89 research outputs found
Relaxation and derelaxation of pure and hydrogenated amorphous silicon during thermal annealing experiments
The structural relaxation of pure amorphous silicon (a-Si) and hydrogenated
amorphous silicon (a-Si:H) materials, that occurs during thermal annealing
experiments, has been analysed by Raman spectroscopy and differential scanning
calorimetry. Unlike a-Si, the heat evolved from a-Si:H cannot be explained by
relaxation of the Si-Si network strain, but it reveals a derelaxation of the
bond angle strain. Since the state of relaxation after annealing is very
similar for pure and hydrogenated materials, our results give strong
experimental support to the predicted configurational gap between a-Si and
crystalline silicon.Comment: 15 pages, 3 figures, 1 table to be published in Applied Physics
Letter
Probing the electron-phonon coupling in ozone-doped graphene by Raman spectroscopy
We have investigated the effects of ozone treatment on graphene by Raman
scattering. Sequential ozone short-exposure cycles resulted in increasing the
doping levels as inferred from the blue shift of the 2 and peak
frequencies, without introducing significant disorder. The two-phonon 2 and
2 Raman peak intensities show a significant decrease, while, on the
contrary, the one-phonon G Raman peak intensity remains constant for the whole
exposure process. The former reflects the dynamics of the photoexcited
electrons (holes) and, specifically, the increase of the electron-electron
scattering rate with doping. From the ratio of 2 to 2 intensities, which
remains constant with doping, we could extract the ratio of electron-phonon
coupling parameters. This ratio is found independent on the number of layers up
to ten layers. Moreover, the rate of decrease of 2 and 2 intensities
with doping was found to slowdown inversely proportional to the number of
graphene layers, revealing the increase of the electron-electron collision
probability
A novel high resolution contactless technique for thermal field mapping and thermal conductivity determination: Two-Laser Raman Thermometry
We present a novel high resolution contactless technique for thermal
conductivity determination and thermal field mapping based on creating a
thermal distribution of phonons using a heating laser, while a second laser
probes the local temperature through the spectral position of a Raman active
mode. The spatial resolution can be as small as nm, whereas its
temperature accuracy is K. We validate this technique investigating the
thermal properties of three free-standing single crystalline Si membranes with
thickness of 250, 1000, and 2000 nm. We show that for 2-dimensional materials
such as free-standing membranes or thin films, and for small temperature
gradients, the thermal field decays as in the diffusive
limit. The case of large temperature gradients within the membranes leads to an
exponential decay of the thermal field, . The
results demonstrate the full potential of this new contactless method for
quantitative determination of thermal properties. The range of materials to
which this method is applicable reaches far beyond the here demonstrated case
of Si, as the only requirement is the presence of a Raman active mode
Lifetimes of Confined Acoustic Phonons in Ultra-Thin Silicon Membranes
We study the relaxation of coherent acoustic phonon modes with frequencies up
to 500 GHz in ultra-thin free-standing silicon membranes. Using an ultrafast
pump-probe technique of asynchronous optical sampling, we observe that the
decay time of the first-order dilatational mode decreases significantly from
\sim 4.7 ns to 5 ps with decreasing membrane thickness from \sim 194 to 8 nm.
The experimental results are compared with theories considering both intrinsic
phonon-phonon interactions and extrinsic surface roughness scattering including
a wavelength-dependent specularity. Our results provide insight to understand
some of the limits of nanomechanical resonators and thermal transport in
nanostructures
Crossover from ballistic to diffusive thermal transport in suspended graphene membranes
We report heat transport measurements on suspended single-layer graphene disks with radius of 150-1600 nm using a high-vacuum scanning thermal microscope. The results of this study revealed a radius-dependent thermal contact resistance between tip and graphene, with values between 1.15 and 1.52 × 10 KW. The observed scaling of thermal resistance with radius is interpreted in terms of ballistic phonon transport in suspended graphene discs with radius smaller than 775 nm. In larger suspended graphene discs (radius >775 nm), the thermal resistance increases with radius, which is attributed to in-plane heat transport being limited by phonon-phonon resistive scattering processes, which resulted in a transition from ballistic to diffusive thermal transport. In addition, by simultaneously mapping topography and steady-state heat flux signals between a self-heated scanning probe sensor and graphene with 17 nm thermal spatial resolution, we demonstrated that the surface quality of the suspended graphene and its connectivity with the Si/SiO substrate play a determining role in thermal transport. Our approach allows the investigation of heat transport in suspended graphene at sub-micrometre length scales and overcomes major limitations of conventional experimental methods usually caused by extrinsic thermal contact resistances, assumptions on the value of the graphene's optical absorbance and limited thermal spatial resolution
Estudio clínico-epidemiológico de leptospirosis en humanos y reservorios en Yucatán, México
A leptospirosis clinical-epidemiological study was made in humans and reservoirs in the state of Yucatán, México. Interviews and serological analyses were made on 400 persons from an open population, 439 probable cases of leptospirosis and 1060 animal reservoirs (cows, pigs, dogs, rats and opossums). IgM Leptospira DipstickTM and Microscopic Agglutination Test (MAT) was used to detect human antibodies to leptospiras and serovar respectively. Leptospirosis incidence in humans was 2.2/100,000 inhab. in 1998, 0.7/100,000 in 1999 and 0.9/100,000 in 2000. Overall seroprevalence was 14.2%, relatively unchanged from seroprevalences observed 20 years ago. Highest seropositivity was found in people over 56 years of age, predominating males over females. Predominant serovars in the open population were tarassovi, hardjo, pomona and panama. Leptospirosis cases were most frequent in rural areas, and the anicteric course predominated over the icteric. The panama, icterohaemorrhagiae and pomona serovars predominated in both anicteric and icteric courses. Dogs, pigs and rodents had the highest seropositivity among the reservoirs. Contact with rodents and natural water sources were significant factors (p ;£; 0.05). Human cases (74%) occurred during the rainy season. It is concluded that leptospirosis is still a serious illness with important clinical and epidemiological implications in the state of Yucatán, Mexico.Un estudio clínico-epidemiológico de leptospirosis fue realizado en humanos y reservorios en el estado de Yucatán, México. Se entrevistaron y analizaron mediante serología 400 personas en población abierta, 439 pacientes sospechosos y 1060 reservorios (bovinos, cerdos, perros, roedores y zarigüeyas). En humanos para la detección de anticuerpos se utilizó IgM Dipstick LeptospiraTM y la prueba de aglutinación microscópica (MAT) para detectar serovar. La incidencia en humanos fue de 2.2/100,000, 0.7/100,000 y 0.9/100,000 habitantes para los años 1998, 1999 y 2000 respectivamente y la seroprevalencia de 14.2%. La frecuencia más alta de seropositivos se encontró en mayores de 56 años, predominando el sexo masculino sobre el femenino. Predominó en población abierta el serovar tarassovi siguiendo en importancia hardjo, pomona y panamá. Los casos fueron más frecuentes en el área rural y el curso anictérico predominó sobre el ictérico. Panamá, icterohaemorrhagiae y pomona predominaron en ambos cursos de la enfermedad. Los perros cerdos y roedores tuvieron mayor positividad. El contacto con roedores y depósitos naturales de agua fue significativo (p ;£; 0.05). El 74.3% de los casos se presentaron en época de lluvia. En conclusión la leptospirosis en Yucatán, México, sigue siendo una entidad patológica de importancia tanto clínica como epidemiológica
Ultra-thin free-standing single crystalline silicon membranes with strain control
We report on fabrication and characterization of ultra-thin suspended single crystalline flat silicon membranes with thickness down to 6 nm. We have developed a method to control the strain in the membranes by adding a strain compensating frame on the silicon membrane perimeter to avoid buckling after the release. We show that by changing the properties of the frame the strain of the membrane can be tuned in controlled manner. Consequently, both the mechanical properties and the band structure can be engineered, and the resulting membranes provide a unique laboratory to study low-dimensional electronic, photonic, and phononic phenomena.Peer reviewe
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