Comparison of pervaporation models with simulation of hybrid separation processes

The industrial application of pervaporation as a membrane separation technology is increasing caused by the numerous advantages of this method. However, to complete engineering design, like in the cases of distillation, azeotropic distillation and absorption, reliable and adequate modelling of the process in flowsheeting environment is indispensable. A proper model is especially needed if the more complicated but more economical and environmentally sound hybrid separation methods are designed or investigated.In this study two pervaporation models, the solution-diffusion model of Rautenbach [1] and its developed form [2], are compared and evaluated with computer simulation on the dehydration processes of isobutanol-water and ethanol-water mixtures. Simulations of a hybrid separation method containing pervaporation for the separation of these mixtures are performed, thus proving the importance of using a proper pervaporation model regarding the discrepancies caused by the application of a false model

A hybrid reactive distillation process with high selectivity pervaporation for butyl acetate production via transesterification

A hybrid reactive distillation system with high selectivity pervaporation was examined to produce butyl acetate and methanol via transesterification of methyl acetate with butanol. High selectivity pervaporation was combined with reactive distillation to eliminate a hitherto required column for the separation of a methanol and methyl acetate azeotrope. The polyamide-6 membrane was used for this purpose because of its high selectivity for methanol while also allowing sufficient permeate flux. The high purity methyl acetate recovered in the retentate stream leads to high conversion in the reactive distillation column, which enhances the energy savings (up to 71%) of this process. The feasibility of the proposed hybrid processes and several alternative designs were evaluated by rigorous simulation and optimization using the Aspen Plus software package. The effects of several designs and operating variables were also investigated for the proposed design. The high potential of the hybrid reactive distillation and pervaporation system for butyl acetate production is very promising; it may not only reduce the total annual costs relative to conventional systems but may also provide an attractive strategy to address problems associated with methanol and methyl acetate azeotropes in the effluent generated in the polyvinyl alcohol industry

Reverse Osmosis Desalination and Hybrid Membrane Processes for Brine Treatment

Waste from seawater reverse osmosis desalination processes is commonly referred to as brine which is one of the obstacles creating environmental and economic inefficiencies. The objective of this work is to simulate the hollow fiber reverse osmosis desalination membrane process to quantify its brine volume and concentration. Then, the pervaporation process and membrane distillation process are simulated to study and compare their brine treatment capabilities. An accurate model is identified and used to represent the hollow fiber reverse osmosis process. Then, the models for pervaporation and membrane distillation are studied separately and the most accurate ones are selected to represent each process. After that, the models are arranged in an order to minimize brine volume so hybrid models are created. Finally, simulation studies are carried out to evaluate the physical parameters for the hybrid processes and to calculate the quantity and quality of brine left. This simulation study involves solving multiple differential equations simultaneously to study the real-time change in the physical parameters such as permeance, concentration, and pressure drops. Therefore, the equations are solved in Python programming language. And the generated data are stored in Microsoft excel sheets to easily deal with the data. The simulation studies show that both pervaporation and membrane distillation has good potential to be used in treating seawater reverse osmosis brine. However, pervaporation showed higher permeate water quality than MD with a 20% reduction in brine volume per stage. On the contrary, membrane distillation showed higher water flux with a 25% reduction in brine volume per stage. Finally, both pervaporation and membrane distillation membranes are capable of treating brine up to 200,000 ppm

Process flowsheet analysis of pervaporation-based hybrid processes in the production of ethyl tert-butyl ether

BACKGROUND The manufacturing process of ethyl tert-butyl ether (ETBE) involves the separation of ETBE, mixed C4 hydrocarbons and unreacted ethanol. Unfortunately, the unreacted ethanol forms azeotropic mixtures with ETBE that are difficult to separate by distillation. One of the alternative methods to overcome this limitation is the application of hybrid distillation–pervaporation processes with alcohol-selective membranes. RESULTS Simulation tasks were carried out with the process simulation software Aspen Plus and the results of alternative process flowsheets that result from the relative location of the separation technologies (for a target product purity) have been compared on the basis of the required membrane area and energy consumption. Thus, in the case study analyzed seven pervaporation modules located on a sidestream withdrawal, with a total membrane area of 210 m2, are required to obtain 6420 kg h−1 of ETBE with a purity of 95.2 wt%. The retentate stream is returned to the column while the permeate stream, with a high ethanol content, is recycled back to feed the reactors CONCLUSION Incorporating pervaporation modules in the process flowsheet for production of ETBE allows unloading of the main separation unit (debutanizer column), thereby reducing energy consumption and operating costs and increasing throughput.Financial support from the Spanish Ministry of Science under the projects CTM2013-44081-R (MINECO, Spain-FEDER 2014–2020), CTQ2015-66078-R and CTQ2016-75158-R is gratefully acknowledged. Adham Norkobilov also thanks the SILKROUTE Project for a PhD scholarship funded by the European Commission through the Erasmus Mundus Action 2 Programme

Comparative study of conventional, reactive-distillation and pervaporation integrated hybrid process for ethyl tert-butyl ether production

Ethyl tert-butyl ether (ETBE) is widely used as an oxygenate additive to gasoline; however, a drawback in the conventional ETBE manufacture is the energy intensive product recovery process, making ETBE expensive. The purification process of ETBE involves the separation of ETBE, mixed C4 hydrocarbons and unreacted ethanol. The unreacted ethanol forms azeotropic mixtures with ETBE that are difficult to separate by distillation. In this work, a comparative study between the conventional process to produce ETBE and two alternative intensified processes is presented by means of process simulation in Aspen Plus. One of the alternative methods for improving the separation and purification section of ETBE is the use of a hybrid distillation-pervaporation process with alcohol-selective membranes, which allows to reach the target ETBE purity (95.2 wt%) with a lower energy consumption and at the same time the permeate stream, with a high ethanol content, is recycled back to the reaction section. Alternatively, the production of ETBE by means of reactive distillation is analyzed for the same basis of calculation. The results show that the reactive distillation allows a significant increase in the conversion of the reactants, but in contrast the energy consumption is higher than in the other processes evaluated.Financial support from the Spanish Ministry of Science under the projects CTM2013-44081-R (MINECO, Spain-FEDER 2014–2020), CTQ2015-66078-R and CTQ2016-75158-R is gratefully acknowledged. Adham Norkobilov also thanks the SILKROUTE Project for a PhD scholarship funded by the European Commission through the Erasmus Mundus Action 2 Programme

Single- and multi-objective optimisation of hybrid distillation-pervaporation and dividing wall column structures

The separation of azeotropic mixtures is often energy intensive, thus process intensification (PI) becomes an attractive route to enhance energy efficiency. Two of the most commonly used separation intensifications are dividing wall columns and hybrid distillation-membrane processes. In this work, three typical hybrid distillation structures, distillation followed by pervaporation (D-P), pervaporation followed by distillation (P-D), and distillation followed by pervaporation then by distillation (D-P-D), are considered and compared with a hybrid dividing wall column (H-DWC) structure, which is a highly integrated process combining a dividing wall column and a pervaporation membrane network. The four structures are compared by both single-objective and multi-objective optimisation. It is shown that the D-P-D and H-DWC structures require significantly lower total annualized costs than the other two designs due to requiring smaller membrane area, as these two structures use the membrane only to help the mixture composition cross the azeotropic point

Membrane processes for the dehydration of organic compounds

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Optimal design of hybrid distillation-membrane processes based on a superstructure approach

Considerable effort is currently being put towards process intensification to design more sustainable and energy-efficient processes. Hybrid distillation-membrane processes are prime examples of such intensified processes. In this work, different strategies are presented for how to handle the complexity of the membrane network of the hybrid process in terms of initialisation and convergence for simulation and optimisation. A superstructure approach for optimisation of membrane networks within hybrid processes is presented and verified. The energy consumption and economic performance of a hybrid distillation-pervaporation process, as well as that of the corresponding extractive distillation process, to separate a minimum-boiling azeotropic mixture are compared for different feed compositions. The impact of membrane properties and cost is also briefly considered. The results show that the total heat duty for the hybrid process is always lower than that of the extractive process for the system considered, confirming that the hybrid process is more energy efficient. In terms of total annualised cost, however, the hybrid process is found to be more economically attractive at lower feed compositions, while the extractive process is preferred for higher compositions