Sex steroid dynamics during embryogenesis and sexual differentiation in Eurasian perch, Perca fluviatilis

It is widely accepted that sex steroid hormones play an important and a specific role during the process of sex differentiation in fish. In order to describe the role of the three main sex steroid hormones (testosterone--T, 17beta-estradiol--E2 and 11keto-testosterone--11KT) during embryogenesis and sex differentiation in Eurasian perch, Perca fluviatilis, eggs, larvae and juveniles originating from two mixed-sex and two all-female progenies were regularly sampled from fertilization to hatching (D0) and from hatching to day 70 post-hatching (D70). Just after spawning, a significant amount of sex steroids [T (1634.2pgg(-1)), E2 (554.4pgg(-1)) and 11KT (1513.2pgg(-1))] was measured in non-fertilised eggs suggesting a maternal transmission of these steroids. From D2 to D70 post-hatching, E2 levels were significantly higher in mixed-sex progenies (median: 725.7pgg(-1)) than in all-female progenies (156.2pgg(-1)) and significantly increased after the onset of the histological differentiation of the gonad in both progenies (D35). Levels of 11KT were significantly higher in mixed-sex (median: 431.5pgg(-1)) than in all-female progenies (below the limit of assay detection) and significantly increased at D35 in all-female progenies (median value: 343.2pgg(-1)). Mean 11KT to E2 ratio was six-fold higher in mixed-sex progenies (1.35) than in all-female progenies (0.24). The data suggest that the 11-oxygenated androgen (11KT) plays a major role in the male differentiation process, and that sex differentiation in Eurasian perch is probably determined by the 11KT to E2 ratio

QUINOXALINE DERIVATIVES AS EFFICIENT CORROSION INHIBITORS FOR STEEL IN ACIDIC MEDIA: BIBLIOMETRIC STUDY

This review summarizes the most works undertaken on corrosion protection using quinoxaline compounds. also known as benzopyrazines. Their inhibitive performance towards the corrosion of mild steel in acid solutions was widely studied using different techniques as weight loss measurements, Electrochemical Impedance Spectroscopy (EIS) and supported by surface analysis and theoretical approaches (DFT, Dynamic simulation …). Scopus database gives more than 70 papers leading to select the five most cited and also the most published authors. In this way, VOSviewer used to conduct a bibliometric study to draw quantitative analysis, and statistical results of the screened academic documents were obtained.  The presence of heteroatoms (N, O, S, P …), aromatic rings and double/triple bonds facilitates the understanding of the adsorption phenomena on the metal surface to create a barrier (physical and/or chemical) to retard the ingress of aggressive ions (H+) and dissolved oxygen, thus inhibiting the corrosion process

Static and dynamic friction in sliding colloidal monolayers

In a pioneer experiment, Bohlein et al. realized the controlled sliding of two-dimensional colloidal crystals over laser-generated periodic or quasi-periodic potentials. Here we present realistic simulations and arguments which besides reproducing the main experimentally observed features, give a first theoretical demonstration of the potential impact of colloid sliding in nanotribology. The free motion of solitons and antisolitons in the sliding of hard incommensurate crystals is contrasted with the soliton-antisoliton pair nucleation at the large static friction threshold Fs when the two lattices are commensurate and pinned. The frictional work directly extracted from particles' velocities can be analysed as a function of classic tribological parameters, including speed, spacing and amplitude of the periodic potential (representing respectively the mismatch of the sliding interface, and the corrugation, or "load"). These and other features suggestive of further experiments and insights promote colloid sliding to a novel friction study instrument.Comment: in print in the Proceedings of the National Academy of Sciences U.S.A. This v2 is identical to v1, but includes ancillary material. A few figures were undersampled due to size limits: those in v1 are far sharpe

Breakdown of a conservation law in incommensurate systems

We show that invariance properties of the Lagrangian of an incommensurate system, as described by the Frenkel Kontorova model, imply the existence of a generalized angular momentum which is an integral of motion if the system remains floating. The behavior of this quantity can therefore monitor the character of the system as floating (when it is conserved) or locked (when it is not). We find that, during the dynamics, the non-linear couplings of our model cause parametric phonon excitations which lead to the appearance of Umklapp terms and to a sudden deviation of the generalized momentum from a constant value, signalling a dynamical transition from a floating to a pinned state. We point out that this transition is related but does not coincide with the onset of sliding friction which can take place when the system is still floating.Comment: 7 pages, 6 figures, typed with RevTex, submitted to Phys. Rev. E Replaced 27-03-2001: changes to text, minor revision of figure

Rubber friction on wet and dry road surfaces: the sealing effect

Rubber friction on wet rough substrates at low velocities is typically 20-30% smaller than for the corresponding dry surfaces. We show that this cannot be due to hydrodynamics and propose a novel explanation based on a sealing effect exerted by rubber on substrate "pools" filled with water. Water effectively smoothens the substrate, reducing the major friction contribution due to induced viscoelastic deformations of the rubber by surface asperities. The theory is illustrated with applications related to tire-road friction.Comment: Format Revtex 4; 8 pages, 11 figures (no color); Published on Phys. Rev. B (http://link.aps.org/abstract/PRB/v71/e035428); previous work on the same topic: cond-mat/041204

Strongly Temperature Dependent Sliding Friction for a Superconducting Interface

A sudden drop in mechanical friction, between an adsorbed nitrogen monolayer and a lead substrate, occurs when the lead passes through the superconducting transition temperature. We attribute this effect to a sudden drop at the superconducting transition temperature of the substrate Ohmic heating. The Ohmic heating is due to the electronic screening current that results from the sliding adsorbed film.Comment: Revte

Theory of friction: contribution from fluctuating electromagnetic field

We calculate the friction force between two semi-infinite solids in relative parallel motion (velocity $V$), and separated by a vacuum gap of width $d$. The friction force result from coupling via a fluctuating electromagnetic field, and can be considered as the dissipative part of the van der Waals interaction. We consider the dependence of the friction force on the temperature $T$, and present a detailed discussion of the limiting cases of small and large $V$ and $d$.Comment: 15 pages, No figure

Simulations of the Static Friction Due to Adsorbed Molecules

The static friction between crystalline surfaces separated by a molecularly thin layer of adsorbed molecules is calculated using molecular dynamics simulations. These molecules naturally lead to a finite static friction that is consistent with macroscopic friction laws. Crystalline alignment, sliding direction, and the number of adsorbed molecules are not controlled in most experiments and are shown to have little effect on the friction. Temperature, molecular geometry and interaction potentials can have larger effects on friction. The observed trends in friction can be understood in terms of a simple hard sphere model.Comment: 13 pages, 13 figure