Anisotropic conductivity of silver thin films grown on silicon (100) vicinal surfaces

The electrical conductivity between 4 and 300 K of Ag thin films (up to 30 mm grown at room temperature on Si(100) vicinal surfaces has been measured and their morphology imaged with an atomic force microscope. A noticeable anisotropy of the resistivity of the films which is related to the structure of the films has been found)Laboratories du CNRS Departamento de Física Materia Condensada. Universidad Autónoma.Peer reviewe

Greening plans as (re)presentation of the city : toward an inclusive and gender-sensitive approach to urban greenspaces

Altres ajuts: acords transformatius de la UABUnidad de excelencia María de Maeztu CEX2019-000940-MCities around the world are increasingly expanding their sustainability agendas and adopting urban green and blue infrastructure planning as a strategy to become more resilient, healthy and sustainable. However, the development of urban greening governance often lacks a holistic vision that considers social inequities within the planning, implementation and management of green and blue spaces. Further, gender inequities have been a specific dimension particularly overlooked in urban greening planning, despite gender concerns gaining increasing political relevance in recent years. In this research, we assessed the extento to which social and gender equity are being considered in urban greening plans and projects at the local level. We chose Barcelona (Spain) as main case study due to its pioneering role in implementing crosscutting equity and gender policies at the municipal level. Building on document analysis and semi-structured interviews with key stakeholders, we examined how social justice and gender are understood and operationalized in practice, from the design phase to implementation and maintenance of greening projects. Our findings suggest a shift in the role of urban greening which evolved from an ornamental role to a multifunctional vision of greening and is recently incorporating equity and inclusivity concerns. We identified three action areas of inclusive, gender-sensitive urban green planning practices: first, the incorporation of inclusivity and care as guiding visible values to recognize multiple needs of city residents; second, urban design for different uses and perceptions of greenspaces, particularly in relation to accessibility and autonomy; and third, the awareness and expertise from municipal staff vis-à-vis the consideration of social and gender equity in green planning and participatory approaches. Finally, we provide practical examples of the strategies that the City of Barcelona is implementing in each area and discuss some challenges and limitations, including what we identify as ad hoc intersectional greening

La calorimetría diferencial de barrido y su aplicación a la Ciencia de Materiales

Se pone de manifiesto la idoneidad de la técnica de calorimetría diferencial de barrido para la caracterización de materiales. Se presentan ejemplos específicos de aplicación de dicha técnica en el estudio de los fenómenos ligados a la transición vitrea y cinética de cristalización de vidrios calcogenuros y metálicos así como en el estudio de la reordenación de fases desordenadas metastables

La calorimetría diferencial de barrido y su aplicación a la Ciencia de Materiales

Se pone de manifiesto la idoneidad de la técnica de calorimetría diferencial de barrido para la caracterización de materiales. Se presentan ejemplos específicos de aplicación de dicha técnica en el estudio de los fenómenos ligados a la transición vitrea y cinética de cristalización de vidrios calcogenuros y metálicos así como en el estudio de la reordenación de fases desordenadas metastables

Tracing and building up environmental justice considerations in the urban ecosystem service literature : A systematic review

Unidad de excelencia María de Maeztu CEX2019-000940-MAltres ajuts: Acord transformatiu CRUE-CSICThe concept of ecosystem services (ES) has mainstreamed as an interdisciplinary framework in the urban sustainability and resilience agenda. While the uptake of ES in urban areas is deeply entangled with multiple values, trade-offs, institutions, management and planning approaches, there is still a lack of a comprehensive and systematic framework to address environmental justice (EJ) in urban ES assessments. This article presents a systematic literature review to examine what factors are critical for the effective inclusion of an EJ lens in urban ES appraisals. More specifically, we assessed how distributional, procedural and recognitional EJ dimensions have been addressed, and in relation to which types of urban ES. Our results reveal that EJ considerations are currently focused on the (un)equal distribution of ES and the associated green and blue infrastructure with regard to socioeconomic groups, with special attention to income and race/ethnicity as the main mechanisms of social stratification. There is also a predominant focus on regulating and cultural ES, analyzing their role on resilience and adaptive capacity on one hand, and recreational values, social cohesion and place-making on the other. In this review, we also evaluate the interconnected dimensions of justice and their constraints, and lay out pathways for new research into intersectional and restorative approaches to justice in ES assessments. Finally, we interrogate what the role of urban ES-based planning might be in making more inclusive and just cities and explore its implications for policy and practice

Pectin methyl esterases and rhamnogalacturonan hydrolases: weapons for successful Monilinia laxa infection in stone fruit?

The secretion of cell wall‐degrading enzymes is one of the mechanisms used by necrotrophic fungi to colonize host tissues. However, information about virulence factors of Monilinia spp., the causal agents of brown rot in stone fruit, is scarce. Plant cell walls have three main components that are broken down by fungal enzymes: cellulose, hemicellulose and pectin. In order to identify Monilinia laxa candidate proteins involved in pectin hydrolysis, two in vitro approaches were conducted: (i) phenotypic and ecophysiological characterization of growth of the pathogen at different pHs, in glucose‐ and pectin‐containing solid media for 7 days' incubation; and (ii) expression analysis of genes encoding M. laxa pectin methyl esterases (MlPMEs) and rhamnogalacturonan hydrolases (MlRG‐HYDs) after incubation for 0.5, 2, 6, 24 and 48 h in glucose‐ and pectin‐containing liquid media. Phenotypic tests showed the role of carbon source on M. laxa growth rate and aggressiveness, and indicated that pectinases were greatly affected by pH. Gene expression analyses uncovered differences among members of each family of pectinases and between the two families, defining sets of genes expressed at earlier (0.5–6 h) and later (48 h) phases. Notably, the up‐ or down‐regulation of these target genes was carbon source‐dependent. Finally, an in vivo study confirmed the synergistic and complementary role that these genes play in the M. laxa–stone fruit pathosystem. Based on these results, it is hypothesized that MlPME2, MlRG‐HYD1 and MlRG‐HYD2 may be potential virulence factors of M. laxa in the process from infection to colonization.info:eu-repo/semantics/acceptedVersio

Aerosol optical properties over Europe: an evaluation of the AQMEII Phase 3 simulations against satellite observations

Abstract. The main uncertainties regarding the estimation of changes in the Earth's energy budget are related to the role of atmospheric aerosols. These changes are caused by aerosol–radiation (ARIs) and aerosol–cloud interactions (ACIs), which heavily depend on aerosol properties. Since the 1980s, many international modeling initiatives have studied atmospheric aerosols and their climate effects. Phase 3 of the Air Quality Modelling Evaluation International Initiative (AQMEII) focuses on evaluating and intercomparing regional and linked global/regional modeling systems by collaborating with the Task Force on the Hemispheric Transport of Air Pollution Phase 2 (HTAP2) initiative. Within this framework, the main aim of this work is the assessment of the representation of aerosol optical depth (AOD) and the Ångström exponent (AE) in AQMEII Phase 3 simulations over Europe. The evaluation was made using remote-sensing data from the Moderate Resolution Imaging Spectroradiometer (MODIS) sensors aboard the Terra and Aqua platforms, and the instruments belonging to the ground-based Aerosol Robotic Network (AERONET) and the Maritime Aerosol Network (MAN). Overall, the skills of AQMEII simulations when representing AOD (mean absolute errors from 0.05 to 0.30) produced lower errors than for the AE (mean absolute errors from 0.30 to 1). Regardless of the models or the emissions used, models were skillful at representing the low and mean AOD values observed (below 0.5). However, high values (around 1.0) were overpredicted for biomass burning episodes, due to an underestimation in the common fires' emissions, and were overestimated for coarse particles – principally desert dust – related to the boundary conditions. Despite this behavior, the spatial and temporal variability of AOD was better represented by all the models than AE variability, which was strongly underestimated in all the simulations. Noticeably, the impact of the model selection when representing aerosol optical properties is higher than the use of different emission inventories. On the other hand, the influence of ARIs and ACIs has a little visible impact compared to the impact of the model used

Anodic formation of self-organized Ti(Nb,Sn) oxide nanotube arrays with tuneable aspect ratio and size distribution

This is the author's version of a work that was accepted for publication in Electrochemistry communications. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Electrochemistry communications, [33,(2013)] DOI10.1016/j.elecom.2013.04.023).In the present communication one-step anodization is used to prepare large arrays of self-assembled Ti(Nb,Sn) oxide nanotubes on Ti-Nb-Sn alloy. Tuneable nanoscale geometries (unimodal vs. bimodal size distribution with variable length/diameter ratios) can be controllably achieved by varying the anodization conditions, which are highly desirable for enhanced functionalities in widespread applications

Space-time evolution of electron cascades in diamond

Here we describe model calculations to follow the spatio-temporal evolution of secondary electron cascades in diamond. The band structure of the insulator has been explicitly incorporated into the calculations as it affects ionizations from the valence band. A Monte-Carlo model was constructed to describe the path of electrons following the impact of a single electron of energy E 250 eV. The results show the evolution of the secondary electron cascades in terms of the number of electrons liberated, the spatial distribution of these electrons, and the energy distribution among the electrons as a function of time. The predicted ionization rates (5-13 electrons in 100 fs) lie within the limits given by experiments and phenomenological models. Calculation of the local electron density and the corresponding Debye length shows that the latter is systematically larger than the radius of the electron cloud. This means that the electron gas generated does not represent a plasma in a single impact cascade triggered by an electron of E 250 eV energy. This is important as it justifies the independent-electron approximation used in the model. At 1 fs, the (average) spatial distribution of secondary electrons is anisotropic with the electron cloud elongated in the direction of the primary impact. The maximal radius of the cascade is about 50 A at this time. As the system cools, energy is distributed more equally, and the spatial distribution of the electron cloud becomes isotropic. At 90 fs maximal radius is about 150 A. The Monte-Carlo model described here could be adopted for the investigation of radiation damage in other insulators and has implications for planned experiments with intense femtosecond X-ray sources.Comment: 26 pages, latex, 13 figure

Fundamentals of interface phenomena in advanced bulk nanoscale materials

The review is devoted to a study of interface phenomena influencing advanced properties of nanoscale materials processed by means of severe plastic deformation, high-energy ball milling and their combinations. Interface phenomena include processes of interface defect structure relaxation from a highly nonequilibrium state to an equilibrium condition, grain boundary phase transformations and enhanced grain boundary and triple junction diffusivity. On the basis of an experimental investigation, a theoretical description of the key interfacial phenomena controlling the functional properties of advanced bulk nanoscale materials has been conducted. An interface defect structure investigation has been performed by TEM, high-resolution x-ray diffraction, atomic simulation and modeling. The problem of a transition from highly non-equilibrium state to an equilibrium one, which seems to be responsible for low thermostability of nanoscale materials, was studied. Also enhanced grain boundary diffusivity is addressed. Structure recovery and dislocation emission from grain boundaries in nanocrystalline materials have been investigated by analytical methods and modeling