95 research outputs found

    Ferroelectric Photovoltaic Effect

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    Tetragonal BiFeO3 films with the thickness of 30 nm were grown epitaxially on (001) oriented LaAlO3 substrate by using pulsed laser deposition (PLD). The transverse photovoltaic effects were studied as a function of the sample directions in-plane as well as the angle between the linearly polarized light and the plane of the sample along X and Y directions. The absorption onset and the direct band gap are ~2.25 and ~2.52 eV, respectively. The photocurrent depends not only on the sample directions in-plane but also on the angle between the linearly polarized light and the plane of the sample along X and Y directions. The results indicate that the bulk photovoltaic effect together with the depolarization field was ascribed to this phenomenon. Detailed analysis presents that the polarization direction is along [110] direction and this depolarization field induced photocurrent is equal to ~3.53 μA/cm2. The BPV induced photocurrent can be approximate described as Jx ≈ 2.23cos(2θ), such an angular dependence of photocurrent is produced as a consequence of asymmetric microscopic processes of carriers such as excitation and recombination

    Influence of Co ion doping on the microstructure, magnetic and dielectric properties of Ni1-xCoxFe2O4 ceramics

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    Ni1-xCoxFe2O4 (x = 0, 0.2, 0.4, 0.6, 0.8) ceramics were prepared by chemical co-precipitation method and the effect of Co ion doping on the microstructure, magnetic and dielectric properties has been investigated. The results show that the synthesized ceramics display only spinel phase of Ni1-xCoxFe2O4, without other apparent impurities found. The lattice of Ni1-xCoxFe2O4 crystal structure was distorted as a result of the incorporation of Co ion, and the lattice parameters increase with the increase of Co ion content. The grain size decreases slightly with increasing the content of Co ion, indicating a change of particle size and morphology at higher doping content. The results of impedance analysis shows that the sample doped with 80 at.% Co possesses the maximal dielectric constant, while the pure NiFe2O4 sample shows the minimal value when the frequency is below 0.1 MHz. The M-H loops of these ceramics exhibit highly magnetic nature and the saturation magnetization. The remnant magnetization increases linearly with the increase of Co-concentration in nickel ferrite while the coercive field (Hc) shows non-monotonic variation with Co content. The minimal and maximal values of Hc can be obtained when the Co concentrations are 40 and 80 at.%, respectively. The highest value of the saturation magnetization is 63 emu/g obtained with 80 at.% Co doping while the lowest value is ∼31 emu/g for the pure NiFe2O4 ceramics. The abnormal magnetic behaviour is due to the A-B super exchange interaction when magnetic Co2+ ions are added

    Dielectric, ferroelectric and magnetic properties of Bi0.78La0.08Sm0.14Fe0.85Ti0.15O3 ceramics prepared at different sintering conditions

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    Although BiFeO3 (BFO) has attracted great attention due to its special physical properties as a typical single phase multiferroic material, the application is limited due to the formation of impurities, defects and so forth. Herein, we report improved multiferroic properties of Bi0.78La0.08Sm0.14Fe0.85Ti0.15O3 (BLSFTO) ceramics by combination of co-doping and sintering schedule. BLSFTO multiferroic ceramics were prepared by using the conventional solid state reaction method and the effect of sintering time (2, 5, 10, 20 and 30 h) on the structural, dielectric and multiferroic properties was investigated systematically. The result indicates that stable BLSFTO phase with perovskite structure was formed for all the samples. Only some impurities such as Bi2O4 can be observed when the sintering time is longer than 20 h, indicating that the sintering time can induce structural changes in BLSFTO and too long sintering time can remarkably increase the secondary phases. In addition, the frequency dependent dielectric properties show that sintering time has distinct effect on the frequency stability and the relaxation process. The result demonstrates that the enhanced magnetization, improved dielectric and ferroelectric properties may be correlated with the structural transformation, impurities, oxygen vacancies and grain morphology

    Study on dynamic strength and liquefaction mechanism of silt soil in Castor earthquake prone areas under different consolidation ratios

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    Under the Castor earthquake, there is a risk of liquefaction instability of saturated tailings, and the evolution of dynamic pore pressure can indirectly reflect its instability process. Before applying dynamic loads, the static stress state of soil is one of the main factors affecting the development of soil dynamic strength and dynamic pore pressure, and there are significant differences in soil dynamic strength under different consolidation ratios. This paper conducted dynamic triaxial tests on saturated tailings silt with different consolidation ratios, and analyzed the dynamic strength variation and liquefaction mechanism of the samples using the discrete element method (PFC3D). The results showed that 1) as the Kc′ gradually increased, and there was a critical consolidation ratio Kc′ during the development of the dynamic strength of the sample. The specific value of Kc′ was related to the properties and stress state of saturated sand. The Kc′ in this research was about 1.9. When Kc < 1.9, dynamic strength was increased with the increase in Kc; when Kc > 1.9, dynamic strength was decreased with the Kc. 2) Under the impact of cyclic load, when samples were normally consolidated (Kc =1), the pore water pressure would tend to be equal to the confining pressure to cause soil liquefaction. In the case of eccentric consolidation (Kc > 1), the pore water pressure would be less than the confining pressure, thus, the soil liquefaction would not be induced, and the pore pressure value would decrease with the increase of consolidation ratio. This paper provides engineering guidance value for the study of dynamic strength and liquefaction mechanism of tailings sand and silt in Castor earthquake prone areas under different consolidation ratios

    Molecular mechanisms controlling synaptic recruitment of GluA4 subunit-containing AMPAreceptors

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    Synaptic recruitment of AMPA receptors (AMPARs) represents a key postsynaptic mechanism driving functional development and maturation of glutamatergic synapses. At immature hippocampal synapses, PKA-driven synaptic insertion of GluA4 is the predominant mechanism for synaptic reinforcement. However, the physiological significance and molecular determinants of this developmentally restricted form of plasticity are not known. Here we show that PKA activation leads to insertion of GluA4 to synaptic sites with initially weak or silent AMPAR-mediated transmission. This effect depends on a novel mechanism involving the extreme C-terminal end of GluA4, which interacts with the membrane proximal region of the C-terminal domain to control GluA4 trafficking. In the absence of GluA4, strengthening of AMPAR-mediated transmission during postnatal development was significantly delayed. These data suggest that the GluA4-mediated activation of silent synapses is a critical mechanism facilitating the functional maturation of glutamatergic circuitry during the critical period of experience-dependent fine-tuning

    Etude de la cinétique des particules dans les couches frontières de la magnétosphère terrestre à l'aide des observations des satellites CLUSTER et DOUBLE STAR

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    The near-Earth space environment is complex and diverse. Particle kinetics plays a key role in understanding the nature of key phenomena and physical processes taking place in the Geospace. By means of the high-resolution data recorded by the multiple-point Cluster and Double star spacecraft, the present thesis investigated low energy ion kinetics in some crucial boundary layers of the terrestrial magnetosphere. The dominating roles played by the particle kinetics in the formations of those small-scale plasma structures and the feature of cross-scale coupling processes are summarized.L'environnement spatial proche de la Terre est complexe et divers. La cinétique des ions joue un rôle clé pour comprendre la nature des phénomènes essentiels et les processus physiques prenant place dans le "Géospace". Au moyen de données à haute résolution enregistrées par les quatre satellites Cluster et les deux satellites Double Star, cette thèse étudie la cinétique des ions de faible énergie dans certaines couches frontières essentielles de la magnétosphère terrestre. Le rôle dominant joué par la cinétique des particules dans les formations de ces structures de plasma à petite échelle et les caractéristiques des processus de couplage à différentes échelles y sont résumés
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