1,022 research outputs found
CO Infrared Phonon Modes in Interstellar Ice Mixtures
CO ice is an important reservoir of carbon and oxygen in star and planet
forming regions. Together with water and CO, CO sets the physical and
chemical characteristics of interstellar icy grain mantles, including
desorption and diffusion energies for other ice constituents. A detailed
understanding of CO ice spectroscopy is a prerequisite to characterize
CO interactions with other volatiles both in interstellar ices and in
laboratory experiments of interstellar ice analogs. We report laboratory
spectra of the CO longitudinal optical (LO) phonon mode in pure CO ice
and in CO ice mixtures with HO, CO, O components. We show that the
LO phonon mode position is sensitive to the mixing ratio of various ice
components of astronomical interest. In the era of JWST, this characteristic
could be used to constrain interstellar ice compositions and morphologies. More
immediately, LO phonon mode spectroscopy provides a sensitive probe of ice
mixing in the laboratory and should thus enable diffusion measurements with
higher precision than has been previously possible
CO diffusion and desorption kinetics in CO ices
Diffusion of species in icy dust grain mantles is a fundamental process that
shapes the chemistry of interstellar regions; yet measurements of diffusion in
interstellar ice analogs are scarce. Here we present measurements of CO
diffusion into CO ice at low temperatures (T=11--23~K) using CO
longitudinal optical (LO) phonon modes to monitor the level of mixing of
initially layered ices. We model the diffusion kinetics using Fick's second law
and find the temperature dependent diffusion coefficients are well fit by an
Arrhenius equation giving a diffusion barrier of 300 40 K. The low
barrier along with the diffusion kinetics through isotopically labeled layers
suggest that CO diffuses through CO along pore surfaces rather than through
bulk diffusion. In complementary experiments, we measure the desorption energy
of CO from CO ices deposited at 11-50 K by temperature-programmed
desorption (TPD) and find that the desorption barrier ranges from 1240 90
K to 1410 70 K depending on the CO deposition temperature and
resultant ice porosity. The measured CO-CO desorption barriers demonstrate
that CO binds equally well to CO and HO ices when both are compact. The
CO-CO diffusion-desorption barrier ratio ranges from 0.21-0.24 dependent on
the binding environment during diffusion. The diffusion-desorption ratio is
consistent with the above hypothesis that the observed diffusion is a surface
process and adds to previous experimental evidence on diffusion in water ice
that suggests surface diffusion is important to the mobility of molecules
within interstellar ices
Smart cities: A literature review and business network approach discussion on the management of organisations
Purpose: The smart city idea refers to new ways of organising city functions and urban life, which are believed to move production and consumption from global to local, manufacturing from competitive to collaborative, and business from a shareholder to a multiple-stakeholder point of view. Most previous research has focussed on the societal level of smart cities, while less seems to be known about the management of business as part of smart cities. The purpose of this paper is to present a literature review on the state of the art of management research on smart cities. The following research question is addressed: How has previous research captured the management of organisations in smart cities? Design/methodology/approach: A literature review using the search term “smart city/cities” in research on business, management, and operational management was conducted for the purpose of capturing previous research. Findings were coded based on main ideas, central concepts, and theories, thematic content of the articles related to the main ideas underpinning smart cities (digitalization, urbanisation, and sustainability as antecedents, and local, collaborative and multiple-stakeholder manufacturing as indicators), and units of analysis. Findings: The paper points to how most studies on the management of organisations as part of smart cities focus on sustainability and how digitalisation enables new businesses. Collaborative efforts are emphasised and the theoretical framing is fragmented. Issues related to the organising of business is also not problematised and the business network approach could, as discussed in the paper, provide valuable insights related to the collaborative efforts of organisations and the multiple-stakeholder perspective. Originality/value: The paper is the first to capture and present an overview of previous research on the management of business as part of smart cities. Research on smart cities has focussed on the policy and societal levels, and so far there is a lack of problematisation on how organisations may act, and potentially change their way of acting, should smart cities become a reality
Laboratory H2O:CO2 ice desorption data: entrapment dependencies and its parameterization with an extended three-phase model
Ice desorption affects the evolution of the gas-phase chemistry during the
protostellar stage, and also determines the chemical composition of comets
forming in circumstellar disks. From observations, most volatile species are
found in H2O-dominated ices. The aim of this study is first to experimentally
determine how entrapment of volatiles in H2O ice depends on ice thickness,
mixture ratio and heating rate, and second, to introduce an extended
three-phase model (gas, ice surface and ice mantle) to describe ice mixture
desorption with a minimum number of free parameters. Thermal H2O:CO2 ice
desorption is investigated in temperature programmed desorption experiments of
thin (10 - 40 ML) ice mixtures under ultra-high vacuum conditions. Desorption
is simultaneously monitored by mass spectrometry and reflection-absorption
infrared spectroscopy. The H2O:CO2 experiments are complemented with selected
H2O:CO, and H2O:CO2:CO experiments. The results are modeled with rate equations
that connect the gas, ice surface and ice mantle phases through surface
desorption and mantle-surface diffusion. The fraction of trapped CO2 increases
with ice thickness (10 - 32 ML) and H2O:CO2 mixing ratio (5:1 - 10:1), but not
with one order of magnitude different heating rates. The fraction of trapped
CO2 is 44 - 84 % with respect to the initial CO2 content for the investigated
experimental conditions. This is reproduced quantitatively by the extended
three-phase model that is introduced here. The H2O:CO and H2O:CO2:CO
experiments are consistent with the H2O:CO2 desorption trends, suggesting that
the model can be used for other ice species found in the interstellar medium to
significantly improve the parameterization of ice desorption.Comment: 12 pages, 9 figures, published in A&
DCO, DCN and ND reveal three different deuteration regimes in the disk around the Herbig Ae star HD163296
The formation pathways of deuterated species trace different regions of
protoplanetary disks and may shed light into their physical structure. We aim
to constrain the radial extent of main deuterated species; we are particularly
interested in spatially characterizing the high and low temperature pathways
for enhancing deuteration of these species. We observed the disk surrounding
the Herbig Ae star HD 163296 using ALMA in Band 6 and obtained resolved
spectral imaging data of DCO (=3-2), DCN (=3-2) and ND
(=3-2). We model the radial emission profiles of DCO, DCN and
ND, assuming their emission is optically thin, using a parametric model
of their abundances and radial excitation temperature estimates. DCO can be
described by a three-region model, with constant-abundance rings centered at 70
AU, 150 AU and 260 AU. The DCN radial profile peaks at about ~60 AU and
ND is seen in a ring at ~160 AU. Simple models of both molecules using
constant abundances reproduce the data. Assuming reasonable average excitation
temperatures for the whole disk, their disk-averaged column densities (and
deuterium fractionation ratios) are 1.6-2.6 cm
(0.04-0.07), 2.9-5.2 cm (0.02) and 1.6-2.5 cm (0.34-0.45) for DCO, DCN and ND, respectively.
Our simple best-fit models show a correlation between the radial location of
the first two rings in DCO and the DCN and ND abundance
distributions that can be interpreted as the high and low temperature
deuteration pathways regimes. The origin of the third DCO ring at 260 AU is
unknown but may be due to a local decrease of ultraviolet opacity allowing the
photodesorption of CO or due to thermal desorption of CO as a consequence of
radial drift and settlement of dust grains
Quantification of segregation dynamics in ice mixtures
(Abridged) The observed presence of pure CO2 ice in protostellar envelopes is
attributed to thermally induced ice segregation, but a lack of quantitative
experimental data has prevented its use as a temperature probe. Quantitative
segregation studies are also needed to characterize diffusion in ices, which
underpins all ice dynamics and ice chemistry. This study aims to quantify the
segregation mechanism and barriers in different H2O:CO2 and H2O:CO ice mixtures
covering a range of astrophysically relevant ice thicknesses and mixture
ratios. The ices are deposited at 16-50 K under (ultra-)high vacuum conditions.
Segregation is then monitored at 23-70 K as a function of time, through
infrared spectroscopy. Thin (8-37 ML) H2O:CO2/CO ice mixtures segregate
sequentially through surface processes, followed by an order of magnitude
slower bulk diffusion. Thicker ices (>100 ML) segregate through a fast bulk
process. The thick ices must therefore be either more porous or segregate
through a different mechanism, e.g. a phase transition. The segregation
dynamics of thin ices are reproduced qualitatively in Monte Carlo simulations
of surface hopping and pair swapping. The experimentally determined
surface-segregation rates for all mixture ratios follow the Ahrrenius law with
a barrier of 1080[190] K for H2O:CO2 and 300[100] K for H2O:CO mixtures. During
low-mass star formation H2O:CO2 segregation will be important already at 30[5]
K. Both surface and bulk segregation is proposed to be a general feature of ice
mixtures when the average bond strengths of the mixture constituents in pure
ice exceeds the average bond strength in the ice mixture.Comment: Accepted for publication in A&A. 25 pages, including 13 figure
Increased HCO production in the outer disk around HD 163296
Three formaldehyde lines were observed (HCO 3--2, HCO
3--2, and HCO 3--2) in the protoplanetary disk
around the Herbig Ae star HD 163296 with ALMA at 0.5 arcsecond (60 AU) spatial
resolution. HCO 3--2 was readily detected via imaging, while
the weaker HCO 3--2 and HCO 3--2 lines
required matched filter analysis to detect. HCO is present throughout most
of the gaseous disk, extending out to 550 AU. An apparent 50 AU inner radius of
the HCO emission is likely caused by an optically thick dust continuum. The
HCO radial intensity profile shows a peak at 100 AU and a secondary bump at
around 300 AU, suggesting increased production in the outer disk. Different
parameterizations of the HCO abundance were compared to the observed
visibilities with minimization, using either a characteristic
temperature, a characteristic radius or a radial power law index to describe
the HCO chemistry. Similar models were applied to ALMA Science Verification
data of CO. In all modeling scenarios, fits to the HCO data show an
increased abundance in the outer disk. The overall best-fit HCO model shows
a factor of two enhancement beyond a radius of 27020 AU, with an inner
abundance of . The HCO emitting region has a lower
limit on the kinetic temperature of K. The CO modeling suggests
an order of magnitude depletion in the outer disk and an abundance of in the inner disk. The increase in HCO outer disk emission
could be a result of hydrogenation of CO ices on dust grains that are then
sublimated via thermal desorption or UV photodesorption, or more efficient
gas-phase production beyond about 300 AU if CO is photodisocciated in this
region
The cometary composition of a protoplanetary disk as revealed by complex cyanides
Observations of comets and asteroids show that the Solar Nebula that spawned
our planetary system was rich in water and organic molecules. Bombardment
brought these organics to the young Earth's surface, seeding its early
chemistry. Unlike asteroids, comets preserve a nearly pristine record of the
Solar Nebula composition. The presence of cyanides in comets, including 0.01%
of methyl cyanide (CH3CN) with respect to water, is of special interest because
of the importance of C-N bonds for abiotic amino acid synthesis. Comet-like
compositions of simple and complex volatiles are found in protostars, and can
be readily explained by a combination of gas-phase chemistry to form e.g. HCN
and an active ice-phase chemistry on grain surfaces that advances
complexity[3]. Simple volatiles, including water and HCN, have been detected
previously in Solar Nebula analogues - protoplanetary disks around young stars
- indicating that they survive disk formation or are reformed in situ. It has
been hitherto unclear whether the same holds for more complex organic molecules
outside of the Solar Nebula, since recent observations show a dramatic change
in the chemistry at the boundary between nascent envelopes and young disks due
to accretion shocks[8]. Here we report the detection of CH3CN (and HCN and
HC3N) in the protoplanetary disk around the young star MWC 480. We find
abundance ratios of these N-bearing organics in the gas-phase similar to
comets, which suggests an even higher relative abundance of complex cyanides in
the disk ice. This implies that complex organics accompany simpler volatiles in
protoplanetary disks, and that the rich organic chemistry of the Solar Nebula
was not unique.Comment: Definitive version of the manuscript is published in Nature, 520,
7546, 198, 2015. This is the author's versio
Water formation at low temperatures by surface O2 hydrogenation II: the reaction network
Water is abundantly present in the Universe. It is the main component of
interstellar ice mantles and a key ingredient for life. Water in space is
mainly formed through surface reactions. Three formation routes have been
proposed in the past: hydrogenation of surface O, O2, and O3. In a previous
paper [Ioppolo et al., Astrophys. J., 2008, 686, 1474] we discussed an
unexpected non-standard zeroth-order H2O2 production behaviour in O2
hydrogenation experiments, which suggests that the proposed reaction network is
not complete, and that the reaction channels are probably more interconnected
than previously thought. In this paper we aim to derive the full reaction
scheme for O2 surface hydrogenation and to constrain the rates of the
individual reactions. This is achieved through simultaneous H-atom and O2
deposition under ultra-high vacuum conditions for astronomically relevant
temperatures. Different H/O2 ratios are used to trace different stages in the
hydrogenation network. The chemical changes in the forming ice are followed by
means of reflection absorption infrared spectroscopy (RAIRS). New reaction
paths are revealed as compared to previous experiments. Several reaction steps
prove to be much more efficient (H + O2) or less efficient (H + OH and H2 + OH)
than originally thought. These are the main conclusions of this work and the
extended network concluded here will have profound implications for models that
describe the formation of water in space.Comment: 1 page, 1 figur
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