Recalibration of the Tethyan shallow-benthic zonation across the Paleocene-Eocene boundary : the Egyptian record

The Galala Mountains in Egypt provide an excellent platform-basin transect with deposits spanning the Paleocene/ Eocene (P/E) boundary. These interfingering deposits enable a recalibration between platform and open marine biostratigraphic schemes. We investigated 18 sections from a shallow-water carbonate platform margin, dominated by larger benthic foraminifera, to basinal marls with pelagic and deep marine biota. The Late Paleocene to Early Eocene development of larger foraminifera is well recorded in the Galala transect, in particular the Tethyan evolutionary event known as the larger foraminifera turnover (LFT). This turnover distinguishes Paleocene assemblages dominated by glomalveolinids, miscellanids and ranikothalids typical for shallow benthic Zone 4 (SBZ4) from those of SBZ5, dominated by alveolinids, nummulitids, and orbitolitids. Our data agree with previous studies that suggested that the larger foraminifera turnover (LFT) coincides with the Paleocene/ Eocene boundary, delineated by the carbon isotopic excursion (CIE) and that it correlates with the boundary between calcareous nannofossils subzones NP9a/b, the benthic extinction event in smaller benthic foraminifera and the boundary between planktic foraminifera Biozones P5/E1

The evolution of late Paleocene-early Eocene carbonate platforms of the Tethys

Abstrac

Singlet-Oxygen Generation by Peroxidases and Peroxygenases for Chemoenzymatic Synthesis

Singlet oxygen is a reactive oxygen species undesired in living cells but a rare and valuable reagent in chemical synthesis. We present a fluorescence spectroscopic analysis of the singlet-oxygen formation activity of commercial peroxidases and novel peroxygenases. Singlet-oxygen sensor green (SOSG) is used as fluorogenic singlet oxygen trap. Establishing a kinetic model for the reaction cascade to the fluorescent SOSG endoperoxide permits a kinetic analysis of enzymatic singlet-oxygen formation. All peroxidases and peroxygenases show singlet-oxygen formation. No singlet oxygen activity could be found for any catalase under investigation. Substrate inhibition is observed for all reactive enzymes. The commercial dye-decolorizing peroxidase industrially used for dairy bleaching shows the highest singlet-oxygen activity and the lowest inhibition. This enzyme was immobilized on a textile carrier and successfully applied for a chemical synthesis. Here, ascaridole was synthesized via enzymatically produced singlet oxygen. © 2020 Wiley-VCH Gmb

Carbonate Platform to Basin Transition along an Upper Cretaceous to Lower Tertiary Syrian Arc Uplift, Galala Plateaus, Eastern Desert of Egypt

ABSTRACT Biostratigraphic and facies analyses were made on Upper Campanian to Lower Eocene strata along a 58-kilometer-long dip transect across the Northern and Southern Galala plateaus, west of the Gulf of Suez. The analyses enabled us to reconstruct the evolution of a platform–slope–basin transition that is roughly parallel with the trend of the plateaus. We interpret individual sedimentary cycles as processes of a southward-prograding carbonate platform that developed along a branch of the Syrian Arc Fold Belt. The Northern Galala area was a structural high as shown by hiatuses spanning Late Cretaceous (Coniacian) to Early Paleocene times. To the south, carbonate platform progradation is evident from the Late Campanian onward. Late Cretaceous platform-derived slope deposits interfinger with basinal chalks and calcareous shales farther south. Early Tertiary carbonates were deposited in platform, slope, and basin settings. The evolution of the platform–slope–basin transition is documented by the changing large-scale depositional geometry. The evolution occurs within sedimentary sequences that are interpreted by means of a high-resolution biostratigraphic framework. The facies architecture reflects the evolution from a rimmed shelf (Late Cretaceous) to a distally steepened ramp (latest Cretaceous to Paleocene) and eventually to a homoclinal ramp (Early Eocene). The reconstruction of the imprint of fluctuating sea levels on the sedimentary record has been used to establish comparisons with age-equivalent cycles from neighboring regions.</jats:p

Ex Argumento Iuris Proedrias

Praeside Casp. Heinr. Hornio, D. Pand. P. P. Curiae Provincialis, Scab. ... IX. Id. Octobr. MDCXCVII. In ICtorum Auditorio publice disseret Christianus Scheibner, Chemnicens. Misnicu