314 research outputs found
Effect of tungstate on acetate and ethanol production by the electrosynthetic bacterium <i>Sporomusa ovata</i>
Additional file 1: Table S1. Primers for RT-qPCR
Anodic Oxidation of m-terphenyl thio-, seleno-and telluroethers: Lowered oxidation potentials due to chalcogen.•••π interaction
The electrochemistry of m-terphenylthio-, seleno-, and telluroethers was studied
using cyclic voltammetry in acetonitrile. All of the compounds studied showed irreversible
oxidations. The first oxidation potentials for the thio- and selenoethers are less positive than
expected. This facilitation in oxidation is ascribed to through-space S···π and Se···π interaction,
respectively, on removal of an electron. No evidence for a comparable effect was
found for the phenyltelluro-ethers studied
Solid Separation from a Mixed Suspension through Electric‐Field‐Enhanced Crystallization
When applied to a pure component suspension in an apolar solvent, a strong inhomogeneous electric field induces particle movement, and the particles are collected at the surface of one of the two electrodes. This new phenomenon was used to separately isolate two organic crystalline compounds, phenazine and caffeine, from their suspension in 1,4-dioxane. First, crystals of both compounds were collected at different electrodes under the influence of an electric field. Subsequent cooling crystallization enabled the immobilization and growth of the particles on the electrodes, which were separately collected after the experiment with purities greater than 91 %. This method can be further developed into a technique for crystal separation and recovery in complex multicomponent suspensions of industrial processes
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