1,035 research outputs found
Des outils d'aide à la décision pour la gestion des territoires en Afrique : de la neutralité de l'outil à la transformation des relations de pouvoir
Les processus de décentralisation engagés dans un grand nombre de pays africains permettent le transfert d'importantes compétences depuis l'Etat vers les collectivités locales, et notamment, pour ce qui concerne le Sénégal, en matière de gestion des ressources naturelles et du foncier. Dans ce contexte politique et institutionnel qui privilégie une participation élargie des populations aux décisions, les outils tirés des Méthodes d'Apprentissage Rapide et de Planification (MARP) sont utilisés comme outils de support à l'information et à la communication relatifs à la gestion des ressources naturelles se présentent comme des supports privilégiés d'aide à la concertation et aux négociations locales entre des acteurs aux intérêts et aux statuts différents. Analysés sous deux angles à la fois: celui de la sociologie des sciences et celui de l'anthropologie politique, les outils d'aide à la décision contenu dans les MARP, soit la cartographie et la modélisation participative nous apparaîtront dans leur finalité en 'soi et dans les effets sociaux qu'ils produisent dans les contextes observés. Loin d'être neutres dans leur usage, ces outils ont cependant en partie liée avec une certaine neutralité en raison du caractère immanent à la garantie de scientificité. Dans le même temps, ils participent, en tant que supports de représentation d'informations et de communication, au glissement des signes conventionnels vers des nouvelles variables jugées utilisables par les acteurs dans leurs négociations. De l'information brute nous passons de la connaissance aux savoirs associés, co-construits, valeur ajoutée pour la prise de décision. En cela, ces outils ouvrent -en principe- des possibilités nouvelles aux acteurs lors des débats et des négociations concernant l'accès, l'usage et l'exploitation de leurs territoires. Nous tenterons, par le biais d'expériences menées dans le Ferlo Sénégalais (Projet DOMINO), d'élucider les formes de délégation de pouvoir que les acteurs octroient à certains instruments (données, modes de représentation et de visualisation du territoire par la cartographie, mode de consultation et cadre de concertation autour des savoirs et des besoins) qui modifient leur capacité à mettre en oeuvre les politiques-publiques de gestion de l'environnement (empowerment pour certaines couches défavorisées ou marginalisées, rapport à l'accountability pour les acteurs élus, etc...). Nous insisterons en cela sur les effets sociaux que ces outils d'aide à la décision produisent dans les relations de pouvoir autour des enjeux territoriaux et la gestion des ressources naturelles. (Résumé d'auteur
Very-high-resolution mapping of river-immersed topography by remote sensing
Remote sensing has been used to map river bathymetry for several decades. Non-contact methods are necessary in several cases: inaccessible rivers, large-scale depth mapping, very shallow rivers. The remote sensing techniques used for river bathymetry are reviewed. Frequently, these techniques have been developed for marine environment and have then been transposed to riverine environments. These techniques can be divided into two types: active remote sensing, such as ground penetrating radar and bathymetric lidar; or passive remote sensing, such as through-water photogrammetry and radiometric models. This last technique which consists of finding a logarithmic relationship between river depth and image values appears to be the most used. Fewer references exist for the other techniques, but lidar is an emerging technique. For each depth measurement method, we detail the physical principles and then a review of the results obtained in the field. This review shows a lack of data for very shallow rivers, where a very high spatial resolution is needed. Moreover, the cost related to aerial image acquisition is often huge. Hence we propose an application of two techniques, radiometric models and through-water photogrammetry, with very high-resolution passive optical imagery, light platforms, and off-the-shelf cameras. We show that, in the case of the radiometric models, measurement is possible with a spatial filtering of about 1 m and a homogeneous river bottom. In contrast, with through-water photogrammetry, fine ground resolution and bottom textures are necessary
Geotraceability and life cycle assessment in environmental life cycle management: towards sustainability.
Sustainability is an emerging concept in product chains and integrates environmental, social, and economic aspects during the product's life cycle. Recently, the demand for environmental quality has required information about the products' life cycle. Life Cycle Assessment (LCA) includes the inventory analysis, where the products´life cycle are systematized, and the Life Cycle Impact Assessment, when the environmental impacts potentials are calculated. A powerful tool to describe the history, use, and lication of a product in called geotraceability..
Radiative transfer and the energy equation in SPH simulations of star formation
We introduce and test a new and highly efficient method for treating the
thermal and radiative effects influencing the energy equation in SPH
simulations of star formation. The method uses the density, temperature and
gravitational potential of each particle to estimate a mean optical depth,
which then regulates the particle's heating and cooling. The method captures --
at minimal computational cost -- the effects of (i) the rotational and
vibrational degrees of freedom of H2, H2 dissociation, H0 ionisation, (ii)
opacity changes due to ice mantle melting, sublimation of dust, molecular
lines, H-, bound-free and free-free processes and electron scattering; (iv)
external irradiation; and (v) thermal inertia. The new algorithm reproduces the
results of previous authors and/or known analytic solutions. The computational
cost is comparable to a standard SPH simulation with a simple barotropic
equation of state. The method is easy to implement, can be applied to both
particle- and grid-based codes, and handles optical depths 0<tau<10^{11}.Comment: Submitted to A&A, recommended for publicatio
Uni- and biaxial impact behavior of double-gated nanoclay-reinforced polypropylene injection moldings
Polypopylene/nanoclay three-dimensional parts were
produced without intermediate steps by direct injection
molding to explore the influence of flow features and
nanoclay incorporation in their impact performance.
The nanocomposite was obtained by direct compounding
of commercial PP with nanoclay masterbatch. The
as-molded morphology was analyzed by X-ray and
TEM analyses in terms of skin-core structure and
nanoclay particle dispersion. The nanoclay particles
induced the reduction of b-form spherulites, a known
toughener. The impact behavior was assessed in tensile
and biaxial modes. The PP nanocomposite molding
toughness was practically unaffected by the processing
melt temperature and flow rate. Conversely the
nanoclay presence is influent in the impact performance.
Under biaxial stress impact, the regions close to
weld lines are tougher than the bulk and the fracture
develops with main crack paths along the flow direction
and the weld line. Cracking along the weld line
results from less macromolecular interpenetration and
chain entanglement, and unfavorable nanoparticle orientation.
It seems that a failure mechanism which
involves nanoclay delamination and multiple matrix
crazing explains the toughening of PP in the directions
where the nanoparticle orientation with respect to
loading is adequate.Contract grant sponsors: CONICET, ANPCyT from Argentina, MINCyT (Argentina) - FCT (Portugal), Universities Nacional de Mar del Plata and Minho
Impact behavior of injected PP/nanoclay parts
This work attempts to contribute to bridge the gap between scientific challenges and industrial stakes regarding
PP/nanoclay composites. Pieces of nanocomposites were obtained by direct injection of commercial PP mixed with a
commercial MB of PP with 50% of organoclay, with a double-gated hot runner mould, which produced mouldings with
a weld line. The moulding microstructure was assessed by POM and XRD, while the distribution and exfoliation grade
of clay was evaluated by TEM and XRD. The typical skin-core structure was found, with a skin thickness wider in bulk
than in weld line zones. Regarding clay platelets mostly intercalated structures were seen. The impact properties at
room temperature were assessed by means of tensile and biaxial tests. Properties were monitored at different sites of the
mouldings. At the weld line zone less energy was consumed under tensile conditions and exhibited higher apparent
impact toughness under biaxial conditions than the bulk zone. Visual inspection of biaxially impacted samples showed
that the orientation of polymer molecules and clay platelets induced by melt flow prevailed, and the weld line was not
the determinant of the toughness of the mouldings. An optimum in impact performance was found for moulding with
3% of clay, since at larger clay contents platelets agglomerated and acted as stress raisers
Evolution of Linear Absorption and Nonlinear Optical Properties in V-Shaped Ruthenium(II)-Based Chromophores
In this article, we describe a series of complexes with electron-rich cis-{Ru^(II)(NH_3)_4}^(2+) centers coordinated to two pyridyl ligands bearing N-methyl/arylpyridinium electron-acceptor groups. These V-shaped dipolar species are new, extended members of a class of chromophores first reported by us (Coe, B. J. et al. J. Am. Chem. Soc. 2005, 127, 4845−4859). They have been isolated as their PF_6− salts and characterized by using various techniques including ^1H NMR and electronic absorption spectroscopies and cyclic voltammetry. Reversible Ru^(III/II) waves show that the new complexes are potentially redox-switchable chromophores. Single crystal X-ray structures have been obtained for four complex salts; three of these crystallize noncentrosymmetrically, but with the individual molecular dipoles aligned largely antiparallel. Very large molecular first hyperpolarizabilities β have been determined by using hyper-Rayleigh scattering (HRS) with an 800 nm laser and also via Stark (electroabsorption) spectroscopic studies on the intense, visible d → π^* metal-to-ligand charge-transfer (MLCT) and π → π^* intraligand charge-transfer (ILCT) bands. The latter measurements afford total nonresonant β_0 responses as high as ca. 600 × 10^(−30) esu. These pseudo-C_(2v) chromophores show two substantial components of the β tensor, β_(zzz) and β_(zyy), although the relative significance of these varies with the physical method applied. According to HRS, β_(zzz) dominates in all cases, whereas the Stark analyses indicate that β_(zyy) is dominant in the shorter chromophores, but β_(zzz) and β_(zyy) are similar for the extended species. In contrast, finite field calculations predict that β_(zyy) is always the major component. Time-dependent density functional theory calculations predict increasing ILCT character for the nominally MLCT transitions and accompanying blue-shifts of the visible absorptions, as the ligand π-systems are extended. Such unusual behavior has also been observed with related 1D complexes (Coe, B. J. et al. J. Am. Chem. Soc. 2004, 126, 3880−3891)
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