Environmental-Friendly and Non-Toxic TBSI as an Alternative for MOR Accelerator

In the solid tyre rubber industry, most accelerators can produce n-nitrosamines as a by-product during the vulcanization process. As many n-nitrosamines are carcinogenic, they are highly regulated in final rubber articles and during manufacturing process.  2-(Morpholinothio benzothiazole (MOR) is the primary accelerator used in vulcanizing systems. It produces nitrogen toxic gases (nitrogen oxide and amine gas) which are carcinogenic. In this research MOR was successfully replaced with N-tert-butyl-2-benzothiazole sulfenimide (TBSI) accelerator which has no carcinogenic effect. The main objective of this research is to maintain its original properties while replacing MOR with TBSI accelerator.  This study was conducted and test samples were made of bonding rubber compound that is used to make the bonding layer of tyres which is the common part in all type of solid tyres. Physical-mechanical and bonding properties were analyzed for MOR and TBSI added bonding compound samples. Tensile, hardness, density and rheological using Oscillating die rheometer properties were also measured to maintain the quality of the tyre. The property change of bond layer can affects the other tyre layers. So, it can lead to failure of curing process or failure in performance of the tyre during the applications. The TBSI curing characteristics are closer to MOR sample. However other physical properties like hardness and density of TBSI samples were bit lower but they were in the required level as a bonding layer compound. Substitution of MOR by ‘safe TBSI’ compounds are still active as accelerators, but do not form carcinogenic gases

Impact of remittances on economic growth in developing countries: The role of openness

The paper examines the empirical relationship between remittances and economic growth for a sample of 62 developing countries over the time period 1990–2014. Remittances seem to promote growth only in the ‘more open’ countries. That is because remittances are in themselves not sufficient for growth. The extent of the benefit depends on domestic institutions and macroeconomic environment in the receiving country. Unlike the ‘less open’ countries, ‘more open’ countries have better institutions and better financial markets to take advantage of the remittances income and channelise them into profitable investments which, in turn, accelerates the rate of economic growth in these countries.N/

The use of hand-held computers (PDAs) to audit and validate eradication of a post-border detection of Khapra Beetle, Trogoderma granarium, in Western Australia

Most of Australia’s agricultural produce is exported. Demonstrating freedom from certain plant and animal pests and diseases is critical to securing and maintaining market access. Surveillance is an important tool in gaining market access and accordingly exporting countries now need to provide accurate, credible evidence to confirm pest freedom status.In the past nearly all field-collected surveillance information was recorded manually to paper reducing the rate of capture, integrity, conformity as well as security of the data. This paper describes the development of pest surveillance data collection software and hardware using PDAs (Personal Digital Assistants) to provide auditing, validation, chain of evidence and increase the volume of data collected as well as its integrity through relational databases and seamless data transfer to corporate systems. The system’s first deployment was during a T. granarium eradication. The khapra beetle (Trogoderma granarium) is one of the most serious pests of stored grain and is a regulated quarantine pest in most countries around the world. In April 2007, there was a post-border detection of T. granarium larvae and adults in a Western Australian residence. Immediate and uncompromising action was taken to quarantine the home and fumigate it with methyl-bromide at an internationally established rate known to control T. granarium (AQIS T9056). A two-year T. granarium trapping program was undertaken which used PDA software to provide evidence of complete eradication via 1273 trap inspections. This achievement was supported by GPSlocated traps, digital voice navigation itineraries, digital time and date stamps, field printed barcode labels, site imagery, all in a single hand-held unit. Keywords: T. granarium, Khapra beetle, Eradication, Biosecurity, PDA, Surveillanc

Spectroscopic Methods For Lubricant Quality Control In Engines And Gear Boxes

Lubricants play a vital role in reducing the wear and tear of engine/gear box metal parts. Number of analytical and spectroscopic methods have been used to analyze the quality of the lubricant oil. Moreover some parameters such as Total Acid Number (TAN), viscosity index also have been used to analyze the quality of the oil. Several used wind turbine gear oil samples were analyzed by various spectroscopic methods such as UV-Visible, Fourier-transform infrared (FTIR) and Fluorescence Spectroscopy. Fluorescence method gave promising results among those three spectroscopic methods. In order to study thermal degradation, motor oil samples were subjected to artificial aging in the laboratory conditions by heating them up to different temperatures for different time periods and then subsequently analyzed with fluorescence spectroscopic method. Subsequently two used engine oil samples from a same diesel engine vehicle were analyzed using fluorescence spectroscopic method.  Notable variation in fluorescence emission intensities was observed with oil aging. Intensity of the fluorescence emission signal decrease with oil degradation.  Therefore fluorescence spectroscopic method can be used to predict the reusability of gear oils as well as to identify the oil degradation. This method can be further extended to develop a novel potential sensor to detect the quality of oil in various types of engines. KEYWORDS: Lubricant oil, Oil degradation, Fluorescence spectroscopy, Analytical methods

SOFI: A 3D simulator for the generation of underwater optical images

International audienceWe present an original simulator-called SOFI-for the synthetic generation of underwater optical images. The simulator architecture is flexible and relies on flow diagrams in order to allow the integration of various models for image generation which are based on the underwater optical phenomena. The objective is also to ensure real time or quasi real time performance so it takes advantage of the latest technologies, such as GPGPU, and relies on GPU programming under CUDA. Two kinds of models for image generation are presented and should be integrated in SOFI: (1) the OSOA model based on the radiative transfer theory and (2) global image modeling which describes globally how an image is deteriorated under the effects of sea water

Sustainable Use of Biomass Boiler Ash as a Reinforcement Filler for Polyamide 6 Composite

The use of biomass combustion ash as a reinforcing filler has taken the attention in recent years to reduce the overall production cost and increase the mechanical properties of plastics. This study evaluates the effect of biomass boilers ash (BBA) as a reinforcing filler on polyamide 6 composites (PA6). The chemical composition and thermal stability of BBA were analyzed by X-ray fluorescence (XRF), Thermogravimetric analysis (TGA), and Differential thermal analysis (DTA) thermographs. Test samples were prepared by varying the ash content (2.5%, 5%, 7.5%, and 10%), and also samples were prepared without adding ash as a control. Moreover, surface modification was carried out by using N-2 (Aminoethyl) 3-aminopropyl triethoxy diamino-silane as a possible coupling agent for BBA  and it was tested by varying the coupling agent concentration (0.5%, 1%, and 2%) by dry process and the samples were prepared by extrusion and injection molding processes. Comparative analysis of the degree of crystallinity, mechanical properties including tensile, flexural, and thermal properties were tested. The highest degree of crystallinity was obtained with 7.5% BBA-filled composites. The addition of 2% surface-modified BBA (SBBA) filled composites (PA6 / 10% Ash 2% CA) showed an increase of tensile strength and elongation at break than the 10% unmodified BBA (UBBA) (PA6/ 10% Ash) filled composites. Stress at peak and bending modulus values in the flexural test data were increased up to 10%. But it was significantly reduced with the increasing of modifying agent concentration due to the increment of stiffness of the composite

Income distribution patterns from a complete social security database

We analyze the income distribution of employees for 9 consecutive years (2001-2009) using a complete social security database for an economically important district of Romania. The database contains detailed information on more than half million taxpayers, including their monthly salaries from all employers where they worked. Besides studying the characteristic distribution functions in the high and low/medium income limits, the database allows us a detailed dynamical study by following the time-evolution of the taxpayers income. To our knowledge, this is the first extensive study of this kind (a previous japanese taxpayers survey was limited to two years). In the high income limit we prove once again the validity of Pareto's law, obtaining a perfect scaling on four orders of magnitude in the rank for all the studied years. The obtained Pareto exponents are quite stable with values around $\alpha \approx 2.5$, in spite of the fact that during this period the economy developed rapidly and also a financial-economic crisis hit Romania in 2007-2008. For the low and medium income category we confirmed the exponential-type income distribution. Following the income of employees in time, we have found that the top limit of the income distribution is a highly dynamical region with strong fluctuations in the rank. In this region, the observed dynamics is consistent with a multiplicative random growth hypothesis. Contrarily with previous results obtained for the japanese employees, we find that the logarithmic growth-rate is not independent of the income.Comment: 10 pages, 7 Figure

Zolpidem: Efficacy and side effects for insomnia

Insomnia is linked to fatigue, distractibility, mood instability, decreased satisfaction, and overall decreased quality of life. Optimal therapy can aid patients in returning to baseline and increase their quality of life. Zolpidem is a helpful drug for the treatment of insomnia in conjunction with cognitive-behavioral therapy. When prescribed to elderly patients, the dose should be adjusted to account for their slower drug metabolism. Still, zolpidem is considered a reasonable choice of therapy because it has a lower incidence of residual daytime sleepiness and risk of falls when compared to other drugs. The most concerning adverse effects, which are often the most publicized, include the complex behaviors that have been seen in patients taking Zolpidem, such as sleeping, hallucinations, increased suicidality, driving cars while asleep, and even a few cases of committing homicide. Even so, zolpidem could be a suitable pharmacological treatment for insomnia. Decisions for whether or not to prescribe it and the dosage should be made on a case-by-case basis, considering both the psychical and psychiatric risks posed to the patient with insomnia versus if the patient were to take zolpidem to treat their condition

Characterising binge eating over the course of a feasibility trial among individuals with binge eating disorder and bulimia nervosa

This is the final version. Available from Elsevier via the DOI in this record.Binge eating disorder and bulimia nervosa are eating disorders that are characterized by recurrent binge eating episodes. The highly contextualized nature of binge eating makes naturalistic research a particularly suitable means of understanding the context within which binge eating occurs. The present study aimed to characterise binge eating days with regards to the frequency and probability of negative affect, food craving, meal skipping, and dietary restriction. In addition, it aimed to examine whether a combined intervention that targets the experience of ‘loss of control’ over eating can decrease these potential maintenance factors that often precede binge eating episodes. Seventy-eight participants with bulimia nervosa (N = 40) or binge eating disorder (n = 38), who were randomly allocated to a food-specific or general intervention combining inhibitory control training and implementation intentions, completed mood and food diaries over four weeks. Results suggest that negative affect and food craving were elevated on binge eating days, but that dietary restraint and meal skipping did not characterise binge eating days. Moreover, meal skipping, binge eating, restriction, and compensation decreased throughout the intervention period, while negative affect and food craving did not. This suggests that some interventions may successfully reduce binge eating frequency without necessarily decreasing negative affect or food craving, thus pointing to the different routes to targeting binge eating and providing implications for future interventions.National Institute for Health Research (NIHR)H2020 European Research Council (ERC)National Institute for Health Research (NIHR)Maudsley NHS Foundation TrustKing's College Londo