (Middle East, Cenomanian to Early Turonian)

Microporous limestones composed of micrite crystals constitute sizeable hydrocarbon reservoirs throughout the world and especially in the Middle East. However, the crystallization history of micrites is poorly understood. Scanning electronic microscopy (SEM) with X-ray energy dispersive spectroscopy (EDS) studies give morphological and bulk composition information about micrites, but no information exists on the distribution of minor elements inside micrite grains. This study proposes Mg maps obtained with X-ray EDS combined with scanning transmission electron microscopy (STEM) of micrite crystals from the Mishrif reservoir Formation (Middle East, Cenomanian to Early Turonian). Three types of Mg distribution were observed through micrite crystals from five different samples: (1) homogenous Mg concentration, (2) small Mg-enriched areas close to the center of the crystal, and (3) geometric Mg impoverishments near crystal edges and parallel to present crystallographic faces. The homogenous Mg distribution is the most frequent and is found both in microporous and in tight micrites. The second type of distribution showing small Mg-enriched areas inside micrite crystals relatively close to their center comes from a microporous sample located below an emersive surface. These enriched areas may correspond to crystal seeds. The third type of distribution was observed in micrite crystals from another microporous sample situated just below an emersive surface. The Mg-poor zones probably represent overgrowths that precipitated in contact with less Mg-rich meteoric fluid

Lacustrine microporous micrites of the Madrid Basin (Late Miocene, Spain) as analogues for shallow-marine carbonates of the Mishrif reservoir Formation (Cenomanian to Early Turonian, Middle East)

Shallow-marine microporous limestones account for many carbonate reservoirs. Their formation, however, remains poorly understood. Due to the lack of recent appropriate marine analogues, this study uses a lacustrine counterpart to examine the diagenetic processes controlling the development of intercrystalline microporosity. Late Miocene lacustrine microporous micrites of the Madrid Basin (Spain) have a similar matrix microfabric as Cenomanian to Early Turonian shallow-marine carbonates of the Mishrif reservoir Formation (Middle East). The primary mineralogy of the precursor mud partly explains this resemblance: low-Mg calcites were the main carbonate precipitates in the Cretaceous seawater and in Late Miocene freshwater lakes of the Madrid Basin. Based on hardness and petrophysical properties, two main facies were identified in the lacustrine limestones: a tight facies and a microporous facies. The tight facies evidences strong compaction, whereas the microporous facies does not. The petrotexture, the sedimentological content, and the mineralogical and chemical compositions are identical in both facies. The only difference lies in the presence of calcite overgrowths: they are pervasive in microporous limestones, but almost absent in tight carbonates. Early diagenetic transformations of the sediment inside a fluctuating meteoric phreatic lens are the best explanation for calcite overgrowths precipitation. Inside the lens, the dissolution of the smallest crystals in favor of overgrowths on the largest ones rigidifies the sediment and prevents compaction, while partly preserving the primary microporous network. Two factors appear essential in the genesis of microporous micrites: a precursor mud mostly composed of low-Mg calcite crystals and an early diagenesis rigidifying the microcrystalline framework prior to buria

Facies characteristics and diversity in carbonate eolianites

Carbonate eolian dunes can form huge sand bodies along the coasts but are seldom described in the pre-Quaternary record. The study of more than 600 thin-sections collected in present-day, Holocene and Pleistocene dunes from Sardinia, Crete, Cyprus, Tunisia, Morocco, Australia and Baja California confirms that these deposits can be easily misinterpreted as shallow marine at core or thin-section scale. The classical eolian criteria (fine-grained and well-sorted sands) are exceptional in carbonate dunes because the diversity of shapes and densities of carbonate particles lowers the critical shear velocity of the sediment thus blurring the sedimentary structures. Wind carbonate deposits are mainly heterogeneous in size and often coarse-grained. The paucity of eolianites in the pre-Quaternary record could be due to misinterpretation of these deposits. The recognition should be based on converging sedimentological and stratigraphic elements at core scale, and diagenetic (vadose diagenesis, pedogenetic imprints) and petrographical (grain verticalization, scarcity of micritic envelopes, broken and/or reworked foraminifera) clues in thin-section. Bioclastic or oolitic grainstones showing evidence of vadose diagenesis or pedogenetic imprints, should always be suspected of having an eolian origi

Lecture publique à l’échelle de l’intercommunalité : cas du Grand Roanne Agglomération (La)

Perspectives intercommunales de la lecture publique au grand Roanne agglomération

Holocene sea level fluctuations and coastal evolution in the central Algarve (southern Portugal)

In Armação de Pêra Bay, southern Portugal, environmental changes during the Holocene can be interpreted based on the morphological and sedimentological similarities between older geomorphic features (cemented beach and dune rocks) and present coastal features. Using knowledge of the present beach and dune processes, we propose a two-step model for the evolution of Armação de Pêra Bay. First, during the rapid sea level rise between about 8800 and 6600 yr cal BP, the bay changed from a positive to a negative budget littoral cell and transgressive dunes formed, favoured by drought conditions. At about 5000 yr cal BP, during a sea level maximum, beach width was less than the critical fetch and dunes stabilized and underwent cementation during the wetter Atlantic climatic event. The second phase of dune accumulation started at about 3200 yr cal BP, due to a regression of sea level during which the bay changed back to a positive budget littoral cell in which beach width was greater than the critical fetch. Currently, the beach width is less than the critical fetch, dunes are inactive, and the sedimentary budget is negative due to sediment storage in local river systems.Fundação para a Ciência e a Tecnologia. FEDER, and OE (Project POCTI/CTA/34162/2000

Sedimentological analysis of marine Pleistocene deposits of southeastern Tunisia: evidence of two positive eustatic pulsations during the marine isotopic substage 5e (Eemian, Tyrrhenian)

International audienceAbstract Detailed sedimentological and petrographic analysis of marine Pleistocene deposits along the coastal area of southeastern Tunisia allow to identify two distinct lithostratigraphic units separated by an erosion surface (fig. 2 et 5 A and B). These two commonly superposed units form a ridge parallel to the coast. The palaeocoastal morphology was more irregular than the present-day coastline with areas either more protected or more exposed than now (fig. 3). The lower unit overlies an erosion surface cutting into Mio-Pliocene and Villafranchian deposits. It consists of fine-grained bioclastic quartz-rich sands (fig. 5 C), locally overlain by thin marl layers containing benthic foraminifera and ostracods. The very fine facies (silts and clays) represent relatively protected areas while the coarser facies developed in the more exposed zones. These deposits locally display a well-developed aeolian facies that terminates the sedimentary sequence. This unit, well developed in Jerba Island and Jorf peninsula, strongly resembles the stratigraphic unit of “Khnis” as defined by Mahmoudi [1988] on the coast of Central Tunisia. The upper unit is the better developed in the studied area. It consists of carbonate deposits composed mainly by ooids and peloids (fig. 5 D) and contains also a warm Senegalese fauna, especially Strombus. Locally, in the exposed areas, it shows a coarse facies which resulted mainly from the erosion of the calcareous Villafranchian deposits. This unit displays a remarkable shallowing-upward sequence from shoreface to aeolian dunes (fig. 5 E and F). It constitutes the lateral equivalent of the stratigraphic unit of “Réjiche” as defined by Mahmoudi [1988] in Central Tunisia. These two units, called in this study “quartz-rich unit” (the lower sequence) and “carbonate unit” (the upper one), developed during two distinctive sedimentation phases associated with two sea-level highstands separated by a marine regression. During the first highstand sea-level was about 3 m higher than today whereas it was at about +5 m during the second highstand [Jedoui, 2000]. Along the Mediterranean coasts the Strombus paleobeaches, which are contemporary with the carbonate unit, are well developed and traditionally called Tyrrhenian deposits. Their radiochemical dating, using corals, gives ages of about 125 ka [Hearty et al., 1986 ; Miller et al., 1986 ; Dumas et al., 1991 ; Vai et Pasini, 1996]. We obtained the most reliable uranium/thorium dates in southeastern Tunisia on oyster shells. Results show that the two units developed during the marine isotopic substage 5e [last interglacial ; Jedoui, 2000]. This evidence suggests that substage 5e was characterised by at least two eustatic maxima separated by a lowering of sea level during a marine regression. Our results are therefore in agreement with recent palaeoclimatic reconstructions and in particular with sea level reconstructions and marine oxygen isotope records that indicate the distinct possibility of two positive eustatic pulsations during the last interglacial [Hillaire-Marcel et al., 1996 ; Kindler et al., 1997 ; Plaziat et al., 1998]. Variations in the petrographic content of the two outlined units reflect drastic palaeoclimatic fluctuations in southeastern Tunisia during the last interglacial. The establishment of wetter climatic conditions at the beginning of marine isotopic substage 5e than today was responsible for an enhanced terrigenous materiel supply from the continent as showed by siliciclastic sedimentation along the coast (lower unit). Our data are in agreement with the strong sea surface salinity lowering observed in Mediterranean basins at the beginning of the last interglacial period [Kallel et al., 2000]. The regression of these conditions during the second half of the last interglacial favoured a carbonate sedimentation (upper unit) in southeastern Tunisia