Translucent perovskite photovoltaics for building integration

Transparent photovoltaics provide diverse levels of average visible transmittance (AVT) along with concurrent light harvesting, making glass façades and windows accessible for photovoltaics. However, improvements in power conversion efficiency (PCE) and aesthetics are required to enhance commercial viability and public acceptance. This work presents the scalable fabrication of efficient micro-patterned translucent perovskite photovoltaics at optical qualities suited for building integration. Optimized laser-scribed transparent areas (25 μm) mitigate detrimental effects on electrical performance, featuring perovskite solar cells with 44% AVT and demonstrating industrial glass quality through neutral color rendering (CRI 97) and only 3% haze. Highlighting scalability, submodules yield PCEs of 9.0% at 32% AVT (4 cm2 aperture area). The transfer to two-terminal perovskite–perovskite tandem solar cells exhibiting PCEs of 17.7% at 12% AVT and 11.1% at 31% AVT demonstrates the first translucent perovskite tandem photovoltaics. Lastly, the novel concept of transmittance gradients with 7% cm−1 absolute change in AVT and 12.0% PCE for submodules is presented, providing a foundation for architectural individualizations

Vapor phase deposition of perovskite photovoltaics:Short track to commercialization?

While perovskite-based photovoltaics (PV) is progressing toward commercialization, it remains an open question which fabrication technology - solution-based, vapor-based, or combinations - will pave the way to faster economic breakthrough. The vast majority of research studies make use of solution-processed perovskite thin films, which benefit from a rapid optimization feedback and inexpensive to procure tools in modern research laboratories, but vapor phase deposition processes dominate today's established thin-film manufacturing. As research and development of vapor phase processed perovskite thin films are still strongly underrepresented in literature, their full potential is yet to be identified. In this collaborative perspective of academic influenced by industrial views, we convey a balanced viewpoint on the prospects of vapor-based processing of perovskite PV at an industrial scale. Our perspective highlights the conceptual advantages of vapor phase deposition, discusses the most crucial process parameters in a technology assessment, contains an overview about relevant global industry clusters, and provides an outlook on the commercialization perspectives of the perovskite technology in general.</p

An open-access database and analysis tool for perovskite solar cells based on the FAIR data principles

Large datasets are now ubiquitous as technology enables higher-throughput experiments, but rarely can a research field truly benefit from the research data generated due to inconsistent formatting, undocumented storage or improper dissemination. Here we extract all the meaningful device data from peer-reviewed papers on metal-halide perovskite solar cells published so far and make them available in a database. We collect data from over 42,400 photovoltaic devices with up to 100 parameters per device. We then develop open-source and accessible procedures to analyse the data, providing examples of insights that can be gleaned from the analysis of a large dataset. The database, graphics and analysis tools are made available to the community and will continue to evolve as an open-source initiative. This approach of extensively capturing the progress of an entire field, including sorting, interactive exploration and graphical representation of the data, will be applicable to many fields in materials science, engineering and biosciences

An open-access database and analysis tool for perovskite solar cells based on the FAIR data principles

Large datasets are now ubiquitous as technology enables higher-throughput experiments, but rarely can a research field truly benefit from the research data generated due to inconsistent formatting, undocumented storage or improper dissemination. Here we extract all the meaningful device data from peer-reviewed papers on metal-halide perovskite solar cells published so far and make them available in a database. We collect data from over 42, 400 photovoltaic devices with up to 100 parameters per device. We then develop open-source and accessible procedures to analyse the data, providing examples of insights that can be gleaned from the analysis of a large dataset. The database, graphics and analysis tools are made available to the community and will continue to evolve as an open-source initiative. This approach of extensively capturing the progress of an entire field, including sorting, interactive exploration and graphical representation of the data, will be applicable to many fields in materials science, engineering and biosciences. © 2021, The Author(s)

Strategy for large???scale monolithic Perovskite/Silicon tandem solar cell: A review of recent progress

For any solar cell technology to reach the final mass-production/commercialization stage, it must meet all technological, economic, and social criteria such as high efficiency, large-area scalability, long-term stability, price competitiveness, and environmental friendliness of constituent materials. Until now, various solar cell technologies have been proposed and investigated, but only crystalline silicon, CdTe, and CIGS technologies have overcome the threshold of mass-production/commercialization. Recently, a perovskite/silicon (PVK/Si) tandem solar cell technology with high efficiency of 29.1% has been reported, which exceeds the theoretical limit of single-junction solar cells as well as the efficiency of stand-alone silicon or perovskite solar cells. The International Technology Roadmap for Photovoltaics (ITRPV) predicts that silicon-based tandem solar cells will account for about 5% market share in 2029 and among various candidates, the combination of silicon and perovskite is the most likely scenario. Here, we classify and review the PVK/Si tandem solar cell technology in terms of homo- and hetero-junction silicon solar cells, the doping type of the bottom silicon cell, and the corresponding so-called normal and inverted structure of the top perovskite cell, along with mechanical and monolithic tandemization schemes. In particular, we review and discuss the recent advances in manufacturing top perovskite cells using solution and vacuum deposition technology for large-area scalability and specific issues of recombination layers and top transparent electrodes for large-area PVK/Si tandem solar cells, which are indispensable for the final commercialization of tandem solar cells

An open-access database and analysis tool for perovskite solar cells based on the FAIR data principles

AbstractLarge datasets are now ubiquitous as technology enables higher-throughput experiments, but rarely can a research field truly benefit from the research data generated due to inconsistent formatting, undocumented storage or improper dissemination. Here we extract all the meaningful device data from peer-reviewed papers on metal-halide perovskite solar cells published so far and make them available in a database. We collect data from over 42,400 photovoltaic devices with up to 100 parameters per device. We then develop open-source and accessible procedures to analyse the data, providing examples of insights that can be gleaned from the analysis of a large dataset. The database, graphics and analysis tools are made available to the community and will continue to evolve as an open-source initiative. This approach of extensively capturing the progress of an entire field, including sorting, interactive exploration and graphical representation of the data, will be applicable to many fields in materials science, engineering and biosciences.</jats:p

Electron Beam Evaporated Nickel Oxide Hole Transport Layers for Perovskite Based Photovoltaics

High amp; 8208;quality charge carrier transport materials are of key importance for stable and efficient perovskite amp; 8208;based photovoltaics. This work reports on electron amp; 8208;beam amp; 8208;evaporated nickel oxide NiOx layers, resulting in stable power conversion efficiencies PCEs of up to 18.5 when integrated into solar cells employing inkjet amp; 8208;printed perovskite absorbers. By adding oxygen as a process gas and optimizing the layer thickness, transparent and efficient NiOx hole transport layers HTLs are fabricated, exhibiting an average absorptance of only 1 . The versatility of the material is demonstrated for different absorber compositions and deposition techniques. As another highlight of this work, all amp; 8208;evaporated perovskite solar cells employing an inorganic NiOx HTL are presented, achieving stable PCEs of up to 15.4 . Along with good PCEs, devices with electron amp; 8208;beam amp; 8208;evaporated NiOx show improved stability under realistic operating conditions with negligible degradation after 40 h of maximum power point tracking at 75 C. Additionally, a strong improvement in device stability under ultraviolet radiation is found if compared to conventional perovskite solar cell architectures employing other metal oxide charge transport layers e.g., titanium dioxide . Finally, an all amp; 8208;evaporated perovskite solar mini amp; 8208;module with a NiOx HTL is presented, reaching a PCE of 12.4 on an active device area of 2.3 cm

Vapor phase deposition of perovskite photovoltaics: short track to commercialization? †

Acknowledgements: The work performed at the National Renewable Energy Laboratory (NREL) was supported by the U.S. Department of Energy's Office of Energy Efficiency and Renewable Energy (EERE) under Solar Energy Technologies Office (SETO) Agreement Number DE-EE0009017 and NREL, operated by the Alliance for Sustainable Energy, LLC, for the U.S. Department of Energy (DOE) under contract number DE-AC36-08GO28308. The views expressed in the article do not necessarily represent the views of the DOE or the U.S. Government. The U.S. Government retains and the publisher, by accepting the article for publication, acknowledges that the U.S. Government retains a nonexclusive, paid-up, irrevocable, worldwide license to publish or reproduce the published form of this work, or allow others to do so, for U.S. Government purposes. The authors furthermore acknowledge the support by the Federal Ministry for Economic Affairs and Climate Action of Germany under grant agreement 03EE1123A (project SHAPE) as well as the European Union through HORIZON EUROPE Research and Innovation Actions under grant agreement number 101075330 (project NEXUS). Views and opinions expressed are those of the authors only and do not necessarily reflect those of the European Union or the European Climate, Infrastructure and Environment Executive Agency (CINEA). Neither the European Union nor the granting authority can be held responsible. Financial support for the creation of the cover artwork by the Ministry of Trade, Industry, and Energy of the Republic of Korea under the grant agreement 202300302107 was highly appreciated. The authors further recognize the kind worldwide support by the many companies in the field of perovskite-based photovoltaics that contributed to the industry survey and gave us first-hand insights into the commercialization of this technology.While perovskite-based photovoltaics (PV) is progressing toward commercialization, it remains an open question which fabrication technology – solution-based, vapor-based, or combinations – will pave the way to faster economic breakthrough. The vast majority of research studies make use of solution-processed perovskite thin films, which benefit from a rapid optimization feedback and inexpensive to procure tools in modern research laboratories, but vapor phase deposition processes dominate today's established thin-film manufacturing. As research and development of vapor phase processed perovskite thin films are still strongly underrepresented in literature, their full potential is yet to be identified. In this collaborative perspective of academic influenced by industrial views, we convey a balanced viewpoint on the prospects of vapor-based processing of perovskite PV at an industrial scale. Our perspective highlights the conceptual advantages of vapor phase deposition, discusses the most crucial process parameters in a technology assessment, contains an overview about relevant global industry clusters, and provides an outlook on the commercialization perspectives of the perovskite technology in general