Thermal Diffusivity and Conductivity Measurements in Diamond Anvil Cells

We have undertaken a study of the feasibility of an innovative method for the determination of thermal properties of materials at extreme conditions. Our approach is essentiality an extension of the flash method to the geometry of the diamond-anvil cell and our ultimate goal is to greatly enlarge the pressure and temperature range over which thermal properties can be investigated. More specifically, we have performed test experiments to establish a technique for probing thermal diffusivity on samples of dimensions compatible with the physical constraints of the diamond anvil cell

An Integrated Method for Accurate Determination of Melting in High-Pressure Laser Heating Experiments

We present an integrated approach for melting determination by monitoring several criteria simultaneously. In particular we combine x-ray diffraction observations with the detection of discontinuities in the optical properties by spectroradiometric measurements. This approach significantly increases the confidence of melt identification, especially with low-Z samples. We demonstrate the method with observations of melt in oxygen at 47 and 55 gigapascals

Lattice dynamics of MgSiO3_3 perovskite (bridgmanite) studied by inelastic x-ray scattering and ab initio calculations

We have determined the lattice dynamics of MgSiO$_3$ perovskite (bridgmanite) by a combination of single-crystal inelastic x-ray scattering and ab initio calculations. We observe a remarkable agreement between experiment and theory, and provide accurate results for phonon dispersion relations, phonon density of states and the full elasticity tensor. The present work constitutes an important milestone to extend this kind of combined studies to extreme conditions of pressure and temperature, directly relevant for the physics and the chemistry of Earth's lower mantle

Experimental investigation of the stability of Fe-rich carbonates in the lower mantle

International audienceThe fate of carbonates in the Earth's mantle plays a key role in the geodynamical carbon cycle. Although iron is a major component of the Earth's lower mantle, the stability of Fe-bearing carbonates has rarely been studied. Here we present experimental results on the stability of Fe-rich carbonates at pressures ranging from 40 to 105 GPa and temperatures of 1450-3600 K, corresponding to depths within the Earth's lower mantle of about 1000-2400 km. Samples of iron oxides and iron-magnesium oxides were loaded into CO2 gas and laser heated in a diamond-anvil cell. The nature of crystalline run products was determined in situ by X-ray diffraction, and the recovered samples were studied by analytical transmission electron microscopy and scanning transmission X-ray microscopy. We show that Fe-(II) is systematically involved in redox reactions with CO2 yielding to Fe-(III)-bearing phases and diamonds. We also report a new Fe-(III)-bearing high-pressure phase resulting from the transformation of FeCO3 at pressures exceeding 40 GPa. The presence of both diamonds and an oxidized C-bearing phase suggests that oxidized and reduced forms of carbon might coexist in the deep mantle. Finally, the observed reactions potentially provide a new mechanism for diamond formation at great depth

Composition of the Earth's Inner Core from High-pressure Sound Velocity Measurements in Fe-Ni-Si alloys

International audienceWe performed room-temperature sound velocity and density measurements on a polycrystalline alloy, Fe0.89Ni0.04Si0.07, in the hexagonal close-packed (hcp) phase up to 108 GPa. Over the investigated pressure range the aggregate compressional sound velocity is ∼9% higher than in pure iron at the same density. The measured aggregate compressional (VP) and shear (VS) sound velocities, extrapolated to core densities and corrected for anharmonic temperature effects, are compared with seismic profiles. Our results provide constraints on the silicon abundance in the core, suggesting a model that simultaneously matches the primary seismic observables, density, P-wave and S-wave velocities, for an inner core containing 4 to 5 wt.% of Ni and 1 to 2 wt.% of Si

Fe–FeO and Fe–Fe₃C melting relations at Earth's core–mantle boundary conditions: Implications for a volatile-rich or oxygen-rich core

International audienceEutectic melting temperatures in the Fe–FeO and Fe–Fe3C systems have been determined up to 150 GPa. Melting criteria include observation of a diffuse scattering signal by in situ X-Ray diffraction, and textural characterisation of recovered samples. In addition, compositions of eutectic liquids have been established by combining in situ Rietveld analyses with ex situ chemical analyses. Gathering these new results together with previous reports on Fe–S and Fe–Si systems allow us to discuss the specific effect of each light element (Si, S, O, C) on the melting properties of the outer core. Crystallization temperatures of Si-rich core compositional models are too high to be compatible with the absence of extensive mantle melting at the core–mantle boundary (CMB) and significant amounts of volatile elements such as S and/or C (>5 at%, corresponding to >2 wt%), or a large amount of O (>15 at% corresponding to ∼5 wt%) are required to reduce the crystallisation temperature of the core material below that of a peridotitic lower mantle

Structure and density of Fe-C liquid alloys under high pressure

International audienceThe density and structure of liquid Fe-C alloys have been measured up to 58 GPa and 3,200 K by in situ X-ray diffraction using a Paris-Edinburgh press and laser-heated diamond anvil cell. Study of the pressure evolution of the local structure inferred by X-ray diffraction measurements is important to understand the compression mechanism of the liquid. Obtained data show that the degree of compression is greater for the first coordination sphere than the second and third coordination spheres. The extrapolation of the measured density suggests that carbon cannot be the only light element alloyed to iron in the Earth's core, as 8-16 at % C (1.8-3.7 wt % C) would be necessary to explain the density deficit of the outer core relative to pure Fe. This concentration is too high to account for outer core velocity. The presence of other light elements (e.g., O, Si, S, and H) is thus required

Seismic detection of the martian core

Clues to a planet's geologic history are contained in its interior structure, particularly its core. We detected reflections of seismic waves from the core-mantle boundary of Mars using InSight seismic data and inverted these together with geodetic data to constrain the radius of the liquid metal core to 1830 +/- 40 kilometers. The large core implies a martian mantle mineralogically similar to the terrestrial upper mantle and transition zone but differing from Earth by not having a bridgmanite-dominated lower mantle. We inferred a mean core density of 5.7 to 6.3 grams per cubic centimeter, which requires a substantial complement of light elements dissolved in the iron-nickel core. The seismic core shadow as seen from InSight's location covers half the surface of Mars, including the majority of potentially active regions-e.g., Tharsis-possibly limiting the number of detectable marsquakes.This is InSight contribution 200. We acknowledge NASA, CNES, and partner agencies and institutions (UKSA, SSO, ESA-PRODEX, DLR, JPL, IPGP-CNRS, ETHZ, IC, and MPS-MPG) for the development of SEIS. Numerical simulations were supported by a grant from the Swiss National Supercomputing Centre (CSCS) under project ID s922 as well as HPC resources of CINES under the allocation A0090407341, made by GENCI. We thank B. Dintrans, director of CINES, for his efficient handling of our request for computational time. Figures were created using matplotlib (83), seismic data processing was done in ObsPy (84), and numerical evaluation was done in NumPy and SciPy (85, 86). Funding: S.C.S., A.K., D.G., J.C., A.C.D., G.Z., and N.D. acknowledge support from ETHZ through the ETH+ funding scheme (ETH+2 19-1: “Planet MARS”). S.C.S. acknowledges funding from ETH research grant ETH-10 17-3. W.B.B., A.G.M., M.P.P., and S.E.S. were supported by the NASA InSight mission and funds from the Jet Propulsion Laboratory, California Institute of Technology, under a contract with the National Aeronautics and Space Administration (80NM0018D0004). D.A. has received funding from the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation program (grant agreement 724690). The French teams acknowledge support from CNES as well as Agence Nationale de la Recherche (ANR-14-CE36-0012-02 and ANR-19-CE31-0008-08). A.R. was financially supported by the Belgian PRODEX program managed by the European Space Agency in collaboration with the Belgian Federal Science Policy Office. M.S. wishes to thank SANIMS (RTI2018-095594-B-I00). M.v.D. received support from the ERC under the European Union’s Horizon 2020 program (grant no. 714069). D.S. and C.S. acknowledge funding from ETH research grant ETH-06 17-02. J.C.E.I. acknowledges support from NASA grant 80NSSC18K1633. N.S., D.K., Q.H., R.M., V.L., and A.G.M. acknowledge NASA grant 80NSSC18K1628 for support. V.L. acknowledges support from the Packard Foundation. W.T.P. and C.C. received funding from the UK Space Agency, grant ST/S001239/1. A.H. was funded by the UK Space Agency (grant ST/R002096/1). A.-C.P. acknowledges the financial support and endorsement from the DLR Management Board Young Research Group Leader Program and the Executive Board Member for Space Research and Technology. Author contributions: S.C.S., D.G., S.C., R.F.G., Q.H., D.K., V.L., M.S., N.S., D.S., É.S., C.S., and G.Z. analyzed the seismic data and made ScS arrival time picks. S.C.S., P.L., D.G., Z.X., C.C., and W.T.P. performed the statistical analysis of the observed signals. S.C.S., Q.H., N.S., R.M., and A.G.M. identified the arrivals as ScS waves based on interior models from A.K., H.S., and A.R. A.K., M.D., A.C.D., and H.S. performed the inversions. S.C.S., A.K., P.L., D.G., D.A., J.C.E.I., M.K., C.P., A.-C.P., A.R., T.G., and S.E.S. participated and contributed to the interpretation of the results. Review of the continuous data and detection of marsquakes was done by S.C.S., S.C., G.Z., C.C., N.D., J.C., M.v.D., T.K., M.P., and A.H. with operational support by É.B., C.P., and P.M.D. S.C.S. and A.K. wrote the central part of the paper with contributions from H.S., N.S., D.A., J.C.E.I., A.G.M., A.-C.P., A.R., J.C., and M.v.D. J.C.E.I., R.M., M.K., and V.L. reviewed the contributions to the supplementary materials. The InSight mission is managed by W.B.B., M.P.P., and S.E.S. The SEIS instrument development was led by P.L., D.G., W.T.P., and W.B.B. Supplementary section 1 was written by M.S., D.S., and É.S. with contributions from S.C.S., C.S., and Z.X. Supplementary section 2 was written by D.K. and V.L. with contributions from J.C.E.I. and N.S. Supplementary section 3 was written by M.S. and É.S. Supplementary section 4 was written by R.F.G. with contributions from M.D. Supplementary section 5 was written by Q.H. with contributions from N.S. Supplementary section 6 was written by S.C.S. with contributions from the authors of the other supplements. Supplementary section 7 was written by Z.X. and C.C. with contributions from P.L. and W.T.P. Supplementary section 8 was written by A.K., M.D., A.C.D., and H.S. Supplementary section 9 was written by M.D. Supplementary section 10 was written by A.C.D., A.K., and M.D. Supplementary section 11 was written by D.A. and A.R. with contributions from A.K. Competing interests: The authors declare that they have no competing interests. Data and materials availability: We thank the operators of JPL, SISMOC, MSDS, IRIS-DMC, and PDS for providing SEED SEIS data (87). Three hundred interior models derived in this study are available from MSDS (88)