Influence of processing parameters on the recrystallized microstructure of extra-low-carbon steels

This article deals with the influence of processing parameters of a new procedure for ferritic rolling on the recrystallized microstructure of extra-low-carbon (ELC) steels. Parameters such as coil transfer temperature and degree of reduction during ferritic rolling are shown to control the morphology of cementite particles and the precipitation of AIN process. The recrystallized grain morphology and the percentage of recrystallization after annealing cycles simulating the industrial coiling process are shown to be strongly influenced by processing parameters.Peer Reviewe

Real-Time and Low-Cost Sensing Technique Based on Photonic Bandgap Structures

This paper was published in OPTICS LETTERS and is made available as an electronic reprint with the permission of OSA. The paper can be found at the following URL on the OSA website: http://dx.doi.org/10.1364/OL.36.002707. Systematic or multiple reproduction or distribution to multiple locations via electronic or other means is prohibited and is subject to penalties under law[EN] A technique for the development of low-cost and high-sensitivity photonic biosensing devices is proposed and experimentally demonstrated. In this technique, a photonic bandgap structure is used as transducer, but its readout is performed by simply using a broadband source, an optical filter, and a power meter, without the need of obtaining the transmission spectrum of the structure; thus, a really low-cost system and real-time results are achieved. Experimental results show that it is possible to detect very low refractive index variations, achieving a detection limit below 2 x 10(-6) refractive index units using this low-cost measuring technique. (C) 2011 Optical Society of America[This work was funded by the Spanish Ministerio de Ciencia e Innovacion (MICINN) under contracts TEC2008-06333, JCI-009-5805, and TEC2008-05490. Support by the Universidad Politecnica de Valencia through program PAID-06-09 and the Conselleria d'Educacio through program GV-2010-031 is acknowledged.García Castelló, J.; Toccafondo, V.; Pérez Millán, P.; Sánchez Losilla, N.; Cruz, JL.; Andres, MV.; García-Rupérez, J. (2011). Real-Time and Low-Cost Sensing Technique Based on Photonic Bandgap Structures. Optics Letters. 36(14):2707-2709. https://doi.org/10.1364/OL.36.002707S270727093614Fan, X., White, I. M., Shopova, S. I., Zhu, H., Suter, J. D., & Sun, Y. (2008). Sensitive optical biosensors for unlabeled targets: A review. Analytica Chimica Acta, 620(1-2), 8-26. doi:10.1016/j.aca.2008.05.022Homola, J., Yee, S. S., & Gauglitz, G. (1999). Surface plasmon resonance sensors: review. Sensors and Actuators B: Chemical, 54(1-2), 3-15. doi:10.1016/s0925-4005(98)00321-9Kersey, A. D., Davis, M. A., Patrick, H. J., LeBlanc, M., Koo, K. P., Askins, C. G., … Friebele, E. J. (1997). Fiber grating sensors. Journal of Lightwave Technology, 15(8), 1442-1463. doi:10.1109/50.618377De Vos, K., Bartolozzi, I., Schacht, E., Bienstman, P., & Baets, R. (2007). Silicon-on-Insulator microring resonator for sensitive and label-free biosensing. Optics Express, 15(12), 7610. doi:10.1364/oe.15.007610Iqbal, M., Gleeson, M. A., Spaugh, B., Tybor, F., Gunn, W. G., Hochberg, M., … Gunn, L. C. (2010). Label-Free Biosensor Arrays Based on Silicon Ring Resonators and High-Speed Optical Scanning Instrumentation. IEEE Journal of Selected Topics in Quantum Electronics, 16(3), 654-661. doi:10.1109/jstqe.2009.2032510Xu, D.-X., Vachon, M., Densmore, A., Ma, R., Delâge, A., Janz, S., … Schmid, J. H. (2010). Label-free biosensor array based on silicon-on-insulator ring resonators addressed using a WDM approach. Optics Letters, 35(16), 2771. doi:10.1364/ol.35.002771Skivesen, N., Têtu, A., Kristensen, M., Kjems, J., Frandsen, L. H., & Borel, P. I. (2007). Photonic-crystal waveguide biosensor. Optics Express, 15(6), 3169. doi:10.1364/oe.15.003169Lee, M. R., & Fauchet, P. M. (2007). Nanoscale microcavity sensor for single particle detection. Optics Letters, 32(22), 3284. doi:10.1364/ol.32.003284García-Rupérez, J., Toccafondo, V., Bañuls, M. J., Castelló, J. G., Griol, A., Peransi-Llopis, S., & Maquieira, Á. (2010). Label-free antibody detection using band edge fringes in SOI planar photonic crystal waveguides in the slow-light regime. Optics Express, 18(23), 24276. doi:10.1364/oe.18.024276Toccafondo, V., García-Rupérez, J., Bañuls, M. J., Griol, A., Castelló, J. G., Peransi-Llopis, S., & Maquieira, A. (2010). Single-strand DNA detection using a planar photonic-crystal-waveguide-based sensor. Optics Letters, 35(21), 3673. doi:10.1364/ol.35.003673Luff, B. J., Wilson, R., Schiffrin, D. J., Harris, R. D., & Wilkinson, J. S. (1996). Integrated-optical directional coupler biosensor. Optics Letters, 21(8), 618. doi:10.1364/ol.21.000618Sepúlveda, B., Río, J. S. del, Moreno, M., Blanco, F. J., Mayora, K., Domínguez, C., & Lechuga, L. M. (2006). Optical biosensor microsystems based on the integration of highly sensitive Mach–Zehnder interferometer devices. Journal of Optics A: Pure and Applied Optics, 8(7), S561-S566. doi:10.1088/1464-4258/8/7/s41Densmore, A., Vachon, M., Xu, D.-X., Janz, S., Ma, R., Li, Y.-H., … Schmid, J. H. (2009). Silicon photonic wire biosensor array for multiplexed real-time and label-free molecular detection. Optics Letters, 34(23), 3598. doi:10.1364/ol.34.003598Povinelli, M. L., Johnson, S. G., & Joannopoulos, J. D. (2005). Slow-light, band-edge waveguides for tunable time delays. Optics Express, 13(18), 7145. doi:10.1364/opex.13.007145Garcia, J., Sanchis, P., Martinez, A., & Marti, J. (2008). 1D periodic structures for slow-wave induced non-linearity enhancement. Optics Express, 16(5), 3146. doi:10.1364/oe.16.003146Pérez-Millán, P., Torres-Peiró, S., Cruz, J. L., & Andrés, M. V. (2008). Fabrication of chirped fiber Bragg gratings by simple combination of stretching movements. Optical Fiber Technology, 14(1), 49-53. doi:10.1016/j.yofte.2007.07.00

Enantioselective Synthesis of Seven-Membered Carbo- and Heterocyles by Organocatalyzed Intramolecular Michael Addition

Producción CientíficaUnprecedented diastereo- and enantioselective synthesis of seven-membered rings has been achieved by organocatalyzed intramolecular Michael addition of enals bearing β-diketone functionality. The cyclization leads to 2,3-disubstituted cycloheptanone derivatives in high yield and excellent stereoselectivity. The same organocatalyzed cyclization process has been used to prepare six-membered homologs, but with lower stereoselectivity.Ministerio de Economía, Industria y Competitividad (CTQ 2011-28487)Junta de Castilla y León (programa de apoyo a proyectos de investigación – Ref. VA064U13)Universidad de Valladolid for a pre-doctoral fellowship

Thermal decomposition of single hydroxychlorides of nickel, copper and cobalto

The thermal decomposition reactions of Ni(OH)Cl.l½H20 in still air and in nitrogen and β-CO2(OH)3Cl and γ-Cu2(OH)3Cl in nitrogen atmosphere, have been studied by DTA and TG analysis, and the intermediates and final products have been characterized by x-ray diffraction and infrared spectroscop. The thermal evolution ot the above indicated compounds under dynamic vacuum conditions has be en studied with the aid of an x-ray high teaperature diffraction chamber. They reveals that in these conditions, the pure metallic nickel, copper and cobalt can be obtained at comparative low temperature. The infrared spectra of thése hydroxychlorides have been tentatively assigned

Averaged Dynamic Modeling and Control of a Quasi-Z-Source Inverter for Wind Power Applications

Typically, permanent magnet synchronous generator (PMSG)-driven wind turbines (WTs) present a two-stage power converter topology based on a DC/DC boost converter and voltage source inverter. In this study, this configuration is substituted by a quasi-Z-source inverter (qZSI), which is an attractive solution for boosting and converting the voltage from DC to AC in a single stage. A 2 MW PMSG WT with qZSI was studied herein. A switched dynamic model (SDM) of the qZSI (including the modeling of all switches and firing pulses) is not recommended for steady-state stability studies, long-term simulations, or large electric power systems. For such studies, two averaged dynamic models are proposed in this work. Both models present the same control system as the SDM, except for the generation of firing pulses, which is not necessary in the averaged models. The two proposed models were evaluated and compared with the SDM in the large-scale WT under different operating conditions, such as wind speed fluctuations, variable power references, and grid disturbances (voltage sag and 3(rd) and 5(th) order harmonics injection), in order to demonstrate their adequacy to represent the system response with a high reduction in the simulation time and computational efforts.This work was supported in part by the Spain's Ministerio de Ciencia, Innovacion y Universidades (MCIU), Agencia Estatal de Investigacion (AEI), and Fondo Europeo de Desarrollo Regional (FEDER) Union Europea (UE) under Grant RTI2018-095720-B-C32, in part by the National Council of Technological and Scientific Development (CNPq), Brazil, in part by the Federal Center for Technological Education of Minas Gerais, Brazil, under Process 23062-010087/2017-51, and in part by the Regional Ministry of Economic Transformation, Industry, Knowledge and Universities of Junta de Andalucia under Grant PY20_00317

Standardization of 18F by Digital β(LS)-γ Coincidence Counting

The nuclide 18F disintegrates to 18O by beta+ emission (96.86%) and electron capture (3.14%) with a half-life of 1.8288 h. It is widely used in nuclear medicine for positron emission tomography (PET). Because of its short half-life this nuclide requires the development of fast measuring methods to be standardized. The combination of LSC methods with digital techniques proves to be a good alternative to get low uncertainties for this, and other, short lived nuclides. A radioactive solution of 18F has been standardized by coincidence counting with a LSC, using the logical sum of double coincidences in a TDCR array and a NaI scintillation detector. The results show good consistency with other techniques like 4Pi-gamma and LSC.Fil: Rodrigues, D.. Comision Nacional de Energia Atomica. Gerencia de Area de Aplicaciones de la Tecnología Nuclear. Gerencia D/aplicaciones y Tec de Radioisotopos; ArgentinaFil: Balpardo, C.. Comision Nacional de Energia Atomica. Gerencia de Area de Aplicaciones de la Tecnología Nuclear. Gerencia D/aplicaciones y Tec de Radioisotopos; ArgentinaFil: Cassete, P.. Aboratoire National Henri Becquerel; FranciaFil: Arenillas P.. Comisión Nacional de Energía Atómica. Centro Atómico Ezeiza; ArgentinaFil: Capoulat, Maria Eugenia. Comisión Nacional de Energía Atómica. Centro Atómico Ezeiza; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Ceruti, G.. Comisión Nacional de Energía Atómica. Centro Atómico Ezeiza; ArgentinaFil: García-Toraño Andrés, Eduardo. Centro de Investigación Energeticas Medioambientales y Tecnología; España. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentin

Effect of Design Parameters on Compressive and Split Tensile Strength of Self-Compacting Concrete with Recycled Aggregate: An Overview

[EN] One of the prime objectives of this review is to understand the role of design parameters on the mechanical properties (Compressive and split tensile strength) of Self-Compacting Concrete (SCC) with recycled aggregates (Recycled Coarse Aggregates (RCA) and Recycled Fine Aggregates (RFA)). The design parameters considered for review are Water to Cement (W/C) ratio, Water to Binder (W/B) ratio, Total Aggregates to Cement (TA/C) ratio, Fine Aggregate to Coarse Aggregate (FA/CA) ratio, Water to Solid (W/S) ratio in percentage, superplasticizer (SP) content (kg/cu.m), replacement percentage of RCA, and replacement percentage of RFA. It is observed that with respect to different grades of SCC, designed parameters affect the mechanical properties of SCC with recycled aggregates

Chiral Ureas and Thioureas Supported on Polystyrene for Enantioselective Aza-Henry Reaction in Solvent-free conditions

Producción CientíficaNovel bifunctional ureas and thioureas inmovilized on sulfonylpystyrene have been prepared as recoverable and reusable organocatalysts and used in the stereoselective aza-Henry reaction under solvent-free conditions. The activity and stereoselection of the catalysts are dependent on the length of the tether bringing the active site and the polymer, being the catalyst derived from 1,6-hexane diamine the best one. It has been also demonstrated that the supported catalysts are more effective than the homologous soluble catalysts.Ministerio de Economía, Industria y Competitividad (CTQ 2011-28487)Junta de Castilla y León (programa de apoyo a proyectos de investigación – Ref. VA064U13

Impact of texture TDS and flavour TDS tasks and of chocolate-chip biscuit characteristics on oral processing features

[EN] The objective of the present study was to investigate differences in oral activity when biscuits of the same type but with subtle composition differences are consumed and how performing a Temporal Dominance of Sensations (TDS) task modifies the way one eats. In addition, comparisons were made between performing a texture TDS (T-TDS) and a flavour TDS (F-TDS). Oral activity while eating biscuits with and without conducting a TDS task was recorded using a 3.dimensional motion capture system to monitor the evolution of jaw movements. The results showed that oral activity evolved over the consumption time, differed depending on the texture of the sample and was affected to a small but significant extent when a TDS task was performed simultaneously (the differences averaged < 4 cycles, 1 s in duration, 0.1 cycles/s in frequency, and 1 mm in lateral displacement). The biscuit samples were affected equally. Almost no differences were found on comparing oral activity during the execution of the T-TDS and the F-TDS tasks. Overall, the present results show differences in oral activity even for food products of the same category with subtle differences in composition. Performing TDS tasks (regardless of their modality) during sample consumption affected the total number, frequency and lateral amplitude of the chewing movements which should be taken into account for future research. However, these differences were small and affected both samples equally.The authors are grateful to the Spanish Ministry of the Economy and Competitiveness (AGL-2016-75403-R, Spain) and to the Regional Government of Valencia (Project Prometeo 2017/189, Spain) for financial support.Rizo, A.; Jimenez-Pérez, I.; Camacho-García, A.; Fiszman, S.; Pérez-Soriano, P.; Tarrega, A. (2019). Impact of texture TDS and flavour TDS tasks and of chocolate-chip biscuit characteristics on oral processing features. Food Quality and Preference. 76:109-117. https://doi.org/10.1016/j.foodqual.2019.04.005S1091177