Complex organic molecules in strongly UV-irradiated gas

We investigate the presence of COMs in strongly UV-irradiated interstellar molecular gas. We have carried out a complete millimetre line survey using the IRAM30m telescope towards the edge of the Orion Bar photodissociation region (PDR), close to the H2 dissociation front, a position irradiated by a very intense far-UV (FUV) radiation field. These observations have been complemented with 8.5 arcsec resolution maps of the H2CO 5(1,5)-4(1,4) and C18O 3-2 emission at 0.9 mm. Despite being a harsh environment, we detect more than 250 lines from COMs and related precursors: H2CO, CH3OH, HCO, H2CCO, CH3CHO, H2CS, HCOOH, CH3CN, CH2NH, HNCO, H13-2CO, and HC3N (in decreasing order of abundance). For each species, the large number of detected lines allowed us to accurately constrain their rotational temperatures (Trot) and column densities (N). Owing to subthermal excitation and intricate spectroscopy of some COMs (symmetric- and asymmetric-top molecules such as CH3CN and H2CO, respectively), a correct determination of N and Trot requires building rotational population diagrams of their rotational ladders separately. We also provide accurate upper limit abundances for chemically related molecules that might have been expected, but are not conclusively detected at the edge of the PDR (HDCO, CH3O, CH3NC, CH3CCH, CH3OCH3, HCOOCH3, CH3CH2OH, CH3CH2CN, and CH2CHCN). A non-LTE LVG excitation analysis for molecules with known collisional rate coefficients, suggests that some COMs arise from different PDR layers but we cannot resolve them spatially. In particular, H2CO and CH3CN survive in the extended gas directly exposed to the strong FUV flux (Tk = 150-250 K and Td > 60 K), whereas CH3OH only arises from denser and cooler gas clumps in the more shielded PDR interior (Tk = 40-50 K). We find a HCO/H2CO/CH3OH = 1/5/3 abundance ratio. These ratios are different from those inferred in hot cores and shocks.Comment: 29 pages, 22 figures, 17 tables. Accepted for publication in A&A (abstract abridged

Direct estimation of electron density in the Orion Bar PDR from mm-wave carbon recombination lines

A significant fraction of the molecular gas in star-forming regions is irradiated by stellar UV photons. In these environments, the electron density (n_e) plays a critical role in the gas dynamics, chemistry, and collisional excitation of certain molecules. We determine n_e in the prototypical strongly irradiated photodissociation region (PDR), the Orion Bar, from the detection of new millimeter-wave carbon recombination lines (mmCRLs) and existing far-IR [13CII] hyperfine line observations. We detect 12 mmCRLs (including alpha, beta, and gamma transitions) observed with the IRAM 30m telescope, at ~25'' angular resolution, toward the H/H2 dissociation front (DF) of the Bar. We also present a mmCRL emission cut across the PDR. These lines trace the C+/C/CO gas transition layer. As the much lower frequency carbon radio recombination lines, mmCRLs arise from neutral PDR gas and not from ionized gas in the adjacent HII region. This is readily seen from their narrow line profiles (dv=2.6+/-0.4 km/s) and line peak LSR velocities (v_LSR=+10.7+/-0.2 km/s). Optically thin [13CII] hyperfine lines and molecular lines - emitted close to the DF by trace species such as reactive ions CO+ and HOC+ - show the same line profiles. We use non-LTE excitation models of [13CII] and mmCRLs and derive n_e = 60-100 cm^-3 and T_e = 500-600 K toward the DF. The inferred electron densities are high, up to an order of magnitude higher than previously thought. They provide a lower limit to the gas thermal pressure at the PDR edge without using molecular tracers. We obtain P_th > (2-4)x10^8 cm^-3 K assuming that the electron abundance is equal or lower than the gas-phase elemental abundance of carbon. Such elevated thermal pressures leave little room for magnetic pressure support and agree with a scenario in which the PDR photoevaporates.Comment: Accepted for publication in A&A Letters (includes language editor corrections

Reusable model transformation components with bentō

The final publication is available at Springer via http://dx.doi.org/10.1007/978-3-319-21155-8_5Building high-quality transformations that can be used in real projects is complex and time-consuming. For this reason, the ability to reuse existing transformations in different, unforeseen scenarios is very valuable. However, there is scarce tool support for this task. This paper presents bentō, a tool which supports the development and execution of reusable transformation components. In bentō, a reusable transformation is written as a regular ATL transformation, but it uses concepts as meta-models. Reuse is achieved by binding such concepts to meta-models, which induces the transformation adaptation. Moreover, composite components enable chaining transformations, and it is possible to convert an existing transformation into a reusable component. Bentō is implemented as an Eclipse plug-in, available as free software.This work was supported by the Spanish Ministry of Economy and Competitivity with project Go-Lite (TIN2011-24139), the R&D programme of the Madrid Region with project (SICOMORO S2013/ICE-3006), and the EU commission with project MONDO (FP7-ICT 2013-10, #611125)

The impact of non–local birds on yellow–legged gulls (Larus michahellis) in the Bay of Biscay: a dump–based assessment

El impacto de los individuos no locales en la gaviota patiamarilla (Larus michahellis) en el Golfo de Vizcaya: una estimación a partir de vertederos Es necesario comprender la forma en que los animales explotan los recursos tróficos de origen no natural, como es el caso de los vertederos, desde múltiples perspectivas como la conservación, la dinámica de poblaciones y la gestión. Son varias las especies de gaviotas depredadoras de gran tamaño (Larus sp.) las que indudablemente se benefician de utilizar los vertederos. La gaviota patiamarilla (L. michahellis) es la especie de gaviota más abundante del Paleártico sudoccidental y el rápido crecimiento de sus poblaciones hasta al menos la primera década del siglo XXI se debe, parcialmente, al aumento de vertederos. El Golfo de Vizcaya es una zona que alberga gaviotas locales residentes y gaviotas invernantes procedentes de otras zonas. A partir de los datos obtenidos en censos y avistamientos de gaviotas marcadas con anillas de color que se recopilaron durante un periodo de ocho años en cuatro vertederos situados en un radio de 60 km desde las colonias de cría en Gipuzkoa, se trató de responder a las siguientes cuestiones: (1) el origen de las gaviotas que usan los vertederos en el Golfo de Vizcaya; (2) el impacto de los individuos locales y no locales en estos vertederos; (3) la posibilidad de que exista un uso distinto según la edad y (4) la posibilidad de que haya fluctuaciones estacionales en el uso de los vertederos. Las gaviotas en los vertederos estudiados provienen de las colonias costeras cercanas de Gipuzkoa, la zona atlántica de la península Ibérica, la región mediterránea y otras zonas como la costa atlántica de Francia y las colonias continentales (Navarra y Alemania). Parece que los vertederos de nuestro estudio fueron utilizados, principalmente, por aves locales.Understanding how animals exploit non–natural feeding sources such as garbage dumps is necessary from many perspectives, including conservation, and population dynamics and management. Several large predatory gulls (Larus spp.) are among the species which most clearly benefit from using dumps. The yellow–legged gull (L. michahellis) is the most abundant gull in the southwestern Palaearctic, and its fast population increase until at least the 2000s was partly due large waste dumps becoming more numerous. The Bay of Biscay is an area that hosts resident local and also wintering non–local yellow–legged gulls. Using data collected over a period of eight years (bird counts, identification of colour–ringed individuals) at four dumps situated within a 60–km radius from the colonies of Gipuzkoa (southwestern Bay of Biscay), we aimed to answer: (1) the origin of gulls using dumps at the Bay of Biscay; (2) the impact of local and non–local gulls at these dumps; (3) the possible age–dependent use of these sites; and (4) the possible seasonal fluctuations in the use of dumps by gulls. Gulls in our area (study dumps) came from nearby colonies in Gipuzkoa, Atlantic Iberia, the Mediterranean region, and other areas such as Atlantic France and inland colonies (Navarra, Germany). Our study dumps seemed to be used mostly by local gulls.El impacto de los individuos no locales en la gaviota patiamarilla (Larus michahellis) en el Golfo de Vizcaya: una estimación a partir de vertederos Es necesario comprender la forma en que los animales explotan los recursos tróficos de origen no natural, como es el caso de los vertederos, desde múltiples perspectivas como la conservación, la dinámica de poblaciones y la gestión. Son varias las especies de gaviotas depredadoras de gran tamaño (Larus sp.) las que indudablemente se benefician de utilizar los vertederos. La gaviota patiamarilla (L. michahellis) es la especie de gaviota más abundante del Paleártico sudoccidental y el rápido crecimiento de sus poblaciones hasta al menos la primera década del siglo XXI se debe, parcialmente, al aumento de vertederos. El Golfo de Vizcaya es una zona que alberga gaviotas locales residentes y gaviotas invernantes procedentes de otras zonas. A partir de los datos obtenidos en censos y avistamientos de gaviotas marcadas con anillas de color que se recopilaron durante un periodo de ocho años en cuatro vertederos situados en un radio de 60 km desde las colonias de cría en Gipuzkoa, se trató de responder a las siguientes cuestiones: (1) el origen de las gaviotas que usan los vertederos en el Golfo de Vizcaya; (2) el impacto de los individuos locales y no locales en estos vertederos; (3) la posibilidad de que exista un uso distinto según la edad y (4) la posibilidad de que haya fluctuaciones estacionales en el uso de los vertederos. Las gaviotas en los vertederos estudiados provienen de las colonias costeras cercanas de Gipuzkoa, la zona atlántica de la península Ibérica, la región mediterránea y otras zonas como la costa atlántica de Francia y las colonias continentales (Navarra y Alemania). Parece que los vertederos de nuestro estudio fueron utilizados, principalmente, por aves locales

UV Plasmonic Metamaterial from Vertical Non-Conventional Nanoantennas

Boston, Massachusetts, November 29-December 4, 2015Metallic nanoantennas have been used as nanophotonic detectors of infrared and visible radiation [1] [2]. The extension of these elements to the ultraviolet (UV) range has not been satisfactory due to the poor optical absorption showed by metals at these frequencies. The low values of electrical conductivity of metals at UV frequencies compromise the generation of currents along the resonant geometries. In change, several non-conventional materials show a larger value of electrical conductivity, increasing notably the absorption of nanoantennas in the UV [3]. This electrical conductivity increment is more noticeable in liquid semimetals as Bismuth or Gallium. Another way to improve optical absorption of these resonant elements is to arrange them with a high spatial density of semimetal nanoantennas. In this contribution we evaluate numerically, using multiphysics simulation, the light to heat conversion performance of a vertical nanoantenna arrangement embedded in a dielectric matrix. The so-obtained UV metamaterial enabling strong electromagnetic plasmonic absorption and heating effects. The use of nanoantennas allows a polarization and frequency selectivity that can be adequate to generate ultraviolet sensors. These selectivities are strongly related with the shape of the resonant elements. Furthermore, since the vertical antennas are embedded within a robust dielectric matrix, this arrangement allows to change from solid to liquid phase maintaining the nanoantenna geometry. This is possible for materials as Bismuth or Gallium which show a lower melting temperature than dielectric substrates [4]. This phase transition makes the metamaterial active upon control of temperature. [1] L. Novotny and N. van Hulst, ¿Antennas for light,¿ Nat. Photon. 5 (2), 83-90, (2011). [2] A. Cuadrado, E. Briones, F.J. González, J. Alda, ¿Polarimetric Pixel using Seebeck Nanoantenna¿. Opt Exp, 22, No 11, 13835-13845, (2014). [3] J.Toudert, R.Serna, and M. Jiménez de Castro, ¿Exploring the optical potencial of nano-Bismuth: Tunable surface Plasmon resonances in the near Ultraviolet-to-Near Infrared range¿, J. Phys. Chem. C, 116 (38), pp 20530-20539, (2012). [4] M. Jiménez de Castro, F. Cabello, J. Toudert, R. Serna and E.Haro-Poniatowski, ¿Potential of bismuth nanoparticles embedded in a glass matrix for spectral-selective thermo-optical devices¿ Appl. Phys. Lett. 105, 113102 (2014).Peer Reviewe

Kalman filters based on multibody models: linking simulation and real world. A comprehensive review

[Abstract] The Kalman filter algorithm estimates variables of linear systems combining information from real sensors and a mathematical model of the system. It may be applied to observe nonlinear systems by means of a linearization of the system model. Multibody system dynamics constitutes a methodology for the analysis and design of mechanical systems. During the last twenty years, many ways of employing a multibody model as the Kalman filter model have been explored. This paper gathers up diverse algorithms, from the first ones based on the continuous expressions of the filter, to the indirect methods that enable real-time implementations of the observation of mechanical systems with a large number of variables. A detailed explanation of the methods and a description of the strengths and weaknesses of each one is presented along this paper, including a benchmark evaluating the performance of the methods. An important aspect of the Kalman filter is the characterization of the system uncertainty by means of white Gaussian noise. Sometimes, the statistical properties of the noise are unknown. Several methods to determine these properties are described, and a new methodology to model systems perturbed by colored noise (time-correlated noise) is presented. In Kalman filters based on multibody models, the information from a real mechanical system can be employed to keep the model behaving like the actual system with a great level of accuracy, linking the simulation to the real behavior of the system

Regresión de un caso de linfosarcoma canino tras un tratamiento inmunoquimioterápico

Presentamos un caso clínico de un linfosarcoma multicéntrico en un perro y su evolución con un tratamiento inmunoquimioterápico, apreciándose una regresión del proceso tumoral al final del mismo.We have reported a case report about a multicentríc lymphosarcoma in a dog and its evolution with an immunochemotherapeutic protocol. We noticed a total regresion of the tumor at the end of the treatment

The chemistry and spatial distribution of small hydrocarbons in UV-irradiated molecular clouds: the Orion Bar PDR

We study the spatial distribution and chemistry of small hydrocarbons in the Orion Bar PDR. We used the IRAM-30m telescope to carry out a millimetre line survey towards the Orion Bar edge, complemented with ~2'x2' maps of the C2H and c-C3H2 emission. We analyse the excitation of the detected hydrocarbons and constrain the physical conditions of the emitting regions with non-LTE radiative transfer models. We compare the inferred column densities with updated gas-phase photochemical models including 13CCH and C13CH isotopomer fractionation. ~40% of the lines in the survey arise from hydrocarbons (C2H, C4H, c-C3H2, c-C3H, C13CH, 13CCH, l-C3H and l-H2C3). We detect new lines from l-C3H+ and improve its rotational spectroscopic constants. Anions or deuterated hydrocarbons are not detected: [C2D]/[C2H]<0.2%, [C2H-]/[C2H]<0.007% and [C4H-]/[C4H]<0.05%. Our gas-phase models can reasonably match the observed column densities of most hydrocarbons (within factors <3). Since the observed spatial distribution of the C2H and c-C3H2 emission is similar but does not follow the PAH emission, we conclude that, in high UV-flux PDRs, photodestruction of PAHs is not a necessary requirement to explain the observed abundances of the smallest hydrocarbons. Instead, gas-phase endothermic reactions (or with barriers) between C+, radicals and H2 enhance the formation of simple hydrocarbons. Observations and models suggest that the [C2H]/[c-C3H2] ratio (~32 at the PDR edge) decreases with the UV field attenuation. The observed low cyclic-to-linear C3H column density ratio (<3) is consistent with a high electron abundance (Xe) PDR environment. In fact, the poorly constrained Xe gradient influences much of the hydrocarbon chemistry in the more UV-shielded gas. We propose that reactions of C2H isotopologues with 13C+ and H atoms can explain the observed [C13CH]/[13CCH]=1.4(0.1) fractionation level.Comment: 30 pages, 23 figures, 15 tables. Accepted for publication in A&A (English edited, abstract abridged