1,844 research outputs found

    A Quantitative Study of Java Software Buildability

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    Researchers, students and practitioners often encounter a situation when the build process of a third-party software system fails. In this paper, we aim to confirm this observation present mainly as anecdotal evidence so far. Using a virtual environment simulating a programmer's one, we try to fully automatically build target archives from the source code of over 7,200 open source Java projects. We found that more than 38% of builds ended in failure. Build log analysis reveals the largest portion of errors are dependency-related. We also conduct an association study of factors affecting build success

    Evolution of populations expanding on curved surfaces

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    The expansion of a population into new habitat is a transient process that leaves its footprints in the genetic composition of the expanding population. How the structure of the environment shapes the population front and the evolutionary dynamics during such a range expansion is little understood. Here, we investigate the evolutionary dynamics of populations consisting of many selectively neutral genotypes expanding on curved surfaces. Using a combination of individual-based off-lattice simulations, geometrical arguments, and lattice-based stepping-stone simulations, we characterise the effect of individual bumps on an otherwise flat surface. Compared to the case of a range expansion on a flat surface, we observe a transient relative increase, followed by a decrease, in neutral genetic diversity at the population front. In addition, we find that individuals at the sides of the bump have a dramatically increased expected number of descendants, while their neighbours closer to the bump's centre are far less lucky. Both observations can be explained using an analytical description of straight paths (geodesics) on the curved surface. Complementing previous studies of heterogeneous flat environments, the findings here build our understanding of how complex environments shape the evolutionary dynamics of expanding populations.Comment: This preprint has also been posted to http://www.biorxiv.org with doi: 10.1101/406280. Seven pages with 5 figures, plus an appendix containing 3 pages with 1 figur

    Co-based heterogeneous catalysts from well-defined Α-diimine complexes : Discussing the role of nitrogen

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    Ar-BIANs and related \uce\ub1-diimine Co complexes were wet impregnated onto Vulcan\uc2\uae XC 72 R carbon black powder and used as precursors for the synthesis of heterogeneous supported nanoscale catalysts by pyrolysis under argon at 800\uc2\ua0\uc2\ub0C. The catalytic materials feature a core-shell structure composed of metallic Co and Co oxides decorated with nitrogen-doped graphitic layers (NGr). These catalysts display high activity in the liquid phase hydrogenation of aromatic nitro compounds (110\uc2\ua0\uc2\ub0C, 50 bar H2) to give chemoselectively substituted aryl amines. The catalytic activity is closely related to the amount and type of nitrogen atoms in the final catalytic material, which suggests a heterolytic activation of dihydrogen

    The maximum modulus of a trigonometric trinomial

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    Let Lambda be a set of three integers and let C_Lambda be the space of 2pi-periodic functions with spectrum in Lambda endowed with the maximum modulus norm. We isolate the maximum modulus points x of trigonometric trinomials T in C_Lambda and prove that x is unique unless |T| has an axis of symmetry. This permits to compute the exposed and the extreme points of the unit ball of C_Lambda, to describe how the maximum modulus of T varies with respect to the arguments of its Fourier coefficients and to compute the norm of unimodular relative Fourier multipliers on C_Lambda. We obtain in particular the Sidon constant of Lambda

    Templated self-assembly of gold nanoparticles in smectic liquid crystals confined at 3D printed curved surfaces

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    The fabrication of assembled structures of topological defects in liquid crystals (LCs) has attracted much attention during the last decade, stemming from the potential application of these defects in modern technologies. A range of techniques can be employed to create large areas of engineered defects in LCs, including mechanical shearing, chemical surface treatment, external fields, or geometric confinement. The technology of 3D printing has recently emerged as a powerful method to fabricate novel patterning topographies inaccessible by other microfabrication techniques, especially confining geometries with curved topographies. In this work, we show the advantages of using 3D-printed curved surfaces and controlled anchoring properties to confine LCs and engineer new structures of topological defects, whose structure we elucidate by comparison with a novel application of Landau-de Gennes free energy minimization to the smectic A-nematic phase transition. We also demonstrate the ability of these defects to act as a scaffold for assembling gold (Au) nanoparticles (NPs) into reconfigurable 3D structures. We discuss the characteristics of this templated self-assembly (TSA) approach and explain the relationship between NP concentrations and defect structures with insights gained from numerical modeling. This work paves the way for a versatile platform of LC defect-templated assembly of a range of functional nanomaterials useful in the field of energy technology.Comment: Main text: 30 pages, 6 figures. Supplementary Information: 5 pages, 4 figure

    <i>In vitro</i> Characterization of Phenylacetate Decarboxylase, a Novel Enzyme Catalyzing Toluene Biosynthesis in an Anaerobic Microbial Community

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    Anaerobic bacterial biosynthesis of toluene from phenylacetate was reported more than two decades ago, but the biochemistry underlying this novel metabolism has never been elucidated. Here we report results of in vitro characterization studies of a novel phenylacetate decarboxylase from an anaerobic, sewage-derived enrichment culture that quantitatively produces toluene from phenylacetate; complementary metagenomic and metaproteomic analyses are also presented. Among the noteworthy findings is that this enzyme is not the well-characterized clostridial p-hydroxyphenylacetate decarboxylase (CsdBC). However, the toluene synthase under study appears to be able to catalyze both phenylacetate and p-hydroxyphenylacetate decarboxylation. Observations suggesting that phenylacetate and p-hydroxyphenylacetate decarboxylation in complex cell-free extracts were catalyzed by the same enzyme include the following: (i) the specific activity for both substrates was comparable in cell-free extracts, (ii) the two activities displayed identical behavior during chromatographic separation of cell-free extracts, (iii) both activities were irreversibly inactivated upon exposure to O2, and (iv) both activities were similarly inhibited by an amide analog of p-hydroxyphenylacetate. Based upon these and other data, we hypothesize that the toluene synthase reaction involves a glycyl radical decarboxylase. This first-time study of the phenylacetate decarboxylase reaction constitutes an important step in understanding and ultimately harnessing it for making bio-based toluene

    Nonclassical correlations of phase noise and photon number in quantum nondemolition measurements

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    The continuous transition from a low resolution quantum nondemolition measurement of light field intensity to a precise measurement of photon number is described using a generalized measurement postulate. In the intermediate regime, quantization appears as a weak modulation of measurement probability. In this regime, the measurement result is strongly correlated with the amount of phase decoherence introduced by the measurement interaction. In particular, the accidental observation of half integer photon numbers preserves phase coherence in the light field, while the accidental observation of quantized values increases decoherence. The quantum mechanical nature of this correlation is discussed and the implications for the general interpretation of quantization are considered.Comment: 16 pages, 5 figures, final version to be published in Phys. Rev. A, Clarifications of the nature of the measurement result and the noise added in section I

    From Einstein's Theorem to Bell's Theorem: A History of Quantum Nonlocality

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    In this Einstein Year of Physics it seems appropriate to look at an important aspect of Einstein's work that is often down-played: his contribution to the debate on the interpretation of quantum mechanics. Contrary to popular opinion, Bohr had no defence against Einstein's 1935 attack (the EPR paper) on the claimed completeness of orthodox quantum mechanics. I suggest that Einstein's argument, as stated most clearly in 1946, could justly be called Einstein's reality-locality-completeness theorem, since it proves that one of these three must be false. Einstein's instinct was that completeness of orthodox quantum mechanics was the falsehood, but he failed in his quest to find a more complete theory that respected reality and locality. Einstein's theorem, and possibly Einstein's failure, inspired John Bell in 1964 to prove his reality-locality theorem. This strengthened Einstein's theorem (but showed the futility of his quest) by demonstrating that either reality or locality is a falsehood. This revealed the full nonlocality of the quantum world for the first time.Comment: 18 pages. To be published in Contemporary Physics. (Minor changes; references and author info added

    Direct observation of long-lived isomers in 212^{212}Bi

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    Long-lived isomers in 212Bi have been studied following 238U projectile fragmentation at 670 MeV per nucleon. The fragmentation products were injected as highly charged ions into the GSI storage ring, giving access to masses and half-lives. While the excitation energy of the first isomer of 212Bi was confirmed, the second isomer was observed at 1478(30) keV, in contrast to the previously accepted value of >1910 keV. It was also found to have an extended Lorentz-corrected in-ring halflife >30 min, compared to 7.0(3) min for the neutral atom. Both the energy and half-life differences can be understood as being due a substantial, though previously unrecognised, internal decay branch for neutral atoms. Earlier shell-model calculations are now found to give good agreement with the isomer excitation energy. Furthermore, these and new calculations predict the existence of states at slightly higher energy that could facilitate isomer de-excitation studies.Comment: published in PRL 110, 12250
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