Near Infrared Surface Properties of the Two Intrinsically Brightest Minor Planets (90377) Sedna and (90482) Orcus

We present low resolution K band spectra taken at the Gemini 8 meter telescope of (90377) Sedna and (90482) Orcus (provisional designations 2003 VB12 and 2004 DW, respectively), currently the two minor planets with the greatest absolute magnitudes (i.e. the two most reflective minor planets). We place crude limits on the surface composition of these two bodies using a Hapke model for a wide variety of assumed albedos. The unusual minor planet (90377) Sedna was discovered on November 14, 2003 UT at roughly 90 AU with 1.6 times the heliocentric distance and perihelion distance of any other bound minor planet. It is the first solar system object discovered between the Kuiper Belt and the Oort Cloud, and may represent a transition population between the two. The reflectance spectrum of (90377) Sedna appears largely featureless at the current signal-to-noise ratio, suggesting a surface likely to be highly processed by cosmic rays. For large grain models (100 micron to 1 cm) we find that (90377) Sedna must have less than 70% surface fraction of water ice and less than 60% surface fraction of methane ice to 3 sigma confidence. Minor planet (90482) Orcus shows strong water ice absorption corresponding to less than 50% surface fraction for grain models 25 micron and larger. Orcus cannot have more than 30% of its surface covered by large (100 mm to 1 cm) methane grains to 3 sigma confidence.Comment: Accepted for publication in the Astrophysical Journa

Underground CO2 storage: demonstrating regulatory conformance by convergence of history-matched modeled and observed CO2 plume behavior using Sleipner time-lapse seismics

One of the three key regulatory requirements in Europe for transfer of storage site liability is to demonstrate conformity between predictive models of reservoir performance and monitoring observations. This is a challenging requirement because a perfect and unique match between observed and modeled behavior is near impossible to achieve. This study takes the time-lapse seismic monitoring data from the Sleipner storage operation to demonstrate that as more seismic data becomes available with time, predictive models can be matched more accurately to observations and become more reliable predictors of future performance. Six simple performance measures were defined: plume footprint area, maximum lateral migration distance of CO2 from the injection point, area of CO2 accumulation trapped at top reservoir, volume of CO2 accumulation trapped at top reservoir, area of all CO2 layers summed, and spreading co-efficient. Model scenarios were developed to predict plume migration up to 2008. Scenarios were developed for 1996 (baseline), 2001, and 2006 conditions, with models constrained by the information available at those times, and compared with monitoring datasets obtained up to 2008. The 1996 predictive range did generally encompass the future observed plume behavior, but with such a wide range of uncertainty as to render it of only marginal practical use. The 2001 predictions (which used the 1999 and 2001 seismic monitoring datasets) had a much lower uncertainty range, with the 2006 uncertainties somewhat lower again. There are still deficiencies in the actual quality of match but a robust convergence, with time, of predicted and observed models is clearly demonstrated. We propose modeling-monitoring convergence as a generic approach to demonstrating conformance

The urine patch diffusional area: An important N2O source?

AbstractUrine patches contribute greatly to greenhouse gas emissions within livestock grazed ecosystems. The effective area of a ruminant urine patch comprises the wetted area, the diffusional area and the pasture response area. This study specifically assesses the importance of considering the diffusional area for monitoring urine patch N2O emissions. Spatial and temporal changes in N2O emissions and potential drivers of emissions (soil pH, EC, redox potential, dissolved organic carbon and nitrogen, NO3− and NH4+) were measured in sheep urine amended Eutric Cambisol mesocosms, maintained at 50% or 70% water-filled pore space (WFPS). At 70% WFPS, over 10 weeks, the emission factor (EF) was greater when considering the wetted area plus a 9 cm diffusional area (EF = 2.75 ± 0.72% of applied N) than when considering the wetted area alone (EF = 1.44 ± 0.30% of applied N); differences were not statistically significant at 50% WFPS. Redox potential, total extractable N and WFPS contributed significantly to the observed variation in daily N2O fluxes from the urine patch. We conclude that the urine patch diffusional area is an extremely important source of emissions from urine patches. This has implications when measuring EFs, as the lateral diffusion of solutes may be restricted by chamber walls resulting in an underestimate of N2O emissions, particularly at higher soil moisture contents. Site-specific assessments of the urine patch diffusional area should be made, and accounted for, prior to monitoring emissions and calculating emission factors from urine patches applied within chambers

Strategies to reduce nutrient pollution from manure management in China

As the demand for livestock products continues to increase in China, so too does the challenge of managing increasing quantities of manure. Urgent action is needed to control point source (housing, storage and processing) and diffuse (field application) pollution and improve the utilization of manure nutrients and organic matter. Here, we review strategies to improve management at each stage of the manure management chain and at different scales. Many strategies require infrastructure investment, e.g., for containment of all manure fractions. Engineering solutions are needed to develop advanced composting systems with lower environmental footprints and design more efficient nutrient stripping technologies. At the field-scale, there is an urgent need to develop a manure nutrient recommendation system that accounts for the range of manure types, cropping systems, soils and climates throughout China. At the regional scale, coordinated planning is necessary to promote recoupling of livestock and cropping systems, and reduce nutrient accumulation in regions with little available landbank, while minimizing the risk of pollution swapping from one region to another. A range of stakeholders are needed to support the step change and innovation required to improve manure management, reduce reliance on inorganic fertilizers, and generate new business opportunities

Nutrient removal capacity of wood residues for the Agro-environmental safety of ground and surface waters

Abstract   The aim of this study was to determine the effectiveness of wood residues in the removal of nutrients (ammonium-N; NH4-N) from nutrient-rich (NH4-N) waters. The water holding capacity of the wood materials was also determined. Carried out at Rothamsted Research, North Wyke, UK, this controlled laboratory experiment tested two wood residues; in length, one being 1-2cm and the other from 150 µm (microns) to 9.5mm. Although a wide range of studies have shown the effectiveness and performance of various absorbent materials as animal beddings, such as straw (cereal straw), woodchip (sawdust, bark or wood shavings), bracken and rushes, only few have focused on the NH4-N sorption/desorption capacity. The depuration capacity of wood residues from nutrient-rich effluents such as those from cattle bedded on woodchip or straw will be controlled by processes such as sorption (adsorption-absorption) and desorption of nutrients. Studies have reported the nitrogen removal capacity of woodchip materials and biochar from woodchip as well as removal of NH4+-N from domestic and municipal wastewater, farm dirty water, landfill and industry effluents. These studies have observed that the mechanism of removal of nitrogen is by either increasing NO3--N removal form leachate by enhancing N2O losses via denitrification (biochar as carbon source for denitrifiers) or by decreasing NH4+-N in leachate through adsorption to negatively charged sites. Results showed that although the cation exchange capacity (CEC) and surface area (SA) are both fundamental properties of adsorbent materials, no correlation was found with CEC and adsorption or desorption. Nor did changes in pH appear to be sufficiently important to cause changes in CEC. For this reason, osmotic pressure appeared to be a more predominant parameter controlling processes of adsorption and desorption of NH4+-N in both wood residues. Thus, wood residues high in NH4+-N should be avoided, as they could have an opposite effect in the adsorption of nutrients from nutrient-rich effluents. The results also showed that some wood residues (G30) had great capacity to adsorb NH4+-N to levels up to nearly 90% whilst demonstrating low desorption capacity of NH4+-N (less than 1%). These are ideal relevant features for an adsorbent material for the removal of nutrients (or heavy metals) from contaminated waters such us farm o industrial effluents, or for the depuration of eutrophic watercourses. This could help reduce the concentration of farm effluents making them more manageable, subsequently contributing towards the compliance of new environmental regulations. Keywords: nutrients, nitrogen, ground and surface wate

Exploring the acceptability of a ‘limited patient consent procedure’ for a proposed blood-borne virus screening programme: a Delphi consensus building technique

Objective To identify components of a proposed blood-borne virus (BBV) population screening programme and its associated consent procedure that both the public and health practitioners (HPs) would find acceptable. The proposed BBV screening system would aim to reduce late diagnosis of BBVs and be used in patients undergoing routine blood tests, aided by risk stratification software to target individuals at higher risk of infection. Design A Delphi technique was used to build consensus among two separate groups, public participants and HPs in England. Methods A survey incorporating vignettes was developed, with input from an external panel of experts. Over three rounds, 46 public participants and 37 HPs completed the survey, rating statements on a four-point Likert scale. The survey covered issues around stigma and sensitivity, the use of risk stratification algorithms and ‘limited’ patient consent (ie, preinformed of the option to ‘opt-out’). Consensus was defined as >70% of participants agreeing or disagreeing with each statement. Results Consensus was achieved among both groups in terms of acceptability of the screening programme. There was also consensus on using patient data to risk-stratify screening algorithms and the need to obtain some form of consent around the time of drawing blood. Conclusions This study found that the special protected status of HIV in England is no longer deemed necessary today and hinders appropriate care. We propose that a novel ‘limited consent procedure’ could be implemented in future screening programmes

Development and testing of a risk indexing framework to determine field-scale critical source areas of faecal bacteria on grassland.

This paper draws on lessons from a UK case study in the management of diffuse microbial pollution from grassland farm systems in the Taw catchment, south west England. We report on the development and preliminary testing of a field-scale faecal indicator organism risk indexing tool (FIORIT). This tool aims to prioritise those fields most vulnerable in terms of their risk of contributing FIOs to water. FIORIT risk indices were related to recorded microbial water quality parameters (faecal coliforms [FC] and intestinal enterococci [IE]) to provide a concurrent on-farm evaluation of the tool. There was a significant upward trend in Log[FC] and Log[IE] values with FIORIT risk score classification (r2 =0.87 and 0.70, respectively and P<0.01 for both FIOs). The FIORIT was then applied to 162 representative grassland fields through different seasons for ten farms in the case study catchment to determine the distribution of on-farm spatial and temporal risk. The high risk fields made up only a small proportion (1%, 2%, 2% and 3% for winter, spring, summer and autumn, respectively) of the total number of fields assessed (and less than 10% of the total area), but the likelihood of the hydrological connection of high FIO source areas to receiving watercourses makes them a priority for mitigation efforts. The FIORIT provides a preliminary and evolving mechanism through which we can combine risk assessment with risk communication to end-users and provides a framework for prioritising future empirical research. Continued testing of FIORIT across different geographical areas under both low and high flow conditions is now needed to initiate its long term development into a robust indexing tool