448 research outputs found
Residual stresses and practical adhesion: effect of organo-metallic complex formation and crystallization
Epoxy-amine liquid pre-polymers are often applied onto metallic substrates and cured to obtain painted materials or bonded joint structures. The overall performance of such systems depends on the interphase created between the epoxy amine polymer and the metallic substrate. When epoxyamine liquid mixtures are applied onto a metallic oxide layer, concomitant amine chemisorption and oxide dissolution occur leading to organo-metallic complex formation. Depending on the amine nature, as soon as the organo-metallic complex concentration is higher than the solubility product (e.g., isophoronediamine (IPDA)), these organo-metallic complexes crystallize as sharp needles. At the same time, the uncrystallized organo-metallic complexes react with the epoxy monomer to form, after curing cycle, a new network. Moreover, the crystal size increases with the solid/liquid contact time leading to an increase of intrinsic residual stresses and Young's modulus. When aliphatic diethylenetriamine (DETA) was used, no crystallization occurred, but the interphase formation was observed. The aim of this study was to understand and to establish the role of crystallization of organo-metallic complexes formed within the interphase on the practical adhesion performance. As the crystallization of the organo-metallic complex depends on the nature of the amine, two amine hardeners were used (IPDA inducing the formation of crystals and DETA without formation of crystals). For DGEBA-IPDA systems, the ultimate load decreases while residual stresses increase when the liquid/solid contact time increases. When no crystal formation was observed (e.g., DGEBADETA system), residual stresses, coating Young's modulus and ultimate load values all remained nearly constant irrespective of the liquid/solid contact time
The Lick AGN Monitoring Project: Reverberation Mapping of Optical Hydrogen and Helium Recombination Lines
We have recently completed a 64-night spectroscopic monitoring campaign at
the Lick Observatory 3-m Shane telescope with the aim of measuring the masses
of the black holes in 12 nearby (z < 0.05) Seyfert 1 galaxies with expected
masses in the range ~10^6-10^7M_sun and also the well-studied nearby active
galactic nucleus (AGN) NGC 5548. Nine of the objects in the sample (including
NGC 5548) showed optical variability of sufficient strength during the
monitoring campaign to allow for a time lag to be measured between the
continuum fluctuations and the response to these fluctuations in the broad
Hbeta emission, which we have previously reported. We present here the light
curves for the Halpha, Hgamma, HeII 4686, and HeI 5876 emission lines and the
time lags for the emission-line responses relative to changes in the continuum
flux. Combining each emission-line time lag with the measured width of the line
in the variable part of the spectrum, we determine a virial mass of the central
supermassive black hole from several independent emission lines. We find that
the masses are generally consistent within the uncertainties. The time-lag
response as a function of velocity across the Balmer line profiles is examined
for six of the AGNs. Finally we compare several trends seen in the dataset
against the predictions from photoionization calculations as presented by
Korista & Goad. We confirm several of their predictions, including an increase
in responsivity and a decrease in the mean time lag as the excitation and
ionization level for the species increases. Further confirmation of
photoionization predictions for broad-line gas behavior will require additional
monitoring programs for these AGNs while they are in different luminosity
states. [abridged]Comment: 37 pages, 18 figures and 15 tables, accepted for publication in the
Astrophysical Journa
The Lick AGN Monitoring Project: Photometric Light Curves and Optical Variability Characteristics
The Lick AGN Monitoring Project targeted 13 nearby Seyfert 1 galaxies with
the intent of measuring the masses of their central black holes using
reverberation mapping. The sample includes 12 galaxies selected to have black
holes with masses roughly in the range 10^6-10^7 solar masses, as well as the
well-studied AGN NGC 5548. In conjunction with a spectroscopic monitoring
campaign, we obtained broad-band B and V images on most nights from 2008
February through 2008 May. The imaging observations were carried out by four
telescopes: the 0.76-m Katzman Automatic Imaging Telescope (KAIT), the 2-m
Multicolor Active Galactic Nuclei Monitoring (MAGNUM) telescope, the Palomar
60-in (1.5-m) telescope, and the 0.80-m Tenagra II telescope. Having
well-sampled light curves over the course of a few months is useful for
obtaining the broad-line reverberation lag and black hole mass, and also allows
us to examine the characteristics of the continuum variability. In this paper,
we discuss the observational methods and the photometric measurements, and
present the AGN continuum light curves. We measure various variability
characteristics of each of the light curves. We do not detect any evidence for
a time lag between the B- and V-band variations, and we do not find significant
color variations for the AGNs in our sample.Comment: 16 pages, 20 figures, 8 tables, accepted for publication in ApJ
The Lick AGN Monitoring Project: Broad-Line Region Radii and Black Hole Masses from Reverberation Mapping of Hbeta
We have recently completed a 64-night spectroscopic monitoring campaign at
the Lick Observatory 3-m Shane telescope with the aim of measuring the masses
of the black holes in 12 nearby (z < 0.05) Seyfert 1 galaxies with expected
masses in the range ~10^6-10^7 M_sun and also the well-studied nearby active
galactic nucleus (AGN) NGC 5548. Nine of the objects in the sample (including
NGC 5548) showed optical variability of sufficient strength during the
monitoring campaign to allow for a time lag to be measured between the
continuum fluctuations and the response to these fluctuations in the broad
Hbeta emission. We present here the light curves for the objects in this sample
and the subsequent Hbeta time lags for the nine objects where these
measurements were possible. The Hbeta lag time is directly related to the size
of the broad-line region, and by combining the lag time with the measured width
of the Hbeta emission line in the variable part of the spectrum, we determine
the virial mass of the central supermassive black hole in these nine AGNs. The
absolute calibration of the black hole masses is based on the normalization
derived by Onken et al. We also examine the time lag response as a function of
velocity across the Hbeta line profile for six of the AGNs. The analysis of
four leads to ambiguous results with relatively flat time lags as a function of
velocity. However, SBS 1116+583A exhibits a symmetric time lag response around
the line center reminiscent of simple models for circularly orbiting broad-line
region (BLR) clouds, and Arp 151 shows an asymmetric profile that is most
easily explained by a simple gravitational infall model. Further investigation
will be necessary to fully understand the constraints placed on physical models
of the BLR by the velocity-resolved response in these objects.Comment: 24 pages, 16 figures and 13 tables, submitted to Ap
First Results from the Lick AGN Monitoring Project: The Mass of the Black Hole in Arp 151
We have recently completed a 64-night spectroscopic monitoring campaign at
the Lick Observatory 3-m Shane telescope with the aim of measuring the masses
of the black holes in 13 nearby (z < 0.05) Seyfert 1 galaxies with expected
masses in the range ~10^6-10^7 M_sun. We present here the first results from
this project -- the mass of the central black hole in Arp 151. Strong
variability throughout the campaign led to an exceptionally clean Hbeta lag
measurement in this object of 4.25(+0.68/-0.66) days in the observed frame.
Coupled with the width of the Hbeta emission line in the variable spectrum, we
determine a black hole mass of (7.1 +/- 1.2)x10^6 M_sun, assuming the Onken et
al. normalization for reverberation-based virial masses. We also find
velocity-resolved lag information within the Hbeta emission line which clearly
shows infalling gas in the Hbeta-emitting region. Further detailed analysis may
lead to a full model of the geometry and kinematics of broad line region gas
around the central black hole in Arp 151.Comment: 4 pages, 4 figures and 2 tables, accepted for publication in ApJ
Letter
The prevalence of enteroviral capsid protein vp1 immunostaining in pancreatic islets in human type 1 diabetes.
addresses: Institute of Biomedical and Clinical Sciences, Peninsula Medical School, Plymouth, UK.The final publication is available at link.springer.com/article/10.1007%2Fs00125-009-1276-0Evidence that the beta cells of human patients with type 1 diabetes can be infected with enterovirus is accumulating, but it remains unclear whether such infections occur at high frequency and are important in the disease process. We have now assessed the prevalence of enteroviral capsid protein vp1 (vp1) staining in a large cohort of autopsy pancreases of recent-onset type 1 diabetic patients and a range of controls
Constitutional patriotism
Constitutional patriotism is a political theory that seeks to provide an explanation for the sense of ownership that most individuals have towards their national constitutional system. Specifically, constitutional patriotism assumes that free-thinking individuals involved in a discussion over the common good will reach an agreement that is perceived, at least by those involved in the debate, as having normative value. The awareness that such a deliberative process has historically been a part of the constitutional system also induces a sense of ownership of past historical accommodations of constitutional principles. The shared perception of being part of historically grounded institutions within a deliberative democracy is sometimes called the ‘normative surplus effect’ or ‘normative spill-over effect’ of the deliberative process. The theory, in its current form, was proposed by Jürgen Habermas and Jean-Werner Müller.
Debates over the common good might take place informally or within the state’s institutions. Pell-mell informal debates, with few exceptions, have a limited effect on amending constitutional norms. Yet, the prerogative to openly discuss laws and policies legitimised by constitutional norms is normally sufficient to develop an inner sense of belonging to a constitutional system. Deliberative debates within public institutions (e.g. parliaments and courts) are more likely to change the functioning of a constitutional system, but they are, by way of comparison to informal political discussions, normally constrained by the system of rules that regulate representative democracy and the administration of justice. Thus, the theory of constitutional patriotism provides an explanatory model for the historical development of a democratic constitutional system.
As one of the most persuasive explanatory theories of modern pluralist democracy, constitutional patriotism has attracted a series of well-articulated critiques. It has been suggested, for instance, that constitutional patriotism might not provide a plausible model of social integration for international organisations such as the European Union (EU). In this essay, I will provide an overview of the theory and a selection of its critiques
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