Phosphorus Abundances in FGK Stars

We measured phosphorus abundances in 22 FGK dwarfs and giants that span --0.55 $<$ [Fe/H] $<$ 0.2 using spectra obtained with the Phoenix high resolution infrared spectrometer on the Kitt Peak National Observatory Mayall 4m telescope, the Gemini South Telescope, and the Arcturus spectral atlas. We fit synthetic spectra to the P I feature at 10581 $\AA$ to determine abundances for our sample. Our results are consistent with previously measured phosphorus abundances; the average [P/Fe] ratio measured in [Fe/H] bins of 0.2 dex for our stars are within $\sim$ 1 $\sigma$ compared to averages from other IR phosphorus studies. Our study provides more evidence that models of chemical evolution using the results of theoretical yields are under producing phosphorus compared to the observed abundances. Our data better fit a chemical evolution model with phosphorus yields increased by a factor of 2.75 compared to models with unadjusted yields. We also found average [P/Si] = 0.02 $\pm$ 0.07 and [P/S] = 0.15 $\pm$ 0.15 for our sample, showing no significant deviations from the solar ratios for [P/Si] and [P/S] ratios.Comment: 11 pages, 5 figures, Accepted to Ap

Abundances of carbon-enhanced metal-poor stars as constraints on their formation

Reproduced with permission from Astronomy & Astrophysics. © 2018 ESO.Context. An increasing fraction of carbon-enhanced metal-poor (CEMP) stars is found as their iron abundance, [Fe/H], decreases below [Fe/H] =−2.0. The CEMP-s stars have the highest absolute carbon abundances, [C/H], and are thought to owe their enrichment in carbon and the slow neutron-capture (s-process) elements to mass transfer from a former asymptotic giant branch (AGB) binary companion. The most Fe-poor CEMP stars are normally single, exhibit somewhat lower [C/H] than CEMP-s stars, but show no s-process element enhancement (CEMP-no stars). Abundance determinations of CNO offer clues to their formation sites. Aims. Our aim is to use the medium-resolution spectrograph X-Shooter/VLT to determine stellar parameters and abundances for C, N, Sr, and Ba in several classes of CEMP stars in order to further classify and constrain the astrophysical formation sites of these stars. Methods. Atmospheric parameters for our programme stars were estimated from a combination of V−K photometry, model isochrone fits, and estimates from a modified version of the SDSS/SEGUE spectroscopic pipeline. We then used X-Shooter spectra in conjunction with the 1D local thermodynamic equilibrium spectrum synthesis code MOOG, 1D ATLAS9 atmosphere models to derive stellar abundances, and, where possible, isotopic 12C/13C ratios. Results. Abundances (or limits) of C, N, Sr, and Ba are derived for a sample of 27 faint metal-poor stars for which the X-Shooter spectra have sufficient signal-to-noise ratios (S/N). These moderate resolution, low S/N (~10−40) spectra prove sufficient to perform limited chemical tagging and enable assignment of these stars into the CEMP subclasses (CEMP-s and CEMP-no). According to the derived abundances, 17 of our sample stars are CEMP-s and 3 are CEMP-no, while the remaining 7 are carbon-normal. For four CEMP stars, the subclassification remains uncertain, and two of them may be pulsating AGB stars. Conclusions. The derived stellar abundances trace the formation processes and sites of our sample stars. The [C/N] abundance ratio is useful for identifying stars with chemical compositions unaffected by internal mixing, and the [Sr/Ba] abundance ratio allows us to distinguish between CEMP-s stars with AGB progenitors and the CEMP-no stars. Suggested formation sites for the latter include faint supernovae with mixing and fallback and/or primordial, rapidly-rotating, massive stars (spinstars). X-Shooter spectra have thus proved to be valuable tools in the continued search for their origin.Peer reviewe

The effects of stellar winds of fast-rotating massive stars in the earliest phases of the chemical enrichment of the Galaxy

We use the growing data sets of very-metal-poor stars to study the impact of stellar winds of fast rotating massive stars on the chemical enrichment of the early Galaxy. We use an inhomogeneous chemical evolution model for the Galactic halo to predict both the mean trend and scatter of C/O and N/O. In one set of models, we assume that massive stars enrich the interstellar medium during both the stellar wind and supernovae phases. In the second set, we consider that in the earliest phases (Z <10^-8), stars with masses above 40 Msun only enrich the interstellar medium via stellar winds, collapsing directly into black holes. We predict a larger scatter in the C/O and N/O ratios at low metallicities when allowing the more massive fast-rotating stars to contribute to the chemical enrichment only via stellar winds. The latter assumption, combined with the stochasticity in the star formation process in the primordial Galactic halo can explain the wide spread observed in the N/O and C/O ratios in normal very-metal-poor stars. For chemical elements with stellar yields that depend strongly on initial mass (and rotation) such as C, N, and neutron capture elements, within the range of massive stars, a large scatter is expected once the stochastic enrichment of the early interstellar medium is taken into account. We also find that stellar winds of fast rotators mixed with interstellar medium gas are not enough to explain the large CNO enhancements found in most of the carbon-enhanced very-metal-poor stars. In particular, this is the case of the most metal-poor star known to date, HE 1327-2326, for which our models predict lower N enhancements than observed when assuming a mixture of stellar winds and interstellar medium. We suggest that these carbon-enhanced very metal-poor stars were formed from almost pure stellar wind material, without dilution with the pristine interstellar medium.Comment: 10 pages, 7 figures, accepted for publication in A&

Solar abundance of manganese: a case for near Chandrasekhar-mass Type la supernova progenitors

Manganese is predominantly synthesised in Type Ia supernova (SN Ia) explosions. Owing to the entropy dependence of the Mn yield in explosive thermonuclear burning, SNe Ia involving near Chandrasekhar-mass (MCh) white dwarfs (WDs) are predicted to produce Mn-to-Fe ratios that significantly exceed those of SN Ia explosions involving sub-Chandrasekhar mass primary WDs. Of all current supernova explosion models, only SN Ia models involving near-MCh WDs produce [Mn/Fe] ≳ 0.0

Uncertainties in νp-process nucleosynthesis from Monte Carlo variation of reaction rates

It has been suggested that a νp-process can occur when hot, dense, and proton-rich matter is expanding within a strong flux of antineutrinos. In such an environment, proton-rich nuclides can be produced in sequences of proton captures and (n, p) reactions, where the free neutrons are created in situ by νe + p → n + e+ reactions. The detailed hydrodynamic evolution determines where the nucleosynthesis path turns off from N = Z line and how far up the nuclear chart it runs. In this work, the uncertainties on the final isotopic abundances stemming from uncertainties in the nuclear reaction rates were investigated in a large-scale Monte Carlo approach, simultaneously varying more than 10 000 reactions. A large range of model conditions was investigated because a definitive astrophysical site for the νp-process has not yet been identified. The present parameter study provides, for each model, identification of the key nuclear reactions dominating the uncertainty for a given nuclide abundance. As all rates appearing in the νp-process involve unstable nuclei, and thus only theoretical rates are available, the final abundance uncertainties are larger than those for nucleosynthesis processes closer to stability. Nevertheless, most uncertainties remain below a factor of 3 in trajectories with robust nucleosynthesis. More extreme conditions allow production of heavier nuclides but show larger uncertainties because of the accumulation of the uncertainties in many rates and because the termination of nucleosynthesis is not at equilibrium conditions. It is also found that the solar ratio of the abundances of 92Mo and 94Mo could be reproduced within uncertainties

Abundance gradients in the Milky Way for alpha elements, Iron peak elements, Barium, Lanthanum and Europium

We model the abundance gradients in the disk of the Milky Way for several chemical elements (O, Mg, Si, S, Ca, Sc, Ti, Co, V, Fe, Ni, Zn, Cu, Mn, Cr, Ba, La and Eu), and compare our results with the most recent and homogeneous observational data. We adopt a chemical evolution model able to well reproduce the main properties of the solar vicinity. We compute, for the first time, the abundance gradients for all the above mentioned elements in the galactocentric distance range 4 - 22 kpc. The comparison with the observed data on Cepheids in the galactocentric distance range 5-17 kpc gives a very good agreement for many of the studied elements. In addition, we fit very well the data for the evolution of Lanthanum in the solar vicinity for which we present results here for the first time. We explore, also for the first time, the behaviour of the abundance gradients at large galactocentric distances by comparing our results with data relative to distant open clusters and red giants and select the best chemical evolution model model on the basis of that. We find a very good fit to the observed abundance gradients, as traced by Cepheids, for most of the elements, thus confirming the validity of the inside-out scenario for the formation of the Milky Way disk as well as the adopted nucleosynthesis prescriptions.Comment: 11 pages, 9 figures, accepted for publication in A&

Uncertainties in νp-process nucleosynthesis from Monte Carlo variation of reaction rates

This article has been accepted for publication in Monthly Notices of the Royal Astronomical Society ©: 2019 The Author(s). Published by Oxford University Press on behalf of the Royal Astronomical Society. All rights reserved.It has been suggested that a νp-process can occur when hot, dense, and proton-rich matter is expanding within a strong flux of antineutrinos. In such an environment, proton-rich nuclides can be produced in sequences of proton captures and (n, p) reactions, where the free neutrons are created in situ by νe + p → n + e+ reactions. The detailed hydrodynamic evolution determines where the nucleosynthesis path turns off from N = Z line and how far up the nuclear chart it runs. In this work, the uncertainties on the final isotopic abundances stemming from uncertainties in the nuclear reaction rates were investigated in a large-scale Monte Carlo approach, simultaneously varying more than 10 000 reactions. A large range of model conditions was investigated because a definitive astrophysical site for the νp-process has not yet been identified. The present parameter study provides, for each model, identification of the key nuclear reactions dominating the uncertainty for a given nuclide abundance. As all rates appearing in the νp-process involve unstable nuclei, and thus only theoretical rates are available, the final abundance uncertainties are larger than those for nucleosynthesis processes closer to stability. Nevertheless, most uncertainties remain below a factor of 3 in trajectories with robust nucleosynthesis. More extreme conditions allow production of heavier nuclides but show larger uncertainties because of the accumulation of the uncertainties in many rates and because the termination of nucleosynthesis is not at equilibrium conditions. It is also found that the solar ratio of the abundances of 92Mo and 94Mo could be reproduced within uncertainties.Peer reviewe

High-resolution abundance analysis of red giants in the globular cluster NGC 6522

The [Sr/Ba] and [Y/Ba] scatter observed in some galactic halo stars that are very metal-poor stars and in a few individual stars of the oldest known Milky Way globular cluster NGC 6522,have been interpreted as evidence of early enrichment by massive fast-rotating stars (spinstars). Because NGC 6522 is a bulge globular cluster, the suggestion was that not only the very-metal poor halo stars, but also bulge stars at [Fe/H]~-1 could be used as probes of the stellar nucleosynthesis signatures from the earlier generations of massive stars, but at much higher metallicity. For the bulge the suggestions were based on early spectra available for stars in NGC 6522, with a medium resolution of R~22,000 and a moderate signal-to-noise ratio. The main purpose of this study is to re-analyse the NGC 6522 stars previously reported using new high-resolution (R~45,000) and high signal-to-noise spectra (S/N>100). We aim at re-deriving their stellar parameters and elemental ratios, in particular the abundances of the neutron-capture s-process-dominated elements such as Sr, Y, Zr, La, and Ba, and of the r-element Eu. High-resolution spectra of four giants belonging to the bulge globular cluster NGC 6522 were obtained at the 8m VLT UT2-Kueyen telescope with the UVES spectrograph in FLAMES-UVESconfiguration. The spectroscopic parameters were derived based on the excitation and ionization equilibrium of \ion{Fe}{I} and \ion{Fe}{II}. Our analysis confirms a metallicity [Fe/H] = -0.95+-0.15 for NGC 6522, and the overabundance of the studied stars in Eu (with +~0.2 < [Eu/Fe] < +~0.4) and alpha-elements O and Mg. The neutron-capture s-element-dominated Sr, Y, Zr, Ba, La now show less pronounced variations from star to star. Enhancements are in the range 0.0 < [Sr/Fe] < +0.4, +0.23 < [Y/Fe] < +0.43, 0.0 < [Zr/Fe] < +0.4, 0.0 < [La/Fe] < +0.35,and 0.05 < [Ba/Fe] < +0.55.Comment: date of acceptation: 31/07/2014, in press, 24 pages, 19 figures,Astronomy & Astrophysics, 201

Structural analysis of the O-acetylated O-polysaccharide isolated from Salmonella Paratyphi A and used for vaccine preparation

Salmonella paratyphi A is increasingly recognized as a common cause of enteric fever cases and there are no licensed vaccines against this infection. Antibodies directed against the O-polysaccharide of the lipopolysaccharide of Salmonella are protective and conjugation of the O-polysaccharide to a carrier protein represents a promising strategy for vaccine development. O-Acetylation of S. paratyphi A O-polysaccharide is considered important for the immunogenicity of S. paratyphi A conjugate vaccines. Here, as part of a programme to produce a bivalent conjugate vaccine against both S. typhi and S. paratyphi A diseases, we have fully elucidated the O-polysaccharide structure of S. paratyphi A by use of HPLC\u2013SEC, HPAEC\u2013PAD/CD, GLC, GLC\u2013MS, 1D and 2D-NMR spectroscopy. In particular, chemical and NMR studies identified the presence of O-acetyl groups on C-2 and C-3 of rhamnose in the lipopolysaccharide repeating unit, at variance with previous reports of O-acetylation at a single position. Moreover HR-MAS NMR analysis performed directly on bacterial pellets from several strains of S. paratyphi A also showed O-acetylation on C-2 and C-3 of rhamnose, thus this pattern is common and not an artefact from O-polysaccharide purification. Conjugation of the O-polysaccharide to the carrier protein had little impact on O-acetylation and therefore should not adversely affect the immunogenicity of the vaccine