Investigation of long-lived eddies on Jupiter

Quasi-geostrophic, two layer models of the Jovian atmosphere are under development; these may be used to simulate eddy phemonena in the atmosphere and include tracer dynamics explicitly. The models permit the investigation of the dynamics of quasi-geostrophic eddies under more controlled conditions than are possible in the laboratory. They can also be used to predict the distribution and behavior of tracer species, and hence to discriminate between different models of the mechanisms forcing the eddies, provided suitable observations can be obtained. At the same time, observational strategies are being developed for the Near Infrared Mapping Spectrometer on the Galileo Orbiter, with the objective of obtaining composition measurements for comparison with the models. Maps of features at thermal infrared wavelengths near 5 micron and reflected sunlight maps as a function of wavelength and phase angle will be obtained. These should provide further useful information on the morphology, composition and microstructure of clouds within eddy features. Equilibrium chemistry models which incorporate advection may then be used to relate these results of the dynamical models and provide addtional means of classifying different types of eddies

Laboratory Characterization and Astrophysical Detection of Vibrationally Excited States of Vinyl Cyanide in Orion-KL

New laboratory data of CH$_2$CHCN (vinyl cyanide) in its ground and vibrationally excited states at the microwave to THz domain allow searching for these excited state transitions in the Orion-KL line survey. Frequency-modulated spectrometers combined into a single broadband 50-1900 GHz spectrum provided measurements of CH$_2$CHCN covering a spectral range of 18-1893 GHz, whose assignments was confirmed by Stark modulation spectra in the 18-40 GHz region and by ab-initio anharmonic force field calculations. For analyzing the emission lines of CH$_2$CHCN species detected in Orion-KL we used the excitation and radiative transfer code (MADEX) at LTE conditions. The rotational transitions of the ground state of this molecule emerge from four cloud components of hot core nature which trace the physical and chemical conditions of high mass star forming regions in the Orion-KL Nebula. The total column density of CH$_2$CHCN in the ground state is (3.0$\pm$0.9)x10$^{15}$ cm$^{-2}$. We report on the first interstellar detection of transitions in the v10=1/(v11=1,v15=1) dyad in space, and in the v11=2 and v11=3 states in Orion-KL. The lowest energy vibrationally excited states of vinyl cyanide such as v11=1 (at 328.5 K), v15=1 (at 478.6 K), v11=2 (at 657.8 K), the v10=1/(v11=1,v15=1) dyad (at 806.4/809.9 K), and v11=3 (at 987.9 K) are populated under warm and dense conditions, so they probe the hottest parts of the Orion-KL source. Column density and rotational and vibrational temperatures for CH$_2$CHCN in their ground and excited states, as well as for the isotopologues, have been constrained by means of a sample of more than 1000 lines in this survey. Moreover, we present the detection of methyl isocyanide (CH$_3$NC) for the first time in Orion-KL and a tentative detection of vinyl isocyanide (CH$_2$CHNC) and give column density ratios between the cyanide and isocyanide isomers.Comment: 46 pages, 22 figures, 14 tables, 9 online table

The precise structures and stereochemistry of trihydroxy-linoleates esterified in human and porcine epidermis and their significance in skin barrier function: Implication of an epoxide hydrolase in the transformations of linoleate

Creation of an intact skin water barrier, a prerequisite for life on dry land, requires the lipoxygenase-catalyzed oxidation of the essential fatty acid linoleate, which is esterified to the ω-hydroxyl of an epidermis-specific ceramide. Oxidation of the linoleate moiety by lipoxygenases is proposed to facilitate enzymatic cleavage of the ester bond, releasing free ω-hydroxyceramide for covalent binding to protein, thus forming the corneocyte lipid envelope, a key component of the epidermal barrier. Herein, we report the transformations of esterified linoleate proceed beyond the initial steps of oxidation and epoxyalcohol synthesis catalyzed by the consecutive actions of 12R-LOX and epidermal LOX3. The major end product in human and porcine epidermis is a trihydroxy derivative, formed with a specificity that implicates participation of an epoxide hydrolase in converting epoxyalcohol to triol. Of the 16 possible triols arising from hydrolysis of 9,10-epoxy-13-hydroxy-octadecenoates, using LC-MS and chiral analyses, we identify and quantify specifically 9R,10S,13R-trihydroxy-11E-octadecenoate as the single major triol esterified in porcine epidermis and the same isomer with lesser amounts of its 10R diastereomer in human epidermis. The 9R,10S,13R-triol is formed by SN2 hydrolysis of the 9R,10R-epoxy-13R-hydroxy-octadecenoate product of the LOX enzymes, a reaction specificity characteristic of epoxide hydrolase. The high polarity of triol over the primary linoleate products enhances the concept that the oxidations disrupt corneocyte membrane lipids, promoting release of free ω-hydroxyceramide for covalent binding to protein and sealing of the waterproof barrier

The Exomars Climate Sounder (EMCS) Investigation

The ExoMars Climate Sounder (EMCS) investigation is developed at the Jet Propulsion Laboratory (Principal Investigator J. T. Schofield) in collaboration with an international scientific team from France, the United Kingdom and the USA. EMCS plans to map daily, global, pole-to-pole profiles of temperature, dust, water and CO2 ices, and water vapor from the proposed 2016 ExoMars Trace Gas Orbiter (EMTGO). These profiles are to be assimilated into Mars General Circulation Models (MGCMs) to generate global, interpolated fields of measured and derived parameters such as wind

Observations of the martian atmosphere with the mars climate sounder

The Mars Climate Sounder (MCS) has obtained measurements of the Martian atmosphere for one Mars year. Onboard the Mars Reconnaissance Orbiter (MRO), MCS continues to acquire high vertical resolution profiles of temperature, dust, condensates of CO2 and H2O, and water vapor by observing the limb of the atmosphere from the surface to 80 km in the spectral intervals 0.3 – 3 ?m and 11.5 – 45 ?m [1]. This paper describes the investigation and introduces some of the observations being studied by the MCS science team. Other presentations by the team at this workshop will describe in greater detail results of ongoing research using MCS data

Seismic Coupling of Short-Period Wind Noise Through Mars’ Regolith for NASA’s InSight Lander

NASA’s InSight lander will deploy a tripod-mounted seismometer package onto the surface of Mars in late 2018. Mars is expected to have lower seismic activity than the Earth, so minimisation of environmental seismic noise will be critical for maximising observations of seismicity and scientific return from the mission. Therefore, the seismometers will be protected by a Wind and Thermal Shield (WTS), also mounted on a tripod. Nevertheless, wind impinging on the WTS will cause vibration noise, which will be transmitted to the seismometers through the regolith (soil). Here we use a 1:1-scale model of the seismometer and WTS, combined with field testing at two analogue sites in Iceland, to determine the transfer coefficient between the two tripods and quantify the proportion of WTS vibration noise transmitted through the regolith to the seismometers. The analogue sites had median grain sizes in the range 0.3–1.0 mm, surface densities of 1.3-1.8 gcm−3, and an effective regolith Young’s modulus of 2.5+1.9−1.4 MPa. At a seismic frequency of 5 Hz the measured transfer coefficients had values of 0.02–0.04 for the vertical component and 0.01–0.02 for the horizontal component. These values are 3–6 times lower than predicted by elastic theory and imply that at short periods the regolith displays significant anelastic behaviour. This will result in reduced short-period wind noise and increased signal-to-noise. We predict the noise induced by turbulent aerodynamic lift on the WTS at 5 Hz to be ∼2×10−10 ms−2 Hz−1/2 with a factor of 10 uncertainty. This is at least an order of magnitude lower than the InSight short-period seismometer noise floor of 10−8 ms−2 Hz−1/2

Queering the grammar school boy: class, sexuality and authenticity in the works of Colin MacInnes and Ray Gosling

In 1959 Colin MacInnes published the fourth in his series of social issue novels, Absolute Beginners. In it the unnamed protagonist is constructed as the iconic teenager, slick, cool, creative, with his ex-lover Crépe Suzette as the object of his art and as his Achilles heel. The novel is framed over one summer, against a backdrop of racial tension, which ultimately led the Boy towards adulthood. MacInnes’s protagonist has been dismissed as an emblem rather than a character, and MacInnes himself derided by George Melly as a perpetual teenager. However in this chapter, we will suggest that taken as a whole MacInnes’ work constructs a complex understanding of The Boy’s political possibilities intersecting with sexuality, gender, race and class. By integrating his novelistic work with his journalistic and activist writing, we will demonstrate the complexity of MacInnes’ Boy as an autonomous, queer political agent, embodied in the ultimate Boy; Ray Gosling. Gosling’s own writing becomes a lens through which to root historical understanding of teenagers and teenage cultures as sexual and racial constructs