Anion emission from water molecules colliding with positive ions: Identification of binary and many-body processes

It is shown that negative ions are ejected from gas-phase water molecules when bombarded with positive ions at keV energies typical of solar-wind velocities. This finding is relevant for studies of planetary and cometary atmospheres, as well as for radiolysis and radiobiology. Emission of both H- and heavier (O- and OH-) anions, with a larger yield for H-, was observed in 6.6-keV 16O+ + H2O collisions. The ex-perimental setup allowed separate identification of anions formed in collisions with many-body dynamics from those created in hard, binary collisions. Most of the ani-ons are emitted with low kinetic energy due to many-body processes. Model calcu-lations show that both nucleus-nucleus interactions and electronic excitations con-tribute to the observed large anion emission yield.Comment: 5 pages, 4 figure

Atomic site sensitive processes in low energy ion-dimer collisions

Electron capture processes for low energy Ar9+ ions colliding on Ar2 dimer targets are investigated, focusing attention on charge sharing as a function of molecule orientation and impact parameter. A preference in charge-asymmetric dissociation channels is observed, with a strong correlation between the projectile scattering angle and the molecular ion orientation. The measurements provide here clear evidences that projectiles distinguish each atom in the target and, that electron capture from near-site atom is favored. Monte Carlo calculations based on the classical over-the-barrier model, with dimer targets represented as two independent atoms, are compared to the data. They give a new insight into the dynamics of the collision by providing, for the di erent electron capture channels, the two-dimensional probability maps p(~b), where ~b is the impact parameter vector in the molecular frame

Phthalocyanine-based dumbbell-shaped molecule: synthesis, structure and charge transport studies

International audienceWe describe the synthesis of a fully conjugated donor-acceptor-donor triad (ZnPc-BTD-ZnPc) made of zinc phthalocyanine donor fragments (ZnPc) at both ends of a benzothiadiazole-based central dye (BTD). The molecule exhibits a broad absorption in the whole visible range. The introduction of sterically demanding alkoxy chains to the ZnPc fragments is found to limit the molecular organization to a short-range columnar order and the charge-carrier mobility to moderate values, but provides outstanding solubilities in organic solvents

Diphoton Production at Hadron Colliders and New Contact Interactions

We explore the capability of the Tevatron and LHC to place limits on the possible existence of flavor-independent $q \bar q \gamma\gamma$ contact interactions which can lead to an excess of diphoton events with large invariant masses. Assuming no departure from the Standard Model is observed, we show that the Tevatron will eventually be able to place a lower bound of 0.5-0.6 TeV on the scale associated with this new contact interaction. At the LHC, scales as large as 3-6 TeV may be probed with suitable detector cuts and an integrated luminosity of $100 fb^{-1}$.Comment: LaTex, 12pages plus 5 figures(available on request), SLAC-PUB-657

Effective-Lagrangian approach to precision measurements: the anomalous magnetic moment of the muon

We investigate the use of effective Lagrangians to describe the effects on high-precision observables of physics beyond the Standard Model. Using the anomalous magnetic moment of the muon as an example, we detail the use of effective vertices in loop calculations. We then provide estimates of the sensitivity of new experiments measuring the muon's $g - 2$ to the scale of physics underlying the Standard Model.Comment: 22 pages, 1 figure, PHYZZX & EPSF, report #s UCRHEP-T98, UM_TH-92-17, and NSF-ITP-92-122I Revision: The paper will now TeX properly; the content is unchange

Electron shakeoff following the β+ decay of trapped 35Ar+ ions

The electron shakeoff of 35Cl atoms resulting from the β+ decay of 35Ar+ ions has been investigated using a Paul trap coupled to a recoil-ion spectrometer. The charge-state distribution of the recoiling daughter nuclei is compared to theoretical calculations accounting for shakeoff and Auger processes. The calculations are in excellent agreement with the experimental results and enable one to identify the ionization reaction routes leading to the formation of all charge states.D.R. acknowledges support from the Spanish ministry of Economy and Competitiveness under the project FPA2010-14803 and the action AIC10-D000562

Constraints on Four Fermion Contact Interactions from Precise Electroweak Measurements

We establish constraints on a general four-fermion contact interaction from precise measurements of electroweak parameters. We compute the one-loop contribution for the leptonic $Z$ width, anomalous magnetic, weak-magnetic, electric and weak dipole moments of leptons in order to extract bounds on the energy scale of these effective interactions.Comment: 16 pages, RevTeX, two figure

Uses and Abuses of Effective Lagrangians

Motivated by past and recent analyses we critically re-examine the use of effective lagrangians in the literature to constrain new physics and to determine the `physics reach' of future experiments. We demonstrate that many calculations, such as those involving anomalous trilinear gauge-boson couplings, either considerably overestimate loop-induced effects, or give ambiguous answers. The source of these problems is the use of cutoffs to evaluate the size of such operators in loop diagrams. In contrast to other critics of these loop estimates, we prove that the inclusion of nonlinearly-realized gauge invariance into the low-energy lagrangian is irrelevant to this conclusion. We use an explicit example using known multi-Higgs physics above the weak scale to underline these points. We show how to draw conclusions regarding the nature of the unknown high-energy physics without making reference to low-energy cutoffs.Comment: 36 page

Cyclic Nucleotide Phosphodiesterases and Compartmentation in Normal and Diseased Heart

International audienceCyclic nucleotide phosphodiesterases (PDEs) degrade the second messengers cAMP and cGMP, thereby regulating multiple aspects of cardiac function. This highly diverse class of enzymes encoded by 21 genes encompasses 11 families which are not only responsible for the termination of cyclic nucleotide signalling, but are also involved in the generation of dynamic microdomains of cAMP and cGMP controlling specific cell functions in response to various neurohormonal stimuli. In myocardium, the PDE3 and PDE4 families are predominant to degrade cAMP and thereby regulate cardiac excitation-contraction coupling. PDE3 inhibitors are positive inotropes and vasodilators in human, but their use is limited to acute heart failure and intermittent claudication. PDE5 is particularly important to degrade cGMP in vascular smooth muscle, and PDE5 inhibitors are used to treat erectile dysfunction and pulmonary hypertension. However, these drugs do not seem efficient in heart failure with preserved ejection fraction. There is experimental evidence that these PDEs as well as other PDE families including PDE1, PDE2 and PDE9 may play important roles in cardiac diseases such as hypertrophy and heart failure. After a brief presentation of the cyclic nucleotide pathways in cardiac cells and the major characteristics of the PDE superfamily, this chapter will present their role in cyclic nucleotide compartmentation and the current use of PDE inhibitors in cardiac diseases together with the recent research progresses that could lead to a better exploitation of the therapeutic potential of these enzymes in the future