Did transit through the galactic spiral arms seed crust production on the early Earth?

Although there is evidence for periodic geological perturbations driven by regular or semi-regular extra-terrestrial bombardment, the production of Earth’s continental crust is generally regarded as a function of planetary differentiation driven by internal processes. We report time series analysis of the Hf isotopic composition of zircon grains from the North Atlantic and Pilbara cratons, the archetypes of Archean plate tectonic and non-plate tectonic settings, respectively. An ~170–200 m.y. frequency is recognized in both cratons that matches the transit of the solar system through the galactic spiral arms, where the density of stars is high. An increase in stellar density is consistent with an enhanced rate of Earth bombardment by comets, the larger of which would have initiated crustal nuclei production via impact-driven decompression melting of the mantle. Hence, the production and preservation of continental crust on the early Earth may have been fundamentally influenced by exogenous processes. A test of this model using oxygen isotopes in zircon from the Pilbara craton reveals correlations between crust with anomalously light isotopic signatures and exit from the Perseus spiral arm and entry into the Norma spiral arm, the latter of which matches the known age of terrestrial spherule beds. Our data support bolide impact, which promoted the growth of crustal nuclei, on solar system transit into and out of the galactic spiral arms

Assessing the mechanisms of common Pb incorporation into titanite

Common Pb, the portion of non-radiogenic Pb within a U bearing mineral, needs to be accurately accounted for in order to subtract its effect on U-Pb isotopic ratios so that meaningful ages can be calculated. The propensity to accommodate common Pb during crystallization, or later, is different across the range of U bearing minerals used for geochronology. Titanite frequently accommodates significant amounts of common Pb. However, the most appropriate method to correct for this requires knowledge on the mechanism and timing of common Pb incorporation; information that is commonly difficult to extract. In this study, the spatial and compositional distribution of trace elements (including Pb) in metamorphic titanites from a Greenland amphibolite is investigated on the grain- to nano-scale. Titanites have an isotopically similar signature for both common and radiogenic-Pb in all grains but significantly different quantities of the non-radiogenic component. Microstructural and compositional examination of these grains reveals undeformed, but high common Pb (F207%) titanites have homogeneous element distributions on the atomic scale suggesting common Pb is incorporated into titanite during its growth and not during later processes. In contrast, deformed titanite comprising low-angle boundaries, formed by subgrain rotation recrystallization, comprise networks of dislocations that are enriched in Mg, Al, K and Fe. Smaller cations may migrate due to elastic strain in the vicinity of the dislocation network, yet the larger K cations more likely reflect the mobility of externally-derived K along the orien tation interface. The absence of Pb enrichment along the boundary indicates that either Pb was too large to fit into migrating lattice dislocations or static low-angle boundaries and/or that there was no external Pb available to diffuse along the grain boundary. As the common Pb composition is distinctly different to regional Pb models, the metamorphic titanite grew in a homogeneous Pb reservoir dominated by the break-down of precursor U-bearing phases. The different quantity of common Pb in the titanite grains indicates a mineral-driven element partitioning in an isotopically homogeneous metamorphic reservoir, consistent with low U, low total REE and flat LREE signatures in high F207% analyses. These results have implications for the selection of appropriate common Pb corrections in titanite and other accessory phases

Petrogenesis and Ni-Cu sulphide potential of mafic-ultramafic rocks in the Mesoproterozoic Fraser Zone within the Albany-Fraser Orogen, Western Australia

The Albany Fraser Orogen is located along the southern and southeastern margins of the Archean Yilgarn Craton. The orogen formed during reworking of the Yilgarn Craton, along with variable additions of juvenile mantle material, from at least 1810 Ma to 1140 Ma. The Fraser Zone is a 425 km long and 50 km wide geophysically distinct belt near the northwestern edge of the orogen, hosting abundant sills of predominantly metagabbroic non-cumulate rocks, but including larger cumulate bodies, all emplaced at c. 1300 Ma. The gabbroic rocks are interpreted to have crystallised from a basaltic magma that had ∼8.8% MgO, 185 ppm Ni, 51 ppm Cu, and extremely low contents of platinum-group elements (PGE, <1 ppb). Levels of high field-strength elements (HFSE) in the least enriched rocks indicate that the magma was derived from a mantle source more depleted than a MORB source. Isotope and trace element systematics suggest that the magma was contaminated (εNd 0 to −2 throughout, La/Nb around 3) with small (<10%) amounts of crust before and during ascent and emplacement. Larger bodies of cumulate rocks show evidence for additional contamination, at the emplacement level, with country-rock metasedimentary rocks or their anatectic melts. The area has been the focus of considerable exploration for Ni–Cu sulphides following the discovery of the Nova deposit in 2012 in an intrusion consisting of olivine gabbronoritic, noritic and peridotitic cumulates, interlayered with metasedimentary rocks belonging to the Snowys Dam Formation of the Arid Basin. Disseminated sulphides from a drillcore intersecting the structurally upper portion of the intrusion, above the main ore zone, have tenors of ∼3–6.3% Ni, 1.8–6% Cu and mostly <500 ppb PGE, suggesting derivation from magma with the same composition as the regional Fraser Zone metagabbroic sills, at R factors of ∼1500. However, the Nova rocks tend to have higher εSr (38–52) and more variable δ34S (−2 to +4) than the regional metagabbros (εSr 17–32, δ34S around 0), consistent with the geochemical evidence for enhanced crustal assimilation of the metasedimentary country-rock in a relatively large magma staging chamber from which pulses of sulphide bearing, crystal-charged magmas were emplaced at slightly different crustal levels. Preliminary investigations suggest that the critical factors determining whether or not Fraser Zone mafic magmas are mineralised probably relate to local geodynamic conditions that allow large magma chambers to endure long enough to sequester country-rock sulphur

U-Th-Pb zircon geochronology on igneous rocks in the Toija and Salittu Formations, Orijärvi area, southwestern Finland: Constraints on the age of volcanism and metamorphism

Zircons from a felsic volcanic rock in the Toija Formation and a synvolcanic gabbro intrusion in the Salittu Formation within the Orijärvi area were dated by U-Th-Pb SIMS in order to provide depositional constraints on these formations. Zircon crystals from the felsic rock preserve a two-stage crystallisation history with zoned core domains and homogeneous rim domains. Inner domains yield a 1878 ± 4 Ma concordia age, interpreted to determine the crystallisation of this rock. Rims yield a 1815 ± 3 Ma concordia age interpreted to determine the regional metamorphism. Small rounded zircon grains from the Salittu gabbro, located within the Jyly shear zone, yield a concordia age of 1792 ± 5 Ma. We interpret the grain textures to suggest that they recrystallised from inherited zircon seeds during the heat and fluid flow into the shear zone. Although no direct ages for the Salittu Formation have been recovered, field relationships imply that it was deposited between 1878−1875 Ma