220 research outputs found
Probing dispersion and re-agglomeration phenomena upon melt-mixing of polymer-functionalized graphite nanoplates
A one-step melt-mixing method is proposed to study dispersion and re-agglomeration phenomena of the as-received and functionalized graphite nanoplates in polypropylene melts. Graphite nanoplates were chemically modified via 1,3-dipolar cycloaddition of an azomethine ylide and then grafted with polypropylene-graft-maleic anhydride. The effect of surface functionalization on the dispersion kinetics, nanoparticle re-agglomeration and interface bonding with the polymer is investigated. Nanocomposites with 2 or 10 wt% of as-received and functionalized graphite nanoplates were prepared in a small-scale prototype mixer coupled to a capillary rheometer. Samples were collected along the flow axis and characterized by optical microscopy, scanning electron microscopy and electrical conductivity measurements. The as-received graphite nanoplates tend to re-agglomerate upon stress relaxation of the polymer melt. The covalent attachment of a polymer to the nanoparticle surface enhances the stability of dispersion, delaying the re-agglomeration. Surface modification also improves interfacial interactions and the resulting composites presented improved electrical conductivity.The authors acknowledge the financial support to Project Matepro Optimizing Materials and Processes, with reference NORTE-07-0124-FEDER-000037 by the Programa Operacional Regional do Norte (ON.2) and Portuguese Foundation for the Science and Technology (FCT) for PEst-C/CTM/LA0025/2013. EC acknowledges FCT for a PhD grant SFRH/BD/87214/2012
Star Formation and Dynamics in the Galactic Centre
The centre of our Galaxy is one of the most studied and yet enigmatic places
in the Universe. At a distance of about 8 kpc from our Sun, the Galactic centre
(GC) is the ideal environment to study the extreme processes that take place in
the vicinity of a supermassive black hole (SMBH). Despite the hostile
environment, several tens of early-type stars populate the central parsec of
our Galaxy. A fraction of them lie in a thin ring with mild eccentricity and
inner radius ~0.04 pc, while the S-stars, i.e. the ~30 stars closest to the
SMBH (<0.04 pc), have randomly oriented and highly eccentric orbits. The
formation of such early-type stars has been a puzzle for a long time: molecular
clouds should be tidally disrupted by the SMBH before they can fragment into
stars. We review the main scenarios proposed to explain the formation and the
dynamical evolution of the early-type stars in the GC. In particular, we
discuss the most popular in situ scenarios (accretion disc fragmentation and
molecular cloud disruption) and migration scenarios (star cluster inspiral and
Hills mechanism). We focus on the most pressing challenges that must be faced
to shed light on the process of star formation in the vicinity of a SMBH.Comment: 68 pages, 35 figures; invited review chapter, to be published in
expanded form in Haardt, F., Gorini, V., Moschella, U. and Treves, A.,
'Astrophysical Black Holes'. Lecture Notes in Physics. Springer 201
A gas cloud on its way towards the super-massive black hole in the Galactic Centre
Measurements of stellar orbits provide compelling evidence that the compact
radio source Sagittarius A* at the Galactic Centre is a black hole four million
times the mass of the Sun. With the exception of modest X-ray and infrared
flares, Sgr A* is surprisingly faint, suggesting that the accretion rate and
radiation efficiency near the event horizon are currently very low. Here we
report the presence of a dense gas cloud approximately three times the mass of
Earth that is falling into the accretion zone of Sgr A*. Our observations
tightly constrain the cloud's orbit to be highly eccentric, with an innermost
radius of approach of only ~3,100 times the event horizon that will be reached
in 2013. Over the past three years the cloud has begun to disrupt, probably
mainly through tidal shearing arising from the black hole's gravitational
force. The cloud's dynamic evolution and radiation in the next few years will
probe the properties of the accretion flow and the feeding processes of the
super-massive black hole. The kilo-electronvolt X-ray emission of Sgr A* may
brighten significantly when the cloud reaches pericentre. There may also be a
giant radiation flare several years from now if the cloud breaks up and its
fragments feed gas into the central accretion zone.Comment: in press at Natur
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