278 research outputs found
Sensitivity of resistive and Hall measurements to local inhomogeneities:Finite-field, intensity, and area corrections
Novel lithium Schiff-base cluster complexes as electron injectors: synthesis, crystal structure, thin film characterisation and their performance in OLEDs
This journal is © The Royal Society of Chemistry 2012A set of novel lithium Schiff base cluster compounds has been synthesised and characterised for the first time and tested as electron injectors in OLED devices. Their electrical, electronic, thermal and optical properties have been investigated and compared with the industry standards LiF and lithium quinolinolate (LiQ). Amongst the compounds tested, lithium 2-((o tolylimino)methyl) phenolate was found to enhance the efficiency of OLEDs by 69% compared to LiF and 15% compared to LiQ. The same electron injector was found to extend the lifetimes of OLEDs by six-fold compared to LiF and 4.3- fold compared to LiQ respectively. The crystal structure of the parent compound, lithium 2- ((phenylamino)methyl)phenolate reveals that the compound is tetrameric in contrast to hexameric LiQ. Substituting the methyl group with fluorine causes a remarkable depression of the HOMO and LUMO levels by up to 1.2 eV. Analysis of current density vs. voltage characteristics of single-layer devices for Li–Al/electron injector/Li–Al and Al/electron injector/Al reveals that both sets of devices are operating as electron-only devices indicating that the formation of free lithium is the cause of enhanced electron injection, but either the energetic aluminium atoms (as proposed previously by other workers) or energetic lithium complexes on an aluminium surface (as we have demonstrated in this paper) are all that is required for efficient electron injection
Insulator-to-metal transition in sulfur-doped silicon
We observe an insulator-to-metal (I-M) transition in crystalline silicon
doped with sulfur to non- equilibrium concentrations using ion implantation
followed by pulsed laser melting and rapid resolidification. This I-M
transition is due to a dopant known to produce only deep levels at equilibrium
concentrations. Temperature-dependent conductivity and Hall effect measurements
for temperatures T > 1.7 K both indicate that a transition from insulating to
metallic conduction occurs at a sulfur concentration between 1.8 and 4.3 x
10^20 cm-3. Conduction in insulating samples is consistent with variable range
hopping with a Coulomb gap. The capacity for deep states to effect metallic
conduction by delocalization is the only known route to bulk intermediate band
photovoltaics in silicon.Comment: Submission formatting; 4 journal pages equivalen
Projet Termitofuel: les termites et leurs symbiontes pour mieux valoriser la biomasse ligno-cellulosique
L’exploitation actuelle de la biomasse ligno-cellulosique, extrêmement abondante sur Terre, est liée à la production de déchets relativement peu valorisables. C’est pourquoi le projet TERMITOFUEL étudie la digestion du bois chez les termites, grâce à une approche pluridisciplinaire, en vue d’améliorer la production de bioéthanol de seconde génération. Au sein de l’Unité d’Entomologie Fonctionnelle et Evolutive, l’approche protéomique est employée afin d’identifier les micro-organismes présents dans le tube digestif des termites et caractériser les activités enzymatiques
Invasive Mutualists Erode Native Pollination Webs
Plant–animal mutualisms are characterized by weak or asymmetric mutual dependences between interacting species, a feature that could increase community stability. If invasive species integrate into mutualistic webs, they may alter web structure, with consequences for species persistence. However, the effect of alien mutualists on the architecture of plant–pollinator webs remains largely unexplored. We analyzed the extent of mutual dependency between interacting species, as a measure of mutualism strength, and the connectivity of 10 paired plant–pollinator webs, eight from forests of the southern Andes and two from oceanic islands, with different incidences of alien species. Highly invaded webs exhibited weaker mutualism than less-invaded webs. This potential increase in network stability was the result of a disproportionate increase in the importance and participation of alien species in the most asymmetric interactions. The integration of alien mutualists did not alter overall network connectivity, but links were transferred from generalist native species to super-generalist alien species during invasion. Therefore, connectivity among native species declined in highly invaded webs. These modifications in the structure of pollination webs, due to dominance of alien mutualists, can leave many native species subject to novel ecological and evolutionary dynamics
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