1,388 research outputs found
Rhenium complex as emitting material in highly efficient phosphorescent organic light-emitting diodes
Interest in luminescent materials able to efficiently emit in the solid state is continuously
growing, because in most applications the dyes are used as solid films. This is the case of the
Organic Light Emitting Diodes (OLEDs), where electroluminescent
metal complexes have been widely investigated as dopants, able to
increase their performances [1]. We present here a dinuclear Re(I)
complexes (1, see Scheme 1) whose emission is higher in solid state
and in PMMA matrix than in solution and is used as dopant in
OLEDs.
This complex belong to the family of neutral Re(I) complexes
with general formula [Re2(CO)6(\u3bc-1,2-diazine)(\u3bc-X)2], where X is halogen. Some of them
have recently gained interest for their intense yellow/green emission, occurring from triplet
metal-to-ligand charge transfer (3MLCT) states [2], showing a modulation effect of the
diazine substituents on wavelengths, lifetimes and quantum yields of the emission. \u3a6 up to
0.53 has been measured for the di-chloro complexes containing diazines bearing alkyl groups
in both the \u3b2 positions [3]. At variance with the chloro derivatives, the bromo analogue 1 is
almost not-emitting in solution (\u3a6em 0.002 in deareated toluene). We have now found that in
the solid state 1 shows intense yellow-orange emission (\u3a6em 0.50 in neat powder), blue
shifted with respect to the solution (560 nm vs. 620 nm). The emission is intense also in
PMMA matrix (\u3a6em 0.19 in PMMA at 10% w/w, 556 nm).
This very high aggregated emission here is discussed in terms of the restriction of the
intramolecular roto-vibrational motions of the \u201cRe2(CO)6(\u3bc-Br)2\u201d scaffold imposed by the
rigid environment, as evidenced by the strong decrease of the knr. Moreover a parallel increase
of kr is noticed, which clearly shows the influence of the halides in determining not only the
energy of the excited state, but also the nature of the lowest (emitting) state.
These properties allowed its successful use as a phosphorescent dopant in OLEDs and
here we report the performances of OLED devices prepared both by solution- and vacuumprocessing.
The values of the external quantum efficiency are 1.7% (4.3 cd/A and 1.7 lm/W)
and 10% (29.1 cd/A and 22.1 lm/W) respectively and are the highest ever reported for
rhenium-based devices, comparable to state-of-the-art devices employing Ir(III)- and Pt(II)-
based metal complexes. The combination of synthetic strategy and encouraging results in
potential OLEDs applications should make these dinuclear Re(I) complexes highly attractive
to a broad spectrum of research fields.
1. \u201cHighly efficient OLEDs with Phosphorescent Materials\u201d H. Yersin Ed. Wiley-VCH, (2008).
2. D. Donghi, G. D\u2019Alfonso, M. Mauro, M. Panigati, P. Mercandelli, A. Sironi, P. Mussini, L. D\u2019Alfonso, Inorg.
Chem. 28 (2008) 4243-4255.
3. M. Mauro, E. Quartapelle Procopio, Y. Sun, C. H. Chien, D. Donghi, M. Panigati, P. Mercandelli, P. Mussini,
G. D\u2019Alfonso, L. De Cola, Adv. Funct. Mater. 19 (2009) 2607-2614
Understorey plant community and light availability in conifer plantations and natural hardwood forests in Taiwan
Questions: What are the effects of replacing mixed species natural forests with Cryptomeria japonica plantations on understorey plant functional and species diversity? What is the role of the understorey light environment in determining understorey diversity and community in the two types of forest?
Location: Subtropical northeast Taiwan.
Methods: We examined light environments using hemispherical photography, and diversity and composition of understorey plants of a 35âyr C. japonica plantation and an adjacent natural hardwood forest.
Results: Understorey plant species richness was similar in the two forests, but the communities were different; only 18 of the 91 recorded understorey plant species occurred in both forests. Relative abundance of plants among different functional groups differed between the two forests. Relative numbers of shadeâtolerant and shadeâintolerant seedling individuals were also different between the two forest types with only one shadeâintolerant seedling in the plantation compared to 23 seedlings belonging to two species in the natural forest. In the natural forest 11 species of tree seedling were found, while in the plantation only five were found, and the seedling density was only one third of that in the natural forest. Across plots in both forests, understorey plant richness and diversity were negatively correlated with direct sunlight but not indirect sunlight, possibly because direct light plays a more important role in understorey plant growth.
Conclusions: We report lower species and functional diversity and higher light availability in a natural hardwood forest than an adjacent 30âyr C. japonica plantation, possibly due to the increased dominance of shadeâintolerant species associated with higher light availability. To maintain plant diversity, management efforts must be made to prevent localized losses of shadeâadapted understorey plants
Study of Bc --> J/psi pi, etac pi decays with perturbative QCD approach
The Bc --> J/psi pi, etac pi decays are studied with the perturbative QCD
approach. It is found that form factors and branching ratios are sensitive to
the parameters w, v, f_J/psi and f_etac, where w and v are the parameters of
the charmonium wave functions for Coulomb potential and harmonic oscillator
potential, respectively, f_J/psi and f_etac are the decay constants of the
J/psi and etac mesons, respectively. The large branching ratios and the clear
signals of the final states make the Bc --> J/psi pi, etac pi decays to be the
prospective channels for measurements at the hadron collidersComment: 21 pages, revtex
A Four-Gene Signature from NCI-60 Cell Line for Survival Prediction in Non-Small Cell Lung Cancer
Purpose: Metastasis is the main cause of mortality in non-small cell lung cancer (NSCLC) patients. Genes that can discriminate the invasion ability of cancer cells may become useful candidates for clinical outcome prediction. We identify invasion-associated genes through computational and laboratorial approach that supported this idea in NSCLC. Experimental Design: We first conducted invasion assay to characterize the invasion abilities of NCI-60 lung cancer cell lines. We then systematically exploited NCI-60 microarray databases to identify invasion-associated genes that showed differential expression between the high and the low invasion cell line groups. Furthermore, using the microarray data of Duke lung cancer cohort (GSE 3141), invasion-associated genes with good survival prediction potentials were obtained. Finally, we validated the findings by conducting quantitative PCR assay on an in-house collected patient group (n = 69) and by using microarray data from two public western cohorts (n = 257 and 186). Results: The invasion-associated four-gene signature (ANKRD49, LPHN1, RABAC1, and EGLN2) had significant prediction in three validation cohorts (P = 0.0184, 0.002, and 0.017, log-rank test). Moreover, we showed that four-gene signature was an independent prognostic factor (hazard ratio, 2.354, 1.480, and 1.670; P = 0.028, 0.014, and 0.033), independent of other clinical covariates, such as age, gender, and stage. Conclusion: The invasion-associated four-gene signature derived from NCI-60 lung cancer cell lines had good survival prediction power for NSCLC patients. (Clin Cancer Res 2009;15(23):7309-15
Semileptonic and nonleptonic B decays to three charm quarks: B->J/psi (eta_c) D l nu and J/psi (eta_c) D pi
We evaluate the form factors describing the semileptonic decays , within the framework of a QCD
relativistic potential model. This decay is complementary to in a phase space region where a pion factors out.We
estimate the branching ratio for these semileptonic and nonleptonic channels,
finding ,
and .Comment: 14 pages, 4 figure
Charmless Exclusive Baryonic B Decays
We present a systematical study of two-body and three-body charmless baryonic
B decays. Branching ratios for two-body modes are in general very small,
typically less than , except that \B(B^-\to p \bar\Delta^{--})\sim
1\times 10^{-6}. In general, due to
the large coupling constant for . For three-body modes we
focus on octet baryon final states. The leading three-dominated modes are with a branching ratio of
order for and
for . The penguin-dominated decays with strangeness
in the meson, e.g., and , have appreciable rates and the mass
spectrum peaks at low mass. The penguin-dominated modes containing a strange
baryon, e.g., , have
branching ratios of order . In contrast, the decay
rate of is smaller. We explain why some of
charmless three-body final states in which baryon-antibaryon pair production is
accompanied by a meson have a larger rate than their two-body counterparts:
either the pole diagrams for the former have an anti-triplet bottom baryon
intermediate state, which has a large coupling to the meson and the
nucleon, or they are dominated by the factorizable external -emission
process.Comment: 46 pages and 3 figures, to appear in Phys. Rev. D. Major changes are:
(i) Calculations of two-body baryonic B decays involving a Delta resonance
are modified, and (ii) Penguin-dominated modes B-> Sigma+N(bar)+p are
discusse
Wave functions and decay constants of and mesons in the relativistic potential model
With the decay constants of and mesons measured in experiment
recently, we revisit the study of the bound states of quark and antiquark in
and mesons in the relativistic potential model. The relativistic bound
state wave equation is solved numerically. The masses, decay constants and wave
functions of and mesons are obtained. Both the masses and decay
constants obtained here can be consistent with the experimental data. The wave
functions can be used in the study of and meson decays.Comment: more discussion added, to appear in EPJ
Fabrication of CuO nanoparticle interlinked microsphere cages by solution method
Here we report a very simple method to convert conventional CuO powders to nanoparticle interlinked microsphere cages by solution method. CuO is dissolved into aqueous ammonia, and the solution is diluted by alcohol and dip coating onto a glass substrate. Drying at 80 °C, the nanostructures with bunchy nanoparticles of Cu(OH)2can be formed. After the substrate immerges into the solution and we vaporize the solution, hollow microspheres can be formed onto the substrate. There are three phases in the as-prepared samples, monoclinic tenorite CuO, orthorhombic Cu(OH)2, and monoclinic carbonatodiamminecopper(II) (Cu(NH3)2CO3). After annealing at 150 °C, the products convert to CuO completely. At annealing temperature above 350 °C, the hollow microspheres became nanoparticle interlinked cages
Deriving the mass of particles from Extended Theories of Gravity in LHC era
We derive a geometrical approach to produce the mass of particles that could
be suitably tested at LHC. Starting from a 5D unification scheme, we show that
all the known interactions could be suitably deduced as an induced symmetry
breaking of the non-unitary GL(4)-group of diffeomorphisms. The deformations
inducing such a breaking act as vector bosons that, depending on the
gravitational mass states, can assume the role of interaction bosons like
gluons, electroweak bosons or photon. The further gravitational degrees of
freedom, emerging from the reduction mechanism in 4D, eliminate the hierarchy
problem since generate a cut-off comparable with electroweak one at TeV scales.
In this "economic" scheme, gravity should induce the other interactions in a
non-perturbative way.Comment: 30 pages, 1 figur
Direct Measurements of the Branching Fractions for and and Determinations of the Form Factors and
The absolute branching fractions for the decays and
are determined using singly
tagged sample from the data collected around 3.773 GeV with the
BES-II detector at the BEPC. In the system recoiling against the singly tagged
meson, events for and events for decays are observed. Those yield
the absolute branching fractions to be and . The
vector form factors are determined to be
and . The ratio of the two form
factors is measured to be .Comment: 6 pages, 5 figure
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