Distillation methods affect the chemical composition of Varronia curassavica Jacq, essential oil?

The objective of this work was to evaluate the chemical composition of essential oil from Varronia curassavica Jacq. obtained by microwave (MI) and hydrodistillation (HD) extraction methods. The MI method tested three powers (500, 600, and 700W), three distillation times (20, 30, and 40 min.), and three water volumes (0, 25, and 50 mL per sample). The HD method tested three distillation times (100, 120, and 140 min.) and three water volumes (1.0, 1.5, and 2.0 L per 3-liter flask). The essential oils were analyzed by GC/MS-FID. The optimal condition for the essential oil extraction by the MI method was 700W for 40 min. (3.28%), regardless of the volume of water. In its turn, the best condition for essential oil extraction by the HD method was 120 min. with 1.0 L of water per flask (3.34%). The most abundant compounds for MI (700 W for 40 min. without water) were shyobunol (26.53%) and bicyclogermacrene (4.96%); and the most abundant compounds for HD (120 min. with 1.0 L of water/flask) were shyobunol (24.00%) and germacrene D-4-ol (10.23%). Methyl farnesoate (2E, 6E) and farnesyl acetate (2Z, 6E) were not detected in the essential oil extracted by HD; however, they were identified by the MI method. By increasing the distillation time and/or volume of water in HD, a reduction was observed for the content of the chemical compounds -elemene (from 1.23 to 0.97%), Ecaryophyllene (from 5.49 to 4.35%), -humulene (from 1.80 to 1.43%), alloaromadendrene (from 1.78 to 1.44%), bicyclogermacrene (from 5.63 to 4.55%), and germacrene D-4-ol (from 11.40 to 9.86%). Power, extraction time, and their interactions influenced the content of essential oil obtained by microwave extraction (MI). Within each power, the highest essential oil content was extracted at the longest distillation time (40 min.), except for 600W, where no significant difference was detected between 30 and 40 min. The optimal essential oil contents for both extraction methods were statically similar by the t-test for dependent samples. However, the MI method presents advantages, such as shorter distillation time and less energy and water consumption

Chaotic Cascades with Kolmogorov 1941 Scaling

We define a (chaotic) deterministic variant of random multiplicative cascade models of turbulence. It preserves the hierarchical tree structure, thanks to the addition of infinitesimal noise. The zero-noise limit can be handled by Perron-Frobenius theory, just as the zero-diffusivity limit for the fast dynamo problem. Random multiplicative models do not possess Kolmogorov 1941 (K41) scaling because of a large-deviations effect. Our numerical studies indicate that deterministic multiplicative models can be chaotic and still have exact K41 scaling. A mechanism is suggested for avoiding large deviations, which is present in maps with a neutrally unstable fixed point.Comment: 14 pages, plain LaTex, 6 figures available upon request as hard copy (no local report #

First observation of 54Zn and its decay by two-proton emission

The nucleus 54Zn has been observed for the first time in an experiment at the SISSI/LISE3 facility of GANIL in the quasi-fragmentation of a 58Ni beam at 74.5 MeV/nucleon in a natNi target. The fragments were analysed by means of the ALPHA-LISE3 separator and implanted in a silicon-strip detector where correlations in space and time between implantation and subsequent decay events allowed us to generate almost background free decay spectra for about 25 different nuclei at the same time. Eight 54Zn implantation events were observed. From the correlated decay events, the half-life of 54Zn is determined to be 3.2 +1.8/-0.8 ms. Seven of the eight implantations are followed by two-proton emission with a decay energy of 1.48(2) MeV. The decay energy and the partial half-life are compared to model predictions and allow for a test of these two-proton decay models.Comment: 4 pages, 4 figures, accepted for publication in PR

The beta-decay of 22Al

In an experiment performed at the LISE3 facility of GANIL, we studied the decay of 22Al produced by the fragmentation of a 36Ar primary beam. A beta-decay half-life of 91.1 +- 0.5 ms was measured. The beta-delayed one- and two-proton emission as well as beta-alpha and beta-delayed gamma decays were measured and allowed us to establish a partial decay scheme for this nucleus. New levels were determined in the daughter nucleus 22Mg. The comparison with model calculations strongly favours a spin-parity of 4+ for the ground state of 22Al

Non-perturbative flow equations from continuous unitary transformations

We use a novel parameterization of the flowing Hamiltonian to show that the flow equations based on continuous unitary transformations, as proposed by Wegner, can be implemented through a nonlinear partial differential equation involving one flow parameter and two system specific auxiliary variables. The implementation is non-perturbative as the partial differential equation involves a systematic expansion in fluctuations, controlled by the size of the system, rather than the coupling constant. The method is applied to the Lipkin model to construct a mapping which maps the non-interacting spectrum onto the interacting spectrum to a very high accuracy. This function is universal in the sense that the full spectrum for any (large) number of particles can be obtained from it. In a similar way expectation values for a large class of operators can be obtained, which also makes it possible to probe the stucture of the eigenstates.Comment: 24 pages, 13 figure

Integración in vivo de secuencias provirales del virus linfotrópico humano tipo i (htlv-1) y expresión de genes virales en células del epitelio oral en individuos seropositivos

Determinar la integración in vivo de secuencias provirales en células del epitelio bucal de individuos seropositivos para el HTLV-I

Integración in vivo de secuencias provirales del virus linfotrópico humano tipo i (htlv-1) y expresión de genes virales en células del epitelio oral en individuos seropositivos

Determinar la integración in vivo de secuencias provirales en células del epitelio bucal de individuos seropositivos para el HTLV-I

Magnetic strip waveguides

We analyze the spectrum of the "local" Iwatsuka model, i.e. a two-dimensional charged particle interacting with a magnetic field which is homogeneous outside a finite strip and translationally invariant along it. We derive two new sufficient conditions for absolute continuity of the spectrum. We also show that in most cases the number of open spectral gaps of the model is finite. To illustrate these results we investigate numerically the situation when the field is zero in the strip being screened, e.g. by a superconducting mask.Comment: 22 pages, a LaTeX source file with three eps figure

Absence of Normalizable Time-periodic Solutions for The Dirac Equation in Kerr-Newman-dS Black Hole Background

We consider the Dirac equation on the background of a Kerr-Newman-de Sitter black hole. By performing variable separation, we show that there exists no time-periodic and normalizable solution of the Dirac equation. This conclusion holds true even in the extremal case. With respect to previously considered cases, the novelty is represented by the presence, together with a black hole event horizon, of a cosmological (non degenerate) event horizon, which is at the root of the possibility to draw a conclusion on the aforementioned topic in a straightforward way even in the extremal case.Comment: 12 pages. AMS styl