1,371 research outputs found
Evidence for Multiple Pathways to Deuterium Enhancements in Protoplanetary Disks
The distributions of deuterated molecules in protoplanetary disks are
expected to depend on the molecular formation pathways. We use observations of
spatially resolved DCN emission from the disk around TW Hya, acquired during
ALMA Science verification with a ~3" synthesized beam, together with comparable
DCO+ observations from the Submillimeter Array, to investigate differences in
the radial distributions of these species and hence differences in their
formation chemistry. In contrast to DCO+, which shows an increasing column
density with radius, DCN is better fit by a model that is centrally peaked. We
infer that DCN forms at a smaller radii and thus at higher temperatures than
DCO+. This is consistent with chemical network model predictions of DCO+
formation from H2D+ at T<30 K and DCN formation from additional pathways
involving CH2D+ at higher temperatures. We estimate a DCN/HCN abundance ratio
of ~0.017, similar to the DCO+/HCO+ abundance ratio. Deuterium fractionation
appears to be efficient at a range of temperatures in this protoplanetary disk.
These results suggest caution in interpreting the range of deuterium fractions
observed in Solar System bodies, as multiple formation pathways should be taken
into account.Comment: accepted for publication in Ap
Photochemistry of the PAH pyrene in water ice: the case for ion-mediated solid-state astrochemistry
Context. Icy dust grains play an important role in the formation of complex
inter- and circumstellar molecules. Observational studies show that polycyclic
aromatic hydrocarbons (PAHs) are abundantly present in the ISM in the gas
phase. It is likely that these non-volatile species freeze out onto dust grains
as well and participate in the astrochemical solid-state network, but
experimental PAH ice studies are largely lacking. Methods. Near UV/VIS
spectroscopy is used to track the in situ VUV driven photochemistry of pyrene
containing ices at temperatures ranging from 10 to 125 K. Results. The main
photoproducts of VUV photolyzed pyrene ices are spectroscopically identified
and their band positions are listed for two host ices, \water and CO. Pyrene
ionisation is found to be most efficient in \water ices at low temperatures.
The reaction products, triplet pyrene and the 1-hydro-1-pyrenyl radical are
most efficiently formed in higher temperature water ices and in low temperature
CO ice. Formation routes and band strength information of the identified
species are discussed. Additionally, the oscillator strengths of Py, Py^+ and
PyH are derived and a quantitative kinetic analysis is performed by fitting a
chemical reaction network to the experimental data. Conclusions. Pyrene is
efficiently ionised in water ice at temperatures below 50 K. Hydrogenation
reactions dominate the chemistry in low temperature CO ice with trace amounts
of water. The results are put in an astrophysical context by determining the
importance of PAH ionisation in a molecular cloud. The photoprocessing of a
sample PAH in ice described in this manuscript indicates that PAH
photoprocessing in the solid state should also be taken into account in
astrochemical models.Comment: 11 pages, 8 figures, accepted for publication in A&
DCO, DCN and ND reveal three different deuteration regimes in the disk around the Herbig Ae star HD163296
The formation pathways of deuterated species trace different regions of
protoplanetary disks and may shed light into their physical structure. We aim
to constrain the radial extent of main deuterated species; we are particularly
interested in spatially characterizing the high and low temperature pathways
for enhancing deuteration of these species. We observed the disk surrounding
the Herbig Ae star HD 163296 using ALMA in Band 6 and obtained resolved
spectral imaging data of DCO (=3-2), DCN (=3-2) and ND
(=3-2). We model the radial emission profiles of DCO, DCN and
ND, assuming their emission is optically thin, using a parametric model
of their abundances and radial excitation temperature estimates. DCO can be
described by a three-region model, with constant-abundance rings centered at 70
AU, 150 AU and 260 AU. The DCN radial profile peaks at about ~60 AU and
ND is seen in a ring at ~160 AU. Simple models of both molecules using
constant abundances reproduce the data. Assuming reasonable average excitation
temperatures for the whole disk, their disk-averaged column densities (and
deuterium fractionation ratios) are 1.6-2.6 cm
(0.04-0.07), 2.9-5.2 cm (0.02) and 1.6-2.5 cm (0.34-0.45) for DCO, DCN and ND, respectively.
Our simple best-fit models show a correlation between the radial location of
the first two rings in DCO and the DCN and ND abundance
distributions that can be interpreted as the high and low temperature
deuteration pathways regimes. The origin of the third DCO ring at 260 AU is
unknown but may be due to a local decrease of ultraviolet opacity allowing the
photodesorption of CO or due to thermal desorption of CO as a consequence of
radial drift and settlement of dust grains
Disk Imaging Survey of Chemistry with SMA: II. Southern Sky Protoplanetary Disk Data and Full Sample Statistics
This is the second in a series of papers based on data from DISCS, a
Submillimeter Array observing program aimed at spatially and spectrally
resolving the chemical composition of 12 protoplanetary disks. We present data
on six Southern sky sources - IM Lup, SAO 206462 (HD 135344b), HD 142527, AS
209, AS 205 and V4046 Sgr - which complement the six sources in the Taurus star
forming region reported previously. CO 2-1 and HCO+ 3-2 emission are detected
and resolved in all disks and show velocity patterns consistent with Keplerian
rotation. Where detected, the emission from DCO+ 3-2, N2H+ 3-2, H2CO 3-2 and
4-3,HCN 3-2 and CN 2-1 are also generally spatially resolved. The detection
rates are highest toward the M and K stars, while the F star SAO 206462 has
only weak CN and HCN emission, and H2CO alone is detected toward HD 142527.
These findings together with the statistics from the previous Taurus disks,
support the hypothesis that high detection rates of many small molecules depend
on the presence of a cold and protected disk midplane, which is less common
around F and A stars compared to M and K stars. Disk-averaged variations in the
proposed radiation tracer CN/HCN are found to be small, despite two orders of
magnitude range of spectral types and accretion rates. In contrast, the
resolved images suggest that the CN/HCN emission ratio varies with disk radius
in at least two of the systems. There are no clear observational differences in
the disk chemistry between the classical/full T Tauri disks and transitional
disks. Furthermore, the observed line emission does not depend on measured
accretion luminosities or the number of infrared lines detected, which suggests
that the chemistry outside of 100 AU is not coupled to the physical processes
that drive the chemistry in the innermost few AU.Comment: accepted for publication in ApJ, 41 pages including 7 figure
Increased HCO production in the outer disk around HD 163296
Three formaldehyde lines were observed (HCO 3--2, HCO
3--2, and HCO 3--2) in the protoplanetary disk
around the Herbig Ae star HD 163296 with ALMA at 0.5 arcsecond (60 AU) spatial
resolution. HCO 3--2 was readily detected via imaging, while
the weaker HCO 3--2 and HCO 3--2 lines
required matched filter analysis to detect. HCO is present throughout most
of the gaseous disk, extending out to 550 AU. An apparent 50 AU inner radius of
the HCO emission is likely caused by an optically thick dust continuum. The
HCO radial intensity profile shows a peak at 100 AU and a secondary bump at
around 300 AU, suggesting increased production in the outer disk. Different
parameterizations of the HCO abundance were compared to the observed
visibilities with minimization, using either a characteristic
temperature, a characteristic radius or a radial power law index to describe
the HCO chemistry. Similar models were applied to ALMA Science Verification
data of CO. In all modeling scenarios, fits to the HCO data show an
increased abundance in the outer disk. The overall best-fit HCO model shows
a factor of two enhancement beyond a radius of 27020 AU, with an inner
abundance of . The HCO emitting region has a lower
limit on the kinetic temperature of K. The CO modeling suggests
an order of magnitude depletion in the outer disk and an abundance of in the inner disk. The increase in HCO outer disk emission
could be a result of hydrogenation of CO ices on dust grains that are then
sublimated via thermal desorption or UV photodesorption, or more efficient
gas-phase production beyond about 300 AU if CO is photodisocciated in this
region
The ancient heritage of water ice in the solar system
Identifying the source of Earth's water is central to understanding the
origins of life-fostering environments and to assessing the prevalence of such
environments in space. Water throughout the solar system exhibits
deuterium-to-hydrogen enrichments, a fossil relic of low-temperature,
ion-derived chemistry within either (i) the parent molecular cloud or (ii) the
solar nebula protoplanetary disk. Utilizing a comprehensive treatment of disk
ionization, we find that ion-driven deuterium pathways are inefficient,
curtailing the disk's deuterated water formation and its viability as the sole
source for the solar system's water. This finding implies that if the solar
system's formation was typical, abundant interstellar ices are available to all
nascent planetary systems.Comment: 33 pages, 7 figures including main text and supplementary materials.
Published in Scienc
Exploring the Origins of Deuterium Enrichments in Solar Nebular Organics
Deuterium-to-hydrogen (D/H) enrichments in molecular species provide clues
about their original formation environment. The organic materials in primitive
solar system bodies have generally higher D/H ratios and show greater D/H
variation when compared to D/H in solar system water. We propose this
difference arises at least in part due to 1) the availability of additional
chemical fractionation pathways for organics beyond that for water, and 2) the
higher volatility of key carbon reservoirs compared to oxygen. We test this
hypothesis using detailed disk models, including a sophisticated, new disk
ionization treatment with a low cosmic ray ionization rate, and find that disk
chemistry leads to higher deuterium enrichment in organics compared to water,
helped especially by fractionation via the precursors CHD/CH. We
also find that the D/H ratio in individual species varies significantly
depending on their particular formation pathways. For example, from
AU, CH can reach , while D/H in CHOH
remains locally unaltered. Finally, while the global organic D/H in our models
can reproduce intermediately elevated D/H in the bulk hydrocarbon reservoir,
our models are unable to reproduce the most deuterium-enriched organic
materials in the solar system, and thus our model requires some inheritance
from the cold interstellar medium from which the Sun formed.Comment: 11 pages, 7 figures, accepted for publication in Ap
SO and SiS Emission Tracing an Embedded Planet and Compact CO and CO Counterparts in the HD 169142 Disk
Planets form in dusty, gas-rich disks around young stars, while at the same
time, the planet formation process alters the physical and chemical structure
of the disk itself. Embedded planets will locally heat the disk and sublimate
volatile-rich ices, or in extreme cases, result in shocks that sputter heavy
atoms such as Si from dust grains. This should cause chemical asymmetries
detectable in molecular gas observations. Using high-angular-resolution ALMA
archival data of the HD 169142 disk, we identify compact SO J=8-7 and
SiS J=19-18 emission coincident with the position of a 2 M
planet seen as a localized, Keplerian NIR feature within a gas-depleted,
annular dust gap at 38 au. The SiS emission is located along an
azimuthal arc and has a similar morphology as a known CO kinematic
excess. This is the first tentative detection of SiS emission in a
protoplanetary disk and suggests that the planet is driving sufficiently strong
shocks to produce gas-phase SiS. We also report the discovery of compact
CO and CO J=3-2 emission coincident with the planet location.
Taken together, a planet-driven outflow provides the best explanation for the
properties of the observed chemical asymmetries. We also resolve a bright,
azimuthally-asymmetric SO ring at 24 au. While most of this SO
emission originates from ice sublimation, its asymmetric distribution implies
azimuthal temperature variations driven by a misaligned inner disk or
planet-disk interactions. Overall, the HD 169142 disk shows several distinct
chemical signatures related to giant planet formation and presents a powerful
template for future searches of planet-related chemical asymmetries in
protoplanetary disks.Comment: 22 pages, 12 figures, accepted for publication in ApJ
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