Investigating the construction methods of an opus vermiculatum mosaic panel

From the third century BC to the second century AD small detailed central panels (emblemata) made using the opus vermiculatum technique were used as focal points in larger mosaic pavements. They were custom made in stone or terracotta trays to facilitate their transport and placement. Although mosaic panels in opus vermiculatum have been discovered throughout the Hellenistic and Roman Mediterranean, the location of the workshops specialising in the production of the finely worked panels is still unclear. Their association with named artists, for example Dioskourides of Samos, and the locations of finds (such as the fragments of the floor by Hephaistion at Pergamon) point to workshops in the eastern Mediterranean. A large unidentified fragment of an emblema, still in its terracotta tray, from the collections of the Department of Greece and Rome in the British Museum was the subject of analytical examination. These investigations of the tesserae (glass cubes), traces of pigments and mortar aimed to determine the raw materials and manufacturing processes for the mosaic and to characterise the nature of the application of paint to the mortar. Egyptian blue pigment and traces of hematite and carbon suggest that a fully coloured drawing was executed on the fresh mortar to guide the positioning of the tesserae. In addition, samples from the terracotta tray were taken in an attempt to identify its provenance. This contribution describes how the results of these investigations have been used to provide a deeper understanding of opus vermiculatum construction methods

Colocation and role of polyphosphates and alkaline phosphatase in apatite biomineralization of elasmobranch tesserae

AbstractElasmobranchs (e.g. sharks and rays), like all fishes, grow continuously throughout life. Unlike other vertebrates, their skeletons are primarily cartilaginous, comprising a hyaline cartilage-like core, stiffened by a thin outer array of mineralized, abutting and interconnected tiles called tesserae. Tesserae bear active mineralization fronts at all margins and the tesseral layer is thin enough to section without decalcifying, making this a tractable but largely unexamined system for investigating controlled apatite mineralization, while also offering a potential analog for endochondral ossification. The chemical mechanism for tesserae mineralization has not been described, but has been previously attributed to spherical precursors, and alkaline phosphatase (ALP) activity. Here, we use a variety of techniques to elucidate the involvement of phosphorus-containing precursors in the formation of tesserae at their mineralization fronts. Using Raman spectroscopy, fluorescence microscopy and histological methods, we demonstrate that ALP activity is located with inorganic phosphate polymers (polyP) at the tessera–uncalcified cartilage interface, suggesting a potential mechanism for regulated mineralization: inorganic phosphate (Pi) can be cleaved from polyP by ALP, thus making Pi locally available for apatite biomineralization. The application of exogenous ALP to tissue cross-sections resulted in the disappearance of polyP and the appearance of Pi in uncalcified cartilage adjacent to mineralization fronts. We propose that elasmobranch skeletal cells control apatite biomineralization by biochemically controlling polyP and ALP production, placement and activity. Previous identification of polyP and ALP shown previously in mammalian calcifying cartilage supports the hypothesis that this mechanism may be a general regulating feature in the mineralization of vertebrate skeletons

Parallel, linear-scaling building-block and embedding method based on localized orbitals and orbital-specific basis sets

We present a new linear scaling method for the energy minimization step of semiempirical and first-principles Hartree-Fock and Kohn-Sham calculations. It is based on the self-consistent calculation of the optimum localized orbitals of any localization method of choice and on the use of orbital-specific basis sets. The full set of localized orbitals of a large molecule is seen as an orbital mosaic where each tessera is made of only a few of them. The orbital tesserae are computed out of a set of embedded cluster pseudoeigenvalue coupled equations which are solved in a building-block self-consistent fashion. In each iteration, the embedded cluster equations are solved independently of each other and, as a result, the method is parallel at a high level of the calculation. In addition to full system calculations, the method enables to perform simpler, much less demanding embedded cluster calculations, where only a fraction of the localized molecular orbitals are variational while the rest are frozen, taking advantage of the transferability of the localized orbitals of a given localization method between similar molecules. Monitoring single point energy calculations of large poly(ethylene oxide) molecules and three dimensional carbon monoxide clusters using an extended Huckel Hamiltonian are presented.Comment: latex, 15 pages, 10 figures, accepted for publication in J.Chem.Phy

Characterization of Roman glass tesserae from the Coriglia excavation site (Italy) via energy-dispersive X-ray fluorescence spectrometry and Raman spectroscopy

The combined use of handheld energy-dispersive X-ray fluorescence spectrometry, Raman spectroscopy, and micro-energy-dispersive X-ray fluorescence spectrometry permitted the characterization of Roman glass tesserae excavation from the Coriglia (Italy) archeological site. Analyses of ten different glass colors were conducted as spot analyses on intact samples and as both spot analyses and line scans on select cross-sectioned samples. The elemental and molecular information gained from these spectral measurements allowed for the qualitative chemical characterization of the bulk glass, decolorants, opacifiers, and coloring agents. The use of an antimony opacifier in many of the samples supports the late Imperial phasing as determined through numismatic, fresco, ceramics, and architectural evidence. And dealinization of the exterior glass layers caused by the burial environment was confirmed

Exhibition Catalog for Learning to Count to One; Can the Center Hold? Tesserae @ .25 : .5 : 1 : 2 : 3 : 4 : 6 : 12 : 24 : 48 : 72 : 96 : 120. Attraction and Entanglement

This catalog provides information on the exhibit Learning to Count to One; Can the Center Hold? Tesserae @ .25 : .5 : 1 : 2 : 3 : 4 : 6 : 12 : 24 : 48 : 72 : 96 : 120. Attraction and Entanglement, by Ron Mills-Pinyas. This exhibit was presented by the Linfield Gallery and the Department of Art at Linfield College from February 8 through March 23, 2019

On the origin of the mitochondrial genetic code: Towards a unified mathematical framework for the management of genetic information

The origin of the genetic code represents one of the most challenging problems in molecular evolution. The genetic code is an important universal feature of extant organisms and indicates a common ancestry of different forms of life on earth. Known variants of the genetic code can be mainly divided in mitochondrial and nuclear classes. Here we provide a new insight on the origin of the mitochondrial genetic code: we found that its degeneracy distribution can be explained by using a mathematical approach recently developed for the description of the Euplotes nuclear variant of the genetic code. The results point to a primeval mitochondrial genetic code composed of four base codons, which we call tesserae, that, among other features, exhibit outstanding error detection capabilities. The theoretical description suggests also a formulation of a plausible biological theory about the origin of protein coding. Such theory is based on the symmetry properties of hypothetical primeval chemical adaptors between nucleic acids and amino acids (ancient tRNA’s). Our paper provides a unified mathematical framework for different hypotheses on the origin of genetic coding. Also, it contributes to revisit our present view about the evolutionary steps that led to extant genetic codes by giving a new first-principles perspective on the difficult problem of the origin of the genetic code, and consequently, on the origin of life on earth

On the Feasibility of Automated Detection of Allusive Text Reuse

The detection of allusive text reuse is particularly challenging due to the sparse evidence on which allusive references rely---commonly based on none or very few shared words. Arguably, lexical semantics can be resorted to since uncovering semantic relations between words has the potential to increase the support underlying the allusion and alleviate the lexical sparsity. A further obstacle is the lack of evaluation benchmark corpora, largely due to the highly interpretative character of the annotation process. In the present paper, we aim to elucidate the feasibility of automated allusion detection. We approach the matter from an Information Retrieval perspective in which referencing texts act as queries and referenced texts as relevant documents to be retrieved, and estimate the difficulty of benchmark corpus compilation by a novel inter-annotator agreement study on query segmentation. Furthermore, we investigate to what extent the integration of lexical semantic information derived from distributional models and ontologies can aid retrieving cases of allusive reuse. The results show that (i) despite low agreement scores, using manual queries considerably improves retrieval performance with respect to a windowing approach, and that (ii) retrieval performance can be moderately boosted with distributional semantics

Natural and simulated aging of historical glasses

We thoroughly studied coloured glass tesserae of historical glass windows of the Santi Giovanni e Paolo Church in Venice by means of ESEM and XPS techniques in order to evaluate the weathering mechanisms of the glass surfaces. The results show a strong impoverishment of the relative content of alkaline ions on the surfaces. Moreover, we exposed the freshly broken surfaces of the samples (having the original glass composition) to an accelerated light and wet/dry aging process using the current rain composition of Venice and then compared to the natural aged surfaces. The results show the validity of the artificial aging methodology employed that allows the measurements of the different leaching rates of the samples

Tessera terrain: Characteristics and models of origin

Tessera terrain consists of complexly deformed regions characterized by sets of ridges and valleys that intersect at angles ranging from orthogonal to oblique, and were first viewed in Venera 15/16 SAR data. Tesserae cover more area (approx. 15 percent of the area north of 30 deg N) than any of the other tectonic units mapped from the Venera data and are strongly concentrated in the region between longitudes 0 deg E and 150 deg E. Tessera terrain is concentrated between a proposed center of crustal extension and divergence in Aphrodite and a region of intense deformation, crustal convergence, and orogenesis in western Ishtar Terra. Thus, the tectonic processes responsible for tesserae are an important part of Venus tectonics. As part of an effort to understand the formation and evolution of this unusual terrain type, the basic characteristics of the tesserae were compared to the predictions made by a number of tectonic models. The basic characteristics of tessera terrain are described and the models and some of their basic predictions are briefly discussed

Three ages of Venus

A central question for any planet is the age of its surface. Based on comparative planetological arguments, Venus should be as young and active as the Earth (Wood and Francis). The detection of probable impact craters in the Venera radar images provides a tool for estimating the age of the surface of Venus. Assuming somewhat different crater production rates, Bazilevskiy et al. derived an age of 1 + or - 0.5 billion years, and Schaber et al. and Wood and Francis estimated an age of 200 to 400 million years. The known impact craters are not randomly distributed, however, thus some area must be older and others younger than this average age. Ages were derived for major geologic units on Venus using the Soviet catalog of impact craters (Bazilevskiy et al.), and the most accessible geologic unit map (Bazilevskiy). The crater counts are presented for (diameters greater than 20 km), areas, and crater densities for the 7 terrain units and coronae. The procedure for examining the distribution of craters is superior to the purely statistical approaches of Bazilevskiy et al. and Plaut and Arvidson because the bins are larger (average size 16 x 10(6) sq km) and geologically significant. Crater densities define three distinct groups: relatively heavily cratered (Lakshmi, mountain belts), moderately cratered (smooth and rolling plains, ridge belts, and tesserae), and essentially uncratered (coronae and domed uplands). Following Schaber et al., Grieve's terrestrial cratering rate of 5.4 + or - 2.7 craters greater than 20 km/10(9) yrs/10(6) sq km was used to calculate ages for the geologic units on Venus. To improve statistics, the data was aggregated into the three crater density groups, deriving the ages. For convenience, the three similar age groups are given informal time stratigraphic unit names, from youngest to oldest: Ulfrunian, Sednaian, Lakshmian