Preliminary comparative assessment of land use for the Satellite Power System (SPS) and alternative electric energy technologies

A preliminary comparative assessment of land use for the satellite power system (SPS), other solar technologies, and alternative electric energy technologies was conducted. The alternative technologies are coal gasification/combined-cycle, coal fluidized-bed combustion (FBC), light water reactor (LWR), liquid metal fast breeder reactor (LMFBR), terrestrial photovoltaics (TPV), solar thermal electric (STE), and ocean thermal energy conversion (OTEC). The major issues of a land use assessment are the quantity, purpose, duration, location, and costs of the required land use. The phased methodology described treats the first four issues, but not the costs. Several past efforts are comparative or single technology assessment are reviewed briefly. The current state of knowledge about land use is described for each technology. Conclusions are drawn regarding deficiencies in the data on comparative land use and needs for further research

Modeling and performance analysis of biomass fast pyrolysis in a solar-thermal reactor

Solar-thermal conversion of biomass through pyrolysis process is an alternative option to store energy in the form of liquid fuel, gas and bio-char. Fast pyrolysis is a highly endothermic process and essentially requires high heating rate and temperature >400 °C. This study presents a theoretical study on biomass fast pyrolysis in a solar-thermal reactor heated by a parabolic trough concentrator. The reactor is part of a novel closed loop pyrolysis-gasification process. A Eulerian-Eulerian flow model, with constitutive closure equation derived from the kinetic theory of granular flow and incorporating heat transfer, drying and pyrolysis reaction equations, was solved using ANSYS Fluent computational fluid dynamics (CFD) software. The highly endothermic pyrolysis was assumed to be satisfied by a constant solar heat flux concentrated on the reactor external wall. At the operating conditions considered, the reactor overall energy efficiency was found equal to 67.8% with the product consisting of 51.5% bio-oil, 43.7% char and 4.8% non-condensable gases. Performance analysis is presented to show the competitiveness of the proposed reactor in terms of thermal conversion efficiency and environmental impact. It is hoped that this study will contribute to the global effort on securing diverse and sustainable energy generation technologies

A new solar fuels reactor concept based on a liquid metal heat transfer fluid: Reactor design and efficiency estimation

Abstract A new reactor concept for two-step partial redox cycles is presented and evaluated by transient simulation that considers heat and mass transfer along with reaction kinetics. The major difference between the reactor described herein and previous designs is that the conversion from solar to chemical energy is divided into two steps: sunlight-to-thermal energy conversion accomplished with a liquid metal based receiver, and the thermal-to-chemical conversion accomplished with a separately optimized array of reaction chambers. To connect these two conversion steps, liquid metal is used as a high temperature heat transfer fluid that feeds the solar energy captured in the receiver to the reactor. The liquid metal also facilitates efficient heat recuperation ($80%) between the reaction chambers. The overall thermal-to-chemical efficiency from the thermal energy in the liquid metal to the chemical energy in the hydrogen fuel is estimated to be 19.8% when ceria is employed as the reactive oxygen storage material. This estimated efficiency is an order of magnitude higher than previous designs and the reactor concept discussed herein identifies important insights that apply to solar-fuel conversion in general

Selective Emitters

This invention relates to a small particle selective emitter for converting thermal energy into narrow band radiation with high efficiency. The small particle selective emitter is used in combination with a photovoltaic array to provide a thermal to electrical energy conversion device. An energy conversion apparatus of this type is called a thermo-photovoltaic device. In the first embodiment, small diameter particles of a rare earth oxide are suspended in an inert gas enclosed between concentric cylinders. The rare earth oxides are used because they have the desired property of large emittance in a narrow wavelength band and small emittance outside the band. However, it should be emphasized that it is the smallness of the particles that enhances the radiation property. The small particle selective emitter is surrounded by a photovoltaic array. In an alternate embodiment, the small particle gas mixture is circulated through a thermal energy source. This thermal energy source can be a nuclear reactor, solar receiver, or combustor of a fossil fuel

The Ammonia Looping System for Mid-Temperature Thermochemical Energy Storage

Thermochemical reactions have a great potential for energy storage and transport. Their application to solar energy is of utmost interest because the possibility of reaching high energy densities and seasonal storage capacity. In this work, thermochemical energy storage of Concentrated Solar Power (CSP) based on an ammonia looping (AL) system is analysed. The AL process for energy storage is based on the reversible reaction of ammonia to produce hydrogen and nitrogen. Concentrating solar energy is used to carry out the decomposition endothermic reaction at temperatures around 650 ºC, which fits in the range of currently commercial CSP plants with tower technology. The stored energy is released through the reverse exothermic reaction. Our work is focused on energy integration in the system modelled by pinch analysis to optimize the process performance and competitiveness. As result a novel configuration is derived which is able to recover high-temperature heat for electricity production with a thermal-to-electric efficiency up to 27 %. The current study shows a clear interest of the system from an energy integration perspective. Further research should be conducted to access the potential for commercial applications

Review of Reactors with Potential Use in Thermochemical Energy Storage in Concentrated Solar Power Plants

The aim of this study is to perform a review of the state-of-the-art of the reactors available in the literature, which are used for solid-gas reactions or thermal decomposition processes around 1000 ºC that could be further implemented for thermochemical energy storage in CSP (concentrated solar power) plants, specifically for SPT (solar power tower) technology. Both direct and indirect systems can be implemented, with direct and closed systems being the most studied ones. Among direct and closed systems, the most used configuration is the stacked bed reactor, with the fixed bed reactor being the most frequent option. Out of all of the reactors studied, almost 70% are used for solid-gas chemical reactions. Few data are available regarding solar efficiency in most of the processes, and the available information indicates relatively low values. Chemical reaction efficiencies show better values, especially in the case of a fluidized bed reactor for solid-gas chemical reactions, and fixed bed and rotary reactors for thermal decompositions.The work is partially funded by the Spanish government (ENE2015-64117-C5-1-R (MINECO/FEDER) and ENE2015-64117-C5-2-R (MINECO/FEDER)). The authors would like to thank the Catalan Government for the quality accreditation given to their research groups GREA (2017 SGR 1537) and DIOPMA (2017 SGR 118). GREA and DIOPMA are certified agents TECNIO in the category of technology developers from the Government of Catalonia. Dr. Aran Solé would like to thank Ministerio de Economía y Competitividad de España for Grant Juan de la Cierva, FJCI-2015-25741

The Calcium-Looping (CaCO3/CaO) Process for Thermochemical Energy Storage in Concentrating Solar Power Plants

Articulo aceptado por la revista. * No publicado aún [28-06-2019]Energy storage based on thermochemical systems is gaining momentum as potential alternative to molten salts in Concentrating Solar Power (CSP) plants. This work is a detailed review about the promising integration of a CaCO3/CaO based system, the so-called Calcium-Looping (CaL) process, in CSP plants with tower technology. The CaL process relies on low cost, widely available and non-toxic natural materials (such as limestone or dolomite), which are necessary conditions for the commercial expansion of any energy storage technology at large scale. A comprehensive analysis of the advantages and challenges to be faced for the process to reach a commercial scale is carried out. The review includes a deep overview of reaction mechanisms and process integration schemes proposed in the recent literature. Enhancing the multicycle CaO conversion is a major challenge of the CaL process. Many lab-scale analyses carried out show that residual effective CaO conversion is highly dependent on the process conditions and CaO precursors used, reaching values as different as 0.07-0.82. The selection of the optimal operating conditions must be based on materials, process integration, technology and economics aspects. Global plant efficiencies over 45% (without considering solar-side losses) show the interest of the technology. Furthermore, the technological maturity and potential of the process is assessed. The direction towards which future works should be headed is discussed.Ministerio de Economia y Competitividad CTQ2014-52763-C2, CTQ2017- 83602-C2 (-1-R and -2-R)Unión Europea Horizon 2020 Grant agreement No 727348, project SOCRATCES

An initial comparative assessment of orbital and terrestrial central power systems

Orbital solar power plants, which beam power to earth by microwave, are compared with ground-based solar and conventional baseload power plants. Candidate systems were identified for three types of plants and the selected plant designs were then compared on the basis of economic and social costs. The representative types of plant selected for the comparison are: light water nuclear reactor; turbines using low BTU gas from coal; central receiver with steam turbo-electric conversion and thermal storage; silicon photovoltaic power plant without tracking and including solar concentration and redox battery storage; and silicon photovoltaics

Solar photochemical process engineering for production of fuels and chemicals

The engineering costs and performance of a nominal 25,000 scmd (883,000 scfd) photochemical plant to produce dihydrogen from water were studied. Two systems were considered, one based on flat-plate collector/reactors and the other on linear parabolic troughs. Engineering subsystems were specified including the collector/reactor, support hardware, field transport piping, gas compression equipment, and balance-of-plant (BOP) items. Overall plant efficiencies of 10.3 and 11.6% are estimated for the flat-plate and trough systems, respectively, based on assumed solar photochemical efficiencies of 12.9 and 14.6%. Because of the opposing effects of concentration ratio and operating temperature on efficiency, it was concluded that reactor cooling would be necessary with the trough system. Both active and passive cooling methods were considered. Capital costs and energy costs, for both concentrating and non-concentrating systems, were determined and their sensitivity to efficiency and economic parameters were analyzed. The overall plant efficiency is the single most important factor in determining the cost of the fuel