4,258 research outputs found
Near-arcsecond resolution observations of the hot corino of the solar type protostar IRAS 16293-2422
Complex organic molecules have previously been discovered in solar type
protostars, raising the questions of where and how they form in the envelope.
Possible formation mechanisms include grain mantle evaporation, interaction of
the outflow with its surroundings or the impact of UV/X-rays inside the
cavities. In this Letter we present the first interferometric observations of
two complex molecules, CH3CN and HCOOCH3, towards the solar type protostar
IRAS16293-2422. The images show that the emission originates from two compact
regions centered on the two components of the binary system. We discuss how
these results favor the grain mantle evaporation scenario and we investigate
the implications of these observations for the chemical composition and
physical and dynamical state of the two components.Comment: 5 pages (apjemulate), 2 figures; accepted by ApJ
Molecular ions in the protostellar shock L1157-B1
We perform a complete census of molecular ions with an abundance larger than
1e-10 in the protostellar shock L1157-B1 by means of an unbiased
high-sensitivity survey obtained with the IRAM-30m and Herschel/HIFI. By means
of an LVG radiative transfer code the gas physical conditions and fractional
abundances of molecular ions are derived. The latter are compared with
estimates of steady-state abundances in the cloud and their evolution in the
shock calculated with the chemical model Astrochem. We detect emission from
HCO+, H13CO+, N2H+, HCS+, and, for the first time in a shock, from HOCO+, and
SO+. The bulk of the emission peaks at blueshifted velocity, ~ 0.5-3 km/s with
respect to systemic, has a width of ~ 4-8 km/s, and is associated with the
outflow cavities (T_kin ~ 20-70 K, n(H2) ~ 1e5 cm-3). Observed HCO+ and N2H+
abundances are in agreement with steady-state abundances in the cloud and with
their evolution in the compressed and heated gas in the shock for cosmic rays
ionization rate Z = 3e-16 s-1. HOCO+, SO+, and HCS+ observed abundances,
instead, are 1-2 orders of magnitude larger than predicted in the cloud; on the
other hand they are strongly enhanced on timescales shorter than the shock age
(~2000 years) if CO2, S or H2S, and OCS are sputtered off the dust grains in
the shock. The performed analysis indicates that HCO+ and N2H+ are a fossil
record of pre-shock gas in the outflow cavity, while HOCO+, SO+, and HCS+ are
effective shock tracers and can be used to infer the amount of CO2 and
sulphur-bearing species released from dust mantles in the shock. The observed
HCS+ (and CS) abundance indicates that OCS should be one of the main sulphur
carrier on grain mantles. However, the OCS abundance required to fit the
observations is 1-2 orders of magnitude larger than observed. Further studies
are required to fully understand the chemistry of sulphur-bearing species.Comment: 12 pages, 5 figures, accepted by A&
First detection of triply-deuterated methanol
We report the first detection of triply-deuterated methanol, with 12 observed
transitions, towards the low-mass protostar IRAS 16293-2422, as well as
multifrequency observations of 13CH3OH, used to derive the column density of
the main isotopomer CH3OH. The derived fractionation ratio [CD3OH]/[CH3OH]
averaged on a 10'' beam is 1.4%. Together with previous CH2DOH and CHD2OH
observations, the present CD3OH observations are consistent with a formation of
methanol on grain surfaces, if the atomic D/H ratio is 0.1 to 0.3 in the
accreting gas. Such a high atomic ratio can be reached in the frame of
gas-phase chemical models including all deuterated isotopomers of H3+.Comment: Accepted by A&
Heavy water around the L1448-mm protostar
Context: L1448-mm is the prototype of a low-mass Class 0 protostar driving a
high-velocity jet. Given its bright H2O spectra observed with ISO, L1448-mm is
an ideal laboratory to observe heavy water (HDO) emission. Aims: Our aim is to
image the HDO emission in the protostar surroundings, the possible occurrence
of HDO emission also investigating off L1448-mm, towards the molecular outflow.
Methods: We carried out observations of L1448-mm in the HDO(1_10-1_11) line at
80.6 GHz, an excellent tracer of HDO column density, with the IRAM Plateau de
Bure Interferometer. Results: We image for the first time HDO emission around
L1448-mm. The HDO structure reveals a main clump at velocities close to the
ambient one towards the the continuum peak that is caused by the dust heated by
the protostar. In addition, the HDO map shows tentative weaker emission at
about 2000 AU from the protostar towards the south, which is possibly
associated with the walls of the outflow cavity opened by the protostellar
wind. Conclusions: Using an LVG code, modelling the density and temperature
profile of the hot-corino, and adopting a gas temperature of 100 K and a
density of 1.5 10^8 cm^-3, we derive a beam diluted HDO column density of about
7 10^13 cm^-2, corresponding to a HDO abundance of about 4 10^-7. In addition,
the present map supports the scenario where HDO can be efficiently produced in
shocked regions and not uniquely in hot corinos heated by the newly born star.Comment: Accepted by A&A as Letter; 5 pages, 3 figure
Sulphur-bearing species in the star forming region L1689N
We report observations of the expected main S-bearing species (SO, SO2 and
H2S) in the low-mass star forming region L1689N. We obtained large scale
(~300''x200'') maps of several transitions from these molecules with the goal
to study the sulphur chemistry, i.e. how the relative abundances change in the
different physical conditions found in L1689N. We identified eight interesting
regions, where we carried out a quantitative comparative study: the molecular
cloud (as reference position), five shocked regions caused by the interaction
of the molecular outflows with the cloud, and the two protostars IRAS16293-2422
and 16293E. In the cloud we carefully computed the gas temperature and density
by means of a non-LTE LVG code, while in other regions we used previous
results. We hence derived the column density of SO, SO2 and H2S, together with
SiO and H2CO - which were observed previously - and their relevant abundance
ratios. We find that SiO is the molecule that shows the largest abundance
variations in the shocked regions, whereas S-bearing molecules show more
moderate variations. Remarkably, the region of the brightest SiO emission in
L1689N is undetected in SO2, H2S and H2CO and only marginally detected in SO.
In the other weaker SiO shocks, SO2 is enhanced with respect to SO. We propose
a schema in which the different molecular ratios correspond to different ages
of the shocks. Finally, we find that SO, SO2 and H2S have significant abundance
jumps in the inner hot core of IRAS16293-2422 and discuss the implications of
the measured abundances.Comment: Accepted 08/10/0
The L1157-B1 astrochemical laboratory: testing the origin of DCN
L1157-B1 is the brightest shocked region of the large-scale molecular
outflow, considered the prototype of chemically rich outflows, being the ideal
laboratory to study how shocks affect the molecular gas. Several deuterated
molecules have been previously detected with the IRAM 30m, most of them formed
on grain mantles and then released into the gas phase due to the shock. We aim
to observationally investigate the role of the different chemical processes at
work that lead to formation the of DCN and test the predictions of the chemical
models for its formation. We performed high-angular resolution observations
with NOEMA of the DCN(2-1) and H13CN(2-1) lines to compute the deuterated
fraction, Dfrac(HCN). We detected emission of DCN(2-1) and H13CN(2-1) arising
from L1157-B1 shock. Dfrac(HCN) is ~4x10 and given the uncertainties, we
did not find significant variations across the bow-shock. Contrary to HDCO,
whose emission delineates the region of impact between the jet and the ambient
material, DCN is more widespread and not limited to the impact region. This is
consistent with the idea that gas-phase chemistry is playing a major role in
the deuteration of HCN in the head of the bow-shock, where HDCO is undetected
as it is a product of grain-surface chemistry. The spectra of DCN and H13CN
match the spectral signature of the outflow cavity walls, suggesting that their
emission result from shocked gas. The analysis of the time dependent gas-grain
chemical model UCL-CHEM coupled with a C-type shock model shows that the
observed Dfrac(HCN) is reached during the post-shock phase, matching the
dynamical timescale of the shock. Our results indicate that the presence of DCN
in L1157-B1 is a combination of gas-phase chemistry that produces the
widespread DCN emission, dominating in the head of the bow-shock, and
sputtering from grain mantles toward the jet impact region.Comment: Accepted for publication in A&A. 7 pages, 5 Figures, 1 Tabl
Constraining the abundances of complex organics in the inner regions of solar-type protostars
The high abundances of Complex Organic Molecules (COMs) with respect to
methanol, the most abundant COM, detected towards low-mass protostars, tend to
be underpredicted by astrochemical models. This discrepancy might come from the
large beam of the single-dish telescopes, encompassing several components of
the studied protostar, commonly used to detect COMs. To address this issue, we
have carried out multi-line observations of methanol and several COMs towards
the two low-mass protostars NGC1333-IRAS2A and -IRAS4A with the Plateau de Bure
interferometer at an angular resolution of 2 arcsec, resulting in the first
multi-line detection of the O-bearing species glycolaldehyde and ethanol and of
the N-bearing species ethyl cyanide towards low-mass protostars other than IRAS
16293. The high number of detected transitions from COMs (more than 40 methanol
transitions for instance) allowed us to accurately derive the source size of
their emission and the COMs column densities. The COMs abundances with respect
to methanol derived towards IRAS2A and IRAS4A are slightly, but not
substantitally, lower than those derived from previous single-dish
observations. The COMs abundance ratios do not vary significantly with the
protostellar luminosity, over five orders of magnitude, implying that low-mass
hot corinos are quite chemically rich as high-mass hot cores. Astrochemical
models still underpredict the abundances of key COMs, such as methyl formate or
di-methyl ether, suggesting that our understanding of their formation remains
incomplete.Comment: 60 pages, 10 figures, 17 tables. Accepted for publication in Ap
Gas phase formation of the prebiotic molecule formamide: insights from new quantum computations
New insights into the formation of interstellar formamide, a species of great
relevance in prebiotic chemistry, are provided by electronic structure and
kinetic calculations for the reaction NH2 + H2CO -> NH2CHO + H. Contrarily to
what previously suggested, this reaction is essentially barrierless and can,
therefore, occur under the low temperature conditions of interstellar objects
thus providing a facile formation route of formamide. The rate coefficient
parameters for the reaction channel leading to NH2CHO + H have been calculated
to be A = 2.6x10^{-12} cm^3 s^{-1}, beta = -2.1 and gamma = 26.9 K in the range
of temperatures 10-300 K. Including these new kinetic data in a refined
astrochemical model, we show that the proposed mechanism can well reproduce the
abundances of formamide observed in two very different interstellar objects:
the cold envelope of the Sun-like protostar IRAS16293-2422 and the molecular
shock L1157-B2. Therefore, the major conclusion of this Letter is that there is
no need to invoke grain-surface chemistry to explain the presence of formamide
provided that its precursors, NH2 and H2CO, are available in the gas-phase.Comment: MNRAS Letters, in pres
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ISO Detection of CO<sup>+</sup> toward the protostar IRAS 16293-2422
In this letter we report the detection of eight high-N rotational transitions of CO+ towards a low mass protostar, IRAS 16293-2422. The source was observed with the Long Wavelength Spectrometer on board the Infrared Space Observatory. This is the first time that CO+ has been detected in a low luminosity source and the first time that high-N lines have been detected in any source. The detection of these lines was not predicted by models and consequently, their interpretation is a challenge. We discuss the possibility that the observed CO+ emission originates in the dense inner regions illuminated by the UV field created in the accretion shock (formed by infalling material), and conclude that this is an improbable explanation. We have also considered the possibility that a strong, dissociative J-shock at ~ 500 AU from the star is the origin of the CO+ emission. This model predicts CO+ column densities in rough agreement with the observations if the magnetic field is ~ 1 mG and the shock velocity is 100 km s-1
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