222 research outputs found

    Hierarchical Dobinski-type relations via substitution and the moment problem

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    We consider the transformation properties of integer sequences arising from the normal ordering of exponentiated boson ([a,a*]=1) monomials of the form exp(x (a*)^r a), r=1,2,..., under the composition of their exponential generating functions (egf). They turn out to be of Sheffer-type. We demonstrate that two key properties of these sequences remain preserved under substitutional composition: (a)the property of being the solution of the Stieltjes moment problem; and (b) the representation of these sequences through infinite series (Dobinski-type relations). We present a number of examples of such composition satisfying properties (a) and (b). We obtain new Dobinski-type formulas and solve the associated moment problem for several hierarchically defined combinatorial families of sequences.Comment: 14 pages, 31 reference

    Influence of reaction atmosphere (H2O, N2, H2, CO2, CO) on fluidized-bed fast pyrolysis of biomass using detailed tar vapor chemistry in computational fluid dynamics

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    Secondary pyrolysis in fluidized bed fast pyrolysis of biomass is the focus of this work. A novel computational fluid dynamics (CFD) model coupled with a comprehensive chemistry scheme (134 species and 4169 reactions, in CHEMKIN format) has been developed to investigate this complex phenomenon. Previous results from a transient three-dimensional model of primary pyrolysis were used for the source terms of primary products in this model. A parametric study of reaction atmospheres (H2O, N2, H2, CO2, CO) has been performed. For the N2 and H2O atmosphere, results of the model compared favorably to experimentally obtained yields after the temperature was adjusted to a value higher than that used in experiments. One notable deviation versus experiments is pyrolytic water yield and yield of higher hydrocarbons. The model suggests a not overly strong impact of the reaction atmosphere. However, both chemical and physical effects were observed. Most notably, effects could be seen on the yield of various compounds, temperature profile throughout the reactor system, residence time, radical concentration, and turbulent intensity. At the investigated temperature (873 K), turbulent intensity appeared to have the strongest influence on liquid yield. With the aid of acceleration techniques, most importantly dimension reduction, chemistry agglomeration, and in-situ tabulation, a converged solution could be obtained within a reasonable time (∌30 h). As such, a new potentially useful method has been suggested for numerical analysis of fast pyrolysis

    Generalized Fock spaces and the Stirling numbers

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    The Bargmann-Fock-Segal space plays an important role in mathematical physics, and has been extended into a number of directions. In the present paper we imbed this space into a Gelfand triple. The spaces forming the Fr\'echet part (i.e. the space of test functions) of the triple are characterized both in a geometric way and in terms of the adjoint of multiplication by the complex variable, using the Stirling numbers of the second kind. The dual of the space of test functions has a topological algebra structure, of the kind introduced and studied by the first named author and G. Salomon.Comment: revised versio

    Dobinski-type relations and the Log-normal distribution

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    We consider sequences of generalized Bell numbers B(n), n=0,1,... for which there exist Dobinski-type summation formulas; that is, where B(n) is represented as an infinite sum over k of terms P(k)^n/D(k). These include the standard Bell numbers and their generalizations appearing in the normal ordering of powers of boson monomials, as well as variants of the "ordered" Bell numbers. For any such B we demonstrate that every positive integral power of B(m(n)), where m(n) is a quadratic function of n with positive integral coefficients, is the n-th moment of a positive function on the positive real axis, given by a weighted infinite sum of log-normal distributions.Comment: 7 pages, 2 Figure

    Indicators of resilience in socio-ecological production landscapes (SEPLs)

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    The following policy report constitutes an important supplement to a set of 20 indicators for resilience in socio-ecological production landscapes (SEPLs) that was developed over the course of joint collaboration between Bioversity International and the United Nations University Institute of Advanced Studies (UNU-IAS). The indicators were disseminated widely in pamphlet form for the first time in March 2012. Subsequently, a need was identified for sharing a more in-depth overview of the considerations that went into creating this list of indicators as well as the outcomes of initial field-testing

    Polymorphisms in RAD51, XRCC2 and XRCC3 genes of the homologous recombination repair in colorectal cancer—a case control study

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    XRCC2 and XRCC3 proteins are structurally and functionally related to RAD51 which play an important role in the homologous recombination, the process frequently involved in cancer transformation. In our previous work we show that the 135G>C polymorphism (rs1801320) of the RAD51 gene can modify the effect of the Thr241Met polymorphism (rs861539) of the XRCC3 gene. We tested the association between the 135G>C polymorphism of the RAD51 gene, the Thr241Met polymorphism of the XRCC3 gene and the Arg188His polymorphism (rs3218536) of the XRCC2 gene and colorectal cancer risk and clinicopathological parameters. Polymorphisms were evaluated by restriction fragment length polymorphism polymerase chain reaction (RFLP-PCR) in 100 patients with invasive adenocarcinoma of the colon and in 100 sex, age and ethnicity matched cancer–free controls. We stratified the patients by genotypes, tumour Duke’s and TNM stage and calculated the linkage of each genotype with each stratum. Carriers of Arg188Arg/Me241tMet, His188His/Thr241Thr and His188His/G135G genotypes had an increased risk of colorectal cancer occurrence (OR 5.70, 95% CI 1.10–29.5; OR 12.4, 95% CI 1.63–94.9; OR 5.88, 95% CI 1.21–28.5, respectively). The C135C genotype decreased the risk of colorectal cancer singly (OR 0.06, 95% CI 0.02–0.22) as well as in combination with other two polymorphisms. TNM and Duke’s staging were not related to any of these polymorphisms. Our results suggest that the 135G>C polymorphism of the RAD51 gene can be an independent marker of colorectal cancer risk. The Thr241Met polymorphism of the XRCC3 gene and the Arg188His polymorphism of the XRCC2 gene can modify the risk of colorectal cancer
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