Isotopic and spin selectivity of H_2 adsorbed in bundles of carbon nanotubes

Due to its large surface area and strongly attractive potential, a bundle of carbon nanotubes is an ideal substrate material for gas storage. In addition, adsorption in nanotubes can be exploited in order to separate the components of a mixture. In this paper, we investigate the preferential adsorption of D_2 versus H_2(isotope selectivity) and of ortho versus para(spin selectivity) molecules confined in the one-dimensional grooves and interstitial channels of carbon nanotube bundles. We perform selectivity calculations in the low coverage regime, neglecting interactions between adsorbate molecules. We find substantial spin selectivity for a range of temperatures up to 100 K, and even greater isotope selectivity for an extended range of temperatures,up to 300 K. This isotope selectivity is consistent with recent experimental data, which exhibit a large difference between the isosteric heats of D_2 and H_2 adsorbed in these bundles.Comment: Paper submitted to Phys.Rev. B; 17 pages, 2 tables, 6 figure

Cnidarians as a Source of New Marine Bioactive Compounds—An Overview of the Last Decade and Future Steps for Bioprospecting

Marine invertebrates are rich sources of bioactive compounds and their biotechnological potential attracts scientific and economic interest worldwide. Although sponges are the foremost providers of marine bioactive compounds, cnidarians are also being studied with promising results. This diverse group of marine invertebrates includes over 11,000 species, 7500 of them belonging to the class Anthozoa. We present an overview of some of the most promising marine bioactive compounds from a therapeutic point of view isolated from cnidarians in the first decade of the 21st century. Anthozoan orders Alcyonacea and Gorgonacea exhibit by far the highest number of species yielding promising compounds. Antitumor activity has been the major area of interest in the screening of cnidarian compounds, the most promising ones being terpenoids (monoterpenoids, diterpenoids, sesquiterpenoids). We also discuss the future of bioprospecting for new marine bioactive compounds produced by cnidarians

Omnivoria e repartição de recursos em águas pobres em nutrientes da Bacia do Rio Negro

Amazonian biodiversity is notorious, this is also valid for the fauna of the mineral-deficient waters of the Rio Negro System. Some 25 years of research on the benthic fauna of Central Amazonian streams resulted in species-rich foodwebs with a high degree of omnivory within dense animal communities. To exemplify the taxonomic range of omnivorous consumers, the detailed resource spectra of 18 consumer species, including Protozoa (2 species), Platyhelminthes (1 species), insects (2 species), fish (6 species) and shrimps (Decapoda, 7 species), associated primarily with the benthic habitats of Rio Negro tributaries, are presented. Special features of omnivory are characterized, and the importance of litter-decomposing fungi as essential energy input into the foodwebs is documented. It is shown that general omnivory -diverse omnivore consumers sharing most of the resource types- is a prevalent feature. The relevance of this general omnivory for the maintenance of biodiversity is discussed.A biodiversidade do Amazonas é notório e isto também é válido para as águas pobres em nutrientes da bacia do Rio Negro. Uma pesquisa de 25 anos da fauna béntica de igarapés da Amazônia Central resultou em redes alimentares caraterizadas por alta diversidade de espécies, por intensa omnivoria e por alta densidade populacional. Para demonstrar a generalidade taxonômica de omnivoria no bentos dos igarapés, são apresentados as listas de presas / recursos de 18 espécies de consumidores, sendo Protozoa (2 epécies), Platyhelminthes (1 espécie), insetos (2 espécies), peixes (6 espécies) e camarões (Decapoda, 7 espécies). Diferentes categorias de omnivoria são apresentados, e a importância de fungos decompositores da liteira submersa como input básico de energia nas redes alimentares é demonstrada. É prevalente a omnivoria geral, sendo que as diferentes espécies omnívoros estão utilizando os mesmos recursos. Considera- se a relevância desta omnivoria geral para a manutenção da biodiversidade

Acid inputs from the atmosphere in the United Kingdom.

Inputs of acidity to the ground arise through two distinct routes: wet deposition which includes all acidity deposited in rain and snow and dry deposition, the direct sorption of SO2, NO2 or HNO3 gases by vegetation or soil surfaces. The acidity from dry deposition of SO2 and NO2 is created during the oxidation of deposited SO2 and NO2 to SO24 and NO3− respectively. The areas of Britain experiencing the largest wet deposition of acidity are the high rainfall areas of the west and north, in particular the west central highlands of Scotland, Galloway and Cumbria where inputs exceed 1 kp H+ ha−1 annually. Wet deposited acidity in the east coast regions of Britain is in the range 0.3–0.6 kg H+ ha−1 a−1. Monitoring data for rainfall acidity at rural sites throughout northern Britain show a decline in deposited acidity of about 50% during the last six years. Dry deposition is largest in the industrial midlands and southeast England and in the central lowlands of Scotland, where concentrations of SO2 are largest. In these regions the dry deposition of SO2 following oxidation may lead to acid inputs approaching 3 kg H+ ha−1 a−1 and greatly exceeding wet deposition

Narrow-line region gas kinematics of 24 264 optically selected AGN: the radio connection

Using a sample of 24 264 optically selected active galactic nuclei (AGNs) from the SDSS DR7 data base, we characterize how the profile of the [O III] λ5007 emission line relates to bolometric luminosity (LAGN), Eddington ratio, radio loudness, radio luminosity (L1.4 GHz) and optical class (i.e. broad/narrow-line Seyfert 1, type 2) to determine what drives the kinematics of this kpc-scale line emitting gas. First, we use spectral stacking to characterize how the average [O III] λ5007 profile changes as a function of these five variables. After accounting for the known correlation between LAGN and L1.4 GHz, we report that L1.4 GHz has the strongest influence on the [O III] λ5007 profile, with AGNs of moderate radio luminosity (L1.4 GHz = 1023–1025 W Hz−1) having the broadest [O III] λ5007 profiles. Conversely, we find only a modest change in the [O III] λ5007 profile with increasing radio loudness and find no significant difference between the [O III] λ5007 profiles of broad- and narrow-line Seyfert 1s. When binned according to Eddington ratio, only the AGNs in our highest bin (i.e. >0.3) show any signs of having broadened [O III] λ5007 profiles, although the small numbers of such extreme AGNs in our sample mean we cannot rule out that other processes (e.g. radio jets) are responsible for this broadening. The [O III] λ5007 profiles of type 1 and type 2 AGNs show the same trends in terms of line width, but type 1 AGNs display a much stronger ‘blue wing’, which we interpret as evidence of outflowing ionized gas. We perform multicomponent fitting to the Hβ, [O III] λλ4959, 5007, [N II] λλ6548, 6584 and Hα lines for all the AGNs in our sample to calculate the proportions of AGNs with broad [O III] λ5007 profiles. The individual fits confirm the results from our stacked spectra; AGNs with L1.4 GHz > 1023 W Hz−1 are roughly five times more likely to have extremely broad [O III] λ5007 lines (full width at half-maximum, FWHMAvg > 1000 km s−1) compared to lower L1.4 GHz AGNs, and the width of the [O III] λ5007 line peaks in moderate-radio-luminosity AGNs (L1.4 GHz ∼ 1024 W Hz−1). Our results are consistent with the most disturbed gas kinematics being induced by compact radio cores (rather than powerful radio jets), although broadened [O III] λ5007 lines are also present, but much rarer, in low-L1.4 GHz systems. Our catalogue of multicomponent fits is freely available as an online resource for statistical studies of the kinematics and luminosities of the narrow- and broad-line AGN regions and the identification of potential targets for follow-up observations at http://sites.google.com/site/sdssalpaka

A Connection between Obscuration and Star Formation in Luminous Quasars

We present a measurement of the star formation properties of a uniform sample of mid-IR-selected, optically unobscured, and obscured quasars (QSO1s and QSO2s) in the Boötes survey region. We use a spectral energy distribution analysis for photometric data spanning optical to far-IR wavelengths to separate the active galactic nucleus (AGN) and host galaxy components. We find that when compared to a matched sample of QSO1s, the QSO2s have roughly twice the far-IR detection fractions, far-IR fluxes, and infrared star formation luminosities ($L_{{\rm IR}}^{{\rm SF}}$). Correspondingly, we show that the AGN obscured fraction rises from 0.3 to 0.7 between (4–40) × ${{10}^{11}}{{L}_{\odot }}$. We also find evidence associating X-ray absorption with the presence of far-IR-emitting dust. Overall, these results are consistent with galaxy evolution models in which quasar obscuration is associated with dust-enshrouded starburst galaxies