High-resolution resonant inelastic soft X-ray scattering as a probe of the crystal electrical field in lanthanides demonstrated for the case of CeRh2Si2

The magnetic properties of rare earth compounds are usually well captured by assuming a fully localized f shell and only considering the Hund's rule ground state multiplet split by a crystal electrical field (CEF). Currently, the standard technique for probing CEF excitations in lanthanides is inelastic neutron scattering. Here we show that with the recent leap in energy resolution, resonant inelastic soft X-ray scattering has become a serious alternative for looking at CEF excitations with some distinct advantages compared to INS. As an example we study the CEF scheme in CeRh2Si2, a system that has been intensely studied for more than two decades now but for which no consensus has been reached yet as to its CEF scheme. We used two new features that have only become available very recently in RIXS, high energy resolution of about 30 meV as well as polarization analysis in the scattered beam, to find a unique CEF description for CeRh2Si2. The result agrees well with previous INS and magnetic susceptibility measurements. Due to its strong resonant character, RIXS is applicable to very small samples, presents very high cross sections for all lanthanides, and further benefits from the very weak coupling to phonon excitation. The rapid progress in energy resolution of RIXS spectrometers is making this technique increasingly attractive for the investigation of the CEF scheme in lanthanides

Estructura poblacional del camarón nailon Heterocarpus reedi (Crustacea: Caridea) y su relación con variables ambientales frente a Chile

11 pages, 6 figures, 2 tables[EN] The population structure of fishery resources and the impact of environmental factors over its productivity are important processes to be considered in fisheriesmanagement. Environmental factors could determine both, the success of larval drift as the population spatial structure and its changes of biomass. In this paper we show the environmental effect over distribution, abundance and spatial structure of nylon shrimp population (Heterocarpus reedi) off central Chile (25°-37°S) from trawling surveys carried out between 1996 and 2011. Environmental variables considered where sea surface concentration of chlorophylla and dissolved organic matter. Results show a geographical separation in population around 32°S. Shrimp density is higher in the southern zone, where concentration of chlorophylla and dissolved organic matter are high due to presence of river tributaries and coastal upwelling zones. In this area, thebulk of the adult population is concentrated, which could act as >source> population and thereby its influence on larval drift could explain both, the preponderance of juveniles in the northern area as the smallest size of its population (“pseudo-sink” population). In the southern area, a process of spatial and bathymetric expansion had driven the increase in population size over time, where the colonization and individual somatic growth had been the main mechanisms. We found that periods of good environmental conditions explain high densities of shrimp with a delay of two years, which might be related mainly with larval survival and enhanced recruitment and somatic growth. The aim of this study was to understand the spatial-temporal variability of the nylon shrimp density in the study area[ES] La estructura poblacional de recursos de interés pesquero y el impacto de los factores ambientales sobre su productividad son procesos claves a considerar en la gestión pesquera. Los factores ambientales pueden determinar tanto el éxito de la deriva larval como la estructura espacial de la población y sus cambios de biomasa. Se muestra el efecto del medio ambiente sobre la distribución, abundancia y estructura espacial de la población de camarón nailon (Heterocarpus reedi) en Chile central (25°-37°S), considerando como variables la concentración de clorofila -a y la materia orgánica disuelta, respecto a los cruceros de arrastre realizados entre 1996 y 2011. Los resultados muestran una separación geográfica de la población alrededor de 32°S. En la zona sur, la densidad del camarón es mayor, donde los altos niveles de concentración de clorofila -a y de materia orgánica disuelta se deben, entre otros, a la presencia de afluentes de ríos y a surgencia costera. En esta área, se concentra la mayor parte de la población adulta, que podría actuar como población "fuente" y por lo tanto, su influencia en la deriva larval podría explicar tanto la preponderancia de juveniles en la zona norte, como el tamaño más pequeño de su población (población "pseudo-sumidero”). En la zona sur, un proceso de expansión espacial y batimétrica habría impulsado el aumento de tamaño de la población a través del tiempo, donde los principales mecanismos habrían sido la colonización y crecimiento somático individual. Se determinó que los períodos de buenas condiciones ambientales explican las altas densidades de camarones con un retraso de dos años, aspecto que estaría relacionado principalmente con la supervivencia larval, reclutamiento y crecimiento somático. El objetivo de este estudio es comprender la variabilidad espacio-temporal de la densidad de camarón nailon en el área de estudioWe thank the Fondo de Investigación Pesquera (FIP) of Chile for providing the data base related with trawl survey's information of nylon shrimp (Heterocarpus reedi) carried out in central-south of Chile between 1996 and 2011Peer Reviewe

Valence fuctuation and magnetic ordering in EuNi2(P1-xGex)2 single crystals

Unusual phases and phase transitions are seen at the magnetic-nonmagnetic boundary in Ce, Eu and Yb-based compounds. EuNi$_2$P$_{2}$ is a very unusual valence fluctuating Eu system, because at low temperatures the Eu valence stays close to 2.5 instead of approaching an integer value. Eu valence and thus the magnetic property in this system can be tuned by Ge substitution in P site as EuNi$_2$Ge$_{2}$ is known to exhibit antiferromagnetc (AFM) ordering of divalent Eu moments with $T_N$ = 30 K. We have grown EuNi$_2$(P$_{1-x}$Ge$_x$)$_2$ (0.0 $\leq$ $x$ $\leq$ 0.5) single crystals and studied their magnetic, thermodynamic and transport properties. Increasing Ge doping to $x >$ 0.4 results in a well-defined AFM ordered state with $T_N$ = 12 K for $x$ = 0.5. Moreover, the reduced value of magnetic entropy for $x$ = 0.5 at $T_N$ suggests the presence of valance fluctuation/ Kondo effect in this compound. Interestingly, the specific heat exhibits an enhanced Sommerfeld coefficient upon Ge doping. Subsequently, electronic structure calculations lead to a non-integral valence in EuNi$_2$P$_{2}$ but a stable divalent Eu state in EuNi$_2$Ge$_{2}$ which is in good agreement with experimental results.Comment: 7 pages, 8 figure

Speckle noise and dynamic range in coronagraphic images

This paper is concerned with the theoretical properties of high contrast coronagraphic images in the context of exoplanet searches. We derive and analyze the statistical properties of the residual starlight in coronagraphic images, and describe the effect of a coronagraph on the speckle and photon noise. Current observations with coronagraphic instruments have shown that the main limitations to high contrast imaging are due to residual quasi-static speckles. We tackle this problem in this paper, and propose a generalization of our statistical model to include the description of static, quasi-static and fast residual atmospheric speckles. The results provide insight into the effects on the dynamic range of wavefront control, coronagraphy, active speckle reduction, and differential speckle calibration. The study is focused on ground-based imaging with extreme adaptive optics, but the approach is general enough to be applicable to space, with different parameters.Comment: 31 pages, 18 figure

Why are boys falling behind girls in schooling?

The paper tries to explain why women in the Philippines, as yet a low middle income country, obtain higher levels of education than boys. Four empirically based reasons are posited - the substantial expansion of the education system, the growth of job opportunities, the culture that encourages girls to develop better study habits and the high returns to their education. Empirical evidence is provided to support these contentions especially on the returns to women's schooling. The study concentrates in estimating by various methods returns to schooling using individual observations from the labor force survey. The more conventional OLS regressions are first applied to allow comparison with many studies and the semi-parametric estimates. But the semi-parametric additive method had to be used in order to check for specification robustness of the model due to the observed violation of the OLS assumption of normal distribution of error terms. The quantile regression was also applied to reflect the income distribution implications of the returns pattern. An additional insight into the returns estimation is given by the inclusion of the effect of being married and marrying well, i.e., whether the spouses are equally or upward matched in education, or not. We find that returns to education are higher the higher the level of education is and that returns to women's education are higher than returns to men's education. Moreover, being married and married well increase earnings. Additionally, there is a fairly high good matching between education classes, i.e., there is substantial intermarriage among college graduates and other college educated and among lower educated individuals. This implies poor social mobility considering that access to education especially at the higher levels is very much constrained by family resources. Intermarriage between college graduates preserves their high social position since access to education is restricted by income. The paper concludes with a list of social issues that emerge from the findings

Pressure effects on the electron-doped high Tc superconductor BaFe(2-x)Co(x)As(2)

Application of pressures or electron-doping through Co substitution into Fe sites transforms the itinerant antiferromagnet BaFe(2)As(2) into a superconductor with the Tc exceeding 20K. We carried out systematic transport measurements of BaFe(2-x)Co(x)As(2) superconductors in pressures up to 2.5GPa, and elucidate the interplay between the effects of electron-doping and pressures. For the underdoped sample with nominal composition x = 0.08, application of pressure strongly suppresses a magnetic instability while enhancing Tc by nearly a factor of two from 11K to 21K. In contrast, the optimally doped x=0.20 sample shows very little enhancement of Tc=22K under applied pressure. Our results strongly suggest that the proximity to a magnetic instability is the key to the mechanism of superconductivity in iron-pnictides.Comment: 5 figure

Digital control implementation to reduce the cost and improve the performance of the control stage of an industrial switch-mode power supply

Personal use of this material is permitted. Permission from IEEE must be obtained for all other uses, in any current or future media, including reprinting/republishing this material for advertising or promotional purposes, creating new collective works, for resale or redistribution to servers or lists, or reuse of any copyrighted component of this work in other works. D. A. Díez, O. M. García, J. A. Oliver, P. Alou, F. Moreno, B. Duret, J. A. Cobos, F. V. Canales, and A. de Castro, "Digital control implementation to reduce the cost and improve the performance of the control stage of an industrial switch-mode power supply", in 2011 IEEE Energy Conversion Congress and Exposition (ECCE), Phoenix (AZ), 2011, pp. 2930 - 2935The main objective of this work is the design and implementation of the digital control stage of a 280W AC/DC industrial power supply in a single low-cost microcontroller to replace the analog control stage. The switch-mode power supply (SMPS) consists of a PFC boost converter with fixed frequency operation and a variable frequency LLC series resonant DC/DC converter. Input voltage range is 85VRMS-550VRMS and the output voltage range is 24V-28V. A digital controller is especially suitable for this kind of SMPS to implement its multiple functionalities and to keep the efficiency and the performance high over the wide range of input voltages. Additional advantages of the digital control are reliability and size. The optimized design and implementation of the digital control stage it is presented. Experimental results show the stable operation of the controlled system and an estimation of the cost reduction achieved with the digital control stage

Spectral signatures of reorganised brain networks in disorders of consciousness.

Theoretical advances in the science of consciousness have proposed that it is concomitant with balanced cortical integration and differentiation, enabled by efficient networks of information transfer across multiple scales. Here, we apply graph theory to compare key signatures of such networks in high-density electroencephalographic data from 32 patients with chronic disorders of consciousness, against normative data from healthy controls. Based on connectivity within canonical frequency bands, we found that patient networks had reduced local and global efficiency, and fewer hubs in the alpha band. We devised a novel topographical metric, termed modular span, which showed that the alpha network modules in patients were also spatially circumscribed, lacking the structured long-distance interactions commonly observed in the healthy controls. Importantly however, these differences between graph-theoretic metrics were partially reversed in delta and theta band networks, which were also significantly more similar to each other in patients than controls. Going further, we found that metrics of alpha network efficiency also correlated with the degree of behavioural awareness. Intriguingly, some patients in behaviourally unresponsive vegetative states who demonstrated evidence of covert awareness with functional neuroimaging stood out from this trend: they had alpha networks that were remarkably well preserved and similar to those observed in the controls. Taken together, our findings inform current understanding of disorders of consciousness by highlighting the distinctive brain networks that characterise them. In the significant minority of vegetative patients who follow commands in neuroimaging tests, they point to putative network mechanisms that could support cognitive function and consciousness despite profound behavioural impairment.This work was supported by grants from the Wellcome Trust [WT093811MA to T.B.]; the James S. McDonnell Foundation [to A.M.O. and J.D.P.]; the UK Medical Research Council [U.1055.01.002.00001.01 to A.M.O. and J.D.P.]; the Canada Excellence Research Chairs program [to A.M.O.]; the National Institute for Health Research Cambridge Biomedical Research Centre [to J.D.P.]; and the National Institute for Health Research Senior Investigator and Healthcare Technology Cooperative awards [to J.D.P.].This is the final version of the article. It first appeared from PLOS via http://dx.doi.org

Density fluctuations and single-particle dynamics in liquid lithium

The single-particle and collective dynamical properties of liquid lithium have been evaluated at several thermodynamic states near the triple point. This is performed within the framework of mode-coupling theory, using a self-consistent scheme which, starting from the known static structure of the liquid, allows the theoretical calculation of several dynamical properties. Special attention is devoted to several aspects of the single-particle dynamics, which are discussed as a function of the thermodynamic state. The results are compared with those of Molecular Dynamics simulations and other theoretical approaches.Comment: 31 pages (in preprint format), 14 figures. Submitted to Phys. Rev.