70 research outputs found
Structural lubricity: Role of dimension and symmetry
When two chemically passivated solids are brought into contact, interfacial
interactions between the solids compete with intrabulk elastic forces. The
relative importance of these interactions, which are length-scale dependent,
will be estimated using scaling arguments. If elastic interactions dominate on
all length scales, solids will move as essentially rigid objects. This would
imply superlow kinetic friction in UHV, provided wear was absent. The results
of the scaling study depend on the symmetry of the surfaces and the
dimensionalities of interface and solids. Some examples are discussed
explicitly such as contacts between disordered three-dimensional solids and
linear bearings realized from multiwall carbon nanotubes.Comment: 7 pages, 1 figur
Combined numerical and experimental investigation of the micro-hydrodynamics of chevron-based textured patterns influencing conjunctional friction of sliding contacts
Reciprocating and low-speed sliding contacts can experience increased friction because of solid boundary interactions. Use of surface texturing has been shown to mitigate undue boundary friction and improve energy efficiency. A combined numerical and experimental investigation is presented to ascertain the beneficial effect of pressure perturbation caused by micro-hydrodynamics of entrapped reservoirs of lubricant in cavities of textured forms as well as improved micro-wedge flow. The results show good agreement between numerical predictions and experimental measurements using a precision sliding rig with a floating bed-plate. Results show that the texture pattern and distribution can be optimised for given conditions, dependent on the intended application under laboratory conditions. The translation of the same into practical in-field applications must be carried out in conjunction with the cost of fabrication and perceived economic gain. This means that near optimal conditions may suffice for most application areas and in practice lesser benefits may accrue than that obtained under ideal laboratory conditions
Nanoscale Contact Mechanics between Two Grafted Polyelectrolyte Surfaces
The adhesive and frictional behavior of end-grafted poly[2-(dimethylamino)ethyl methacrylate] (PDMAEMA) films (brushes) in contact with atomic force microscope tips from which PDMAEMA or poly(methacrylic acid) (PMAA) were grafted has been shown to be a strong function of pH in aqueous solution. The interaction between the brush-coated surfaces is determined by a combination of electrostatic and noncovalent interactions, modulated by the effect of the solvation state on the brush and the resulting area of contact between the probe and the surface. For cationic PDMAEMA-PDMAEMA contacts at low pH, the brushes are highly solvated; a combination of electrostatic repulsion and a high degree of solvation (leading to a significant osmotic pressure) leads to a small area of contact, weak adhesion, and energy dissipation through plowing. As the pH increases, the electrostatic repulsion and the osmotic pressure decrease, leading to an increase in the area of contact and a concomitant increase in the strength of adhesion through hydrophobic interactions; as a consequence, the friction-load relationship becomes nonlinear as shear processes contribute to friction and the mechanics are fitted by DMT theory and, at higher pH, by the JKR model. For PDMAEMA-PMAA, the electrostatic interaction is attractive at neutral pH, leading to a large adhesion force, a large area of contact, and a nonlinear friction-load relationship. However, as the pH becomes either very small or very large, a significant charge is acquired by one of the contacting surfaces, leading to a large amount of bound solvent and a significant osmotic pressure that resists deformation. As a consequence, the area of contact is small, adhesion forces are reduced, and the friction-load relationship is linear, with energy dissipation dominated by molecular plowing
Long Term Friction: from Stick-Slip to Stable Sliding
We have devised an original laboratory experiment where we investigate the
frictional behaviour of a single crystal salt slider over a large number of
deformation cycles. Because of its physical properties, salt, a surrogate for
natural faults, allows for friction and plastic deformation and pressure
solution creep to be efficient on the same timescale. During the same
experiment, we observe a continuous change of the frictional behaviour of the
slider under constant conditions of stiffness, temperature and loading
velocity. The stick-slip regime is progressively vanishing, eventually reaching
the stable sliding regime. Concomitantly, the contact interface, observed under
the microscope, develops a striated morphology with contact asperities increase
in length and width, arguing for an increase in the critical slip distance dc.
Complementary experiments including velocity jumps show that the frictional
parameters of the rate and state friction law, a and b, progressively vanish
with the cumulative slip. In our experimental conditions, the ultimate stage of
friction is therefore rate and state independent.Comment: 10 pages; 4 figures; 1 Tabl
Physio-chemical hydrodynamic mechanism underlying the formation of thin adsorbed boundary films
Polymers and biopolymers at interfaces
This review updates recent progress in the understanding of the behaviour of polymers at surfaces and interfaces, highlighting examples in the areas of wetting, dewetting, crystallization, and 'smart' materials. Recent developments in analysis tools have yielded a large increase in the study of biological systems, and some of these will also be discussed, focussing on areas where surfaces are important. These areas include molecular binding events and protein adsorption as well as the mapping of the surfaces of cells. Important techniques commonly used for the analysis of surfaces and interfaces are discussed separately to aid the understanding of their application
A Three‐Dimensional Approach and Open Source Structure for the Design and Experimentation of Teaching‐Learning Sequences: The case of friction
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