Quantum-ionic features in the absorption spectra of homonuclear diatomic molecules

Under the terms of the Creative Commons Attribution License 3.0 (CC-BY).We show that additional features can emerge in the linear absorption spectra of homonuclear diatomic molecules when the ions are described quantum mechanically. In particular, the widths and energies of the peaks in the optical spectra change with the initial configuration, mass, and charge of the molecule. We introduce a model that can describe these features and we provide a quantitative analysis of the resulting peak energy shifts and width broadenings as a function of the mass.We acknowledge financial support from the European Research Council Advanced Grant DYNamo (Grant No. ERC-2010-AdG-267374), Spanish Grants No. FIS2013-46159-C3-1-P and No. PIB2010US-00652, and Grupo Consolidado UPV/EHU del Gobierno Vasco (Grant No. IT578-13). A.C.-U. acknowledges financial support from the Departamento de Educacion, Universidades e Investigacion del Gobierno Vasco (Reference No. BFI-2011-26).Peer Reviewe

Development of a Mechanics Reasoning Inventory

Strategic knowledge is required to appropriately organize procedures and concepts to solve problems. We are developing a standardized instrument assessing strategic knowledge in the domain of introductory mechanics. This instrument is inspired in part by Lawson's Classroom Test of Scientific Reasoning and Van Domelen's Problem Decomposition Diagnostic. The predictive validity of the instrument has been suggested by preliminary studies showing significant correlation with performance on final exams administered in introductory mechanics courses at the Massachusetts Institute of Technology and the Georgia Institute of Technology. In order to study the validity of the content from the student's perspective, we have administered the instrument in free-response format to 40 students enrolled in calculus-based introductory mechanics at the University of Wisconsin-Platteville. This procedure has the additional advantage of improving the construct validity of the inventory, since student responses suggest effective distractors for the multiple-choice form of the inventory.National Science Foundation (U.S.) (PHY-0757931)National Science Foundation (U.S.) (DUE-1044294)National Institutes of Health (U.S.) (1-RC1-RR028302-01

Item response theory analysis of the mechanics baseline test

Item response theory is useful in both the development and evaluation of assessments and in computing standardized measures of student performance. In item response theory, individual parameters (difficulty, discrimination) for each item or question are fit by item response models. These parameters provide a means for evaluating a test and offer a better measure of student skill than a raw test score, because each skill calculation considers not only the number of questions answered correctly, but the individual properties of all questions answered. Here, we present the results from an analysis of the Mechanics Baseline Test given at MIT during 2005-2010. Using the item parameters, we identify questions on the Mechanics Baseline Test that are not effective in discriminating between MIT students of different abilities. We show that a limited subset of the highest quality questions on the Mechanics Baseline Test returns accurate measures of student skill. We compare student skills as determined by item response theory to the more traditional measurement of the raw score and show that a comparable measure of learning gain can be computed

When students can choose easy, medium, or hard homework problems

We investigate student-chosen, multi-level homework in our Integrated Learning Environment for Mechanics [1] built using the LON-CAPA [2] open-source learning system. Multi-level refers to problems categorized as easy, medium, and hard. Problem levels were determined a priori based on the knowledge needed to solve them [3]. We analyze these problems using three measures: time-per-problem, LON-CAPA difficulty, and item difficulty measured by item response theory. Our analysis of student behavior in this environment suggests that time-per-problem is strongly dependent on problem category, unlike either score-based measures. We also found trends in student choice of problems, overall effort, and efficiency across the student population. Allowing students choice in problem solving seems to improve their motivation; 70% of students worked additional problems for which no credit was given.National Science Foundation (U.S.) (Grant PHY-0757931)National Science Foundation (U.S.) (Grant DUE-1044294

Systemic insulin sensitivity is regulated by GPS2 inhibition of AKT ubiquitination and activation in adipose tissue

OBJECTIVE: Insulin signaling plays a unique role in the regulation of energy homeostasis and the impairment of insulin action is associated with altered lipid metabolism, obesity, and Type 2 Diabetes. The main aim of this study was to provide further insight into the regulatory mechanisms governing the insulin signaling pathway by investigating the role of non-proteolytic ubiquitination in insulin-mediated activation of AKT. METHODS: The molecular mechanism of AKT regulation through ubiquitination is first dissected in vitro in 3T3-L1 preadipocytes and then validated in vivo using mice with adipo-specific deletion of GPS2, an endogenous inhibitor of Ubc13 activity (GPS2-AKO mice). RESULTS: Our results indicate that K63 ubiquitination is a critical component of AKT activation in the insulin signaling pathway and that counter-regulation of this step is provided by GPS2 preventing AKT ubiquitination through inhibition of Ubc13 enzymatic activity. Removal of this negative checkpoint, through GPS2 downregulation or genetic deletion, results in sustained activation of insulin signaling both in vitro and in vivo. As a result, the balance between lipid accumulation and utilization is shifted toward storage in the adipose tissue and GPS2-AKO mice become obese under normal laboratory chow diet. However, the adipose tissue of GPS2-AKO mice is not inflamed, the levels of circulating adiponectin are elevated, and systemic insulin sensitivity is overall improved. CONCLUSIONS: Our findings characterize a novel layer of regulation of the insulin signaling pathway based on non-proteolytic ubiquitination of AKT and define GPS2 as a previously unrecognized component of the insulin signaling cascade. In accordance with this role, we have shown that GPS2 presence in adipocytes modulates systemic metabolism by restricting the activation of insulin signaling during the fasted state, whereas in absence of GPS2, the adipose tissue is more efficient at lipid storage, and obesity becomes uncoupled from inflammation and insulin resistance

Galaxy Zoo: Are Bars Responsible for the Feeding of Active Galactic Nuclei at 0.2 < z < 1.0?

We present a new study investigating whether active galactic nuclei (AGN) beyond the local universe are preferentially fed via large-scale bars. Our investigation combines data from Chandra and Galaxy Zoo: Hubble (GZH) in the AEGIS, COSMOS, and GOODS-S surveys to create samples of face-on, disc galaxies at 0.2 < z < 1.0. We use a novel method to robustly compare a sample of 120 AGN host galaxies, defined to have 10^42 erg/s < L_X < 10^44 erg/s, with inactive control galaxies matched in stellar mass, rest-frame colour, size, Sersic index, and redshift. Using the GZH bar classifications of each sample, we demonstrate that AGN hosts show no statistically significant enhancement in bar fraction or average bar likelihood compared to closely-matched inactive galaxies. In detail, we find that the AGN bar fraction cannot be enhanced above the control bar fraction by more than a factor of two, at 99.7% confidence. We similarly find no significant difference in the AGN fraction among barred and non-barred galaxies. Thus we find no compelling evidence that large-scale bars directly fuel AGN at 0.2<z<1.0. This result, coupled with previous results at z=0, implies that moderate-luminosity AGN have not been preferentially fed by large-scale bars since z=1. Furthermore, given the low bar fractions at z>1, our findings suggest that large-scale bars have likely never directly been a dominant fueling mechanism for supermassive black hole growth.Comment: 13 pages, 5 figures, 2 tables, accepted by MNRA

Stellar populations of barred quiescent galaxies

International audienceSelecting centrally quiescent galaxies from the Sloan Digital Sky Survey (SDSS) to create high signal-to-noise ratio (greater than or similar to 100 angstrom(-1)) stacked spectra with minimal emission-line contamination, we accurately and precisely model the central stellar populations of barred and unbarred quiescent disk galaxies. By splitting our sample by redshift, we can use the fixed size of the SDSS fiber to model the stellar populations at different radii within galaxies. At 0.02 \textless z \textless 0.04, the SDSS fiber radius corresponds to approximate to 1 kpc, which is the typical half-light radii of both classical bulges and disky pseudobulges. Assuming that the SDSS fiber primarily covers the bulges at these redshifts, our analysis shows that there are no significant differences in the stellar populations, i.e., stellar age, [Fe/H], [Mg/Fe], and [N/Fe], of the bulges of barred versus unbarred quiescent disk galaxies. Modeling the stellar populations at different redshift intervals from z = 0.020 to z = 0.085 at fixed stellar masses produces an estimate of the stellar population gradients out to about half the typical effective radius of our sample, assuming null evolution over this approximate to 1 Gyr epoch. We find that there are no noticeable differences in the slopes of the azimuthally averaged gradients of barred versus unbarred quiescent disk galaxies. These results suggest that bars are not a strong influence on the chemical evolution of quiescent disk galaxies

The ~0.9 mJy sample: A mid-infrared spectroscopic catalog of 150 infrared-luminous, 24 micron selected galaxies at 0.3<z<3.5

We present a catalog of mid-infrared (MIR) spectra of 150 infrared (IR) luminous galaxies in the Spitzer extragalactic first look survey obtained with IRS on board Spitzer. The sample is selected to be brighter than ~0.9 mJy at 24 micron and it has a z distribution in the range [0.3,3.5] with a peak at z=1. It primarily comprises ultraluminous IR galaxies at z>1 and luminous IR galaxies at z<1, as estimated from their monochromatic 14 micron luminosities. The number of sources with spectra that are dominated by an active galactic nucleus (AGN) continuum is 49, while 39 sources have strong, star-formation related features. For this classification, we used the equivalent width (EW) of the 11.3 micron polycyclic aromatic hydrocarbon (PAH) feature. Several intermediate/high z starbursts have higher PAH EW than local ULIRGs. An increase in the AGN activity is observed with increasing z and luminosity, based on the decreasing EW of PAHs and the increasing [NeIII]/[NeII] ratio. Spectral stacking leads to the detection of the 3.3 micron PAH, the H2 0-0 S(1) and S(3) lines, and the [NeV] line. We observe differences in the flux ratios of PAHs in the stacked spectra of IR-luminous galaxies with z or luminosity, which are not due to extinction effects. When placing the observed galaxies on IR color-color diagrams, we find that the wedge defining AGN comprises most sources with continuum-dominated spectra, but also contains many starbursts. The comparison of the 11.3 micron PAH EW and the H-band effective radius, measured from HST data, indicates that sources with EW>2 micron, are typically more extended than ~3 kpc. However, there is no strong correlation between the MIR spectral type and the near-IR extent of the sources. [Abridged].Comment: accepted for publication in the Astrophysical Journa