487 research outputs found

    Fast quantitative analysis of n-alkanes, PAHs and alkenones in sediments

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    Altres ajuts: acord transformatiu CRUE-CSICUnidad de excelencia MarĂ­a de Maeztu CEX2019-000940-MThe study of different organic biomarker classes is essential to elucidate global Earth dynamics since different biogeochemical processes play a role in regulating environmental and climatic conditions. However, multiproxy analysis generally consists of labor-intensive and time-consuming methodologies, which hamper the study of a large number of samples. Here, we develop and validate a fast analytical method to quantify different classes of organic biomarkers (PAHs, n-alkanes and alkenones) in sediments. This new method sequentally extracts and fractionates the target compounds using a pressure liquid extraction (PLE) system, which allows us to selectively obtain the analytes by reducing the time of analysis, sample handling and solvent usage. We show that our method provides reproducible results and high recoveries (>70%), and can be applied to a wide range of sedimentary environments, such as oceanic basins, continental slope and shelf, and lakes. Moreover, the method provides reproducible estimates of paleoclimatic indices, such as the carbon preference index (CPI), the average chain length (ACL) and the U37K'-derived sea-surface temperature (SST). Therefore, this new method enables fast quantitative multiproxy analysis of oceanic, coastal and lake sediments

    Revealing the last 13,500 years of environmental history from the multiproxy record of a mountain lake (Lago Enol, northern Iberian Peninsula)

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    This is the author's accepted manuscript. The final publication is available at Springer via http://dx.doi.org/10.1007/s10933-009-9387-7.We present the Holocene sequence from Lago Enol (43°16â€ČN, 4°59â€ČW, 1,070 m a.s.l.), Cantabrian Mountains, northern Spain. A multiproxy analysis provided comprehensive information about regional humidity and temperature changes. The analysis included sedimentological descriptions, physical properties, organic carbon and carbonate content, mineralogy and geochemical composition together with biological proxies including diatom and ostracod assemblages. A detailed pollen study enabled reconstruction of variations in vegetation cover, which were interpreted in the context of climate changes and human impact. Four distinct stages were recognized for the last 13,500 years: (1) a cold and dry episode that includes the Younger Dryas event (13,500–11,600 cal. year BP); (2) a humid and warmer period characterizing the onset of the Holocene (11,600–8,700 cal. year BP); (3) a tendency toward a drier climate during the middle Holocene (8,700–4,650 cal. year BP); and (4) a return to humid conditions following landscape modification by human activity (pastoral activities, deforestation) in the late Holocene (4,650–2,200 cal. year BP). Superimposed on relatively stable landscape conditions (e.g. maintenance of well established forests), the typical environmental variability of the southern European region is observed at this site.The Spanish Inter-Ministry Commission of Science and Technology (CICYT), the Spanish National Parks agency, the European Commission, the Spanish Ministry of Science, and the European Social Fund

    Revealing the last 13,500 years of environmental history from the multiproxy record of a mountain lake (Lago Enol, northern Iberian Peninsula)

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    This is the author's accepted manuscript. The final publication is available at Springer via http://dx.doi.org/10.1007/s10933-009-9387-7.We present the Holocene sequence from Lago Enol (43°16â€ČN, 4°59â€ČW, 1,070 m a.s.l.), Cantabrian Mountains, northern Spain. A multiproxy analysis provided comprehensive information about regional humidity and temperature changes. The analysis included sedimentological descriptions, physical properties, organic carbon and carbonate content, mineralogy and geochemical composition together with biological proxies including diatom and ostracod assemblages. A detailed pollen study enabled reconstruction of variations in vegetation cover, which were interpreted in the context of climate changes and human impact. Four distinct stages were recognized for the last 13,500 years: (1) a cold and dry episode that includes the Younger Dryas event (13,500–11,600 cal. year BP); (2) a humid and warmer period characterizing the onset of the Holocene (11,600–8,700 cal. year BP); (3) a tendency toward a drier climate during the middle Holocene (8,700–4,650 cal. year BP); and (4) a return to humid conditions following landscape modification by human activity (pastoral activities, deforestation) in the late Holocene (4,650–2,200 cal. year BP). Superimposed on relatively stable landscape conditions (e.g. maintenance of well established forests), the typical environmental variability of the southern European region is observed at this site.The Spanish Inter-Ministry Commission of Science and Technology (CICYT), the Spanish National Parks agency, the European Commission, the Spanish Ministry of Science, and the European Social Fund

    Controls on luminescence signals in lake sediment cores:A study from Lake Suigetsu, Japan

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    The luminescence characteristics of sediments are driven by a range of environmental factors and can be used as indicators of both local and regional environmental shifts. Hence, rapid luminescence profiling techniques are increasingly employed during multiproxy analysis of sediment cores, overcoming the practical limitations of traditional (dating) methods. One emerging application of luminescence profiling is in the palaeoenvironmental investigation of lake cores. This study demonstrates the versatility of rapid core profiling using portable optically stimulated luminescence and laboratory profiling techniques for appraising the luminescence characteristics of the Lake Suigetsu (Japan) sediment cores. These techniques were employed across four key time periods, each selected for their unique environmental context and significance on either a local or global scale, in order to identify relationships between down-core luminescence and environmental change. We demonstrate that the luminescence characteristics of the cores are susceptible to a range of environmental perturbations and can therefore act as proxies of past change. Additionally, the quantification of these luminescence signals, alongside an assessment of dose rate variations down-core, supports the notion that future luminescence dating is feasible. The results of this analysis contribute to the wider understanding of the application of luminescence techniques – both profiling and dating – to lake sediment cores

    Landscape-scale drivers of glacial ecosystem change in the montane forests of the eastern Andean flank, Ecuador

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    Understanding the impact of landscape-scale disturbance events during the last glacial period is vital in accu- rately reconstructing the ecosystem dynamics of montane environments. Here, a sedimentary succession from the tropical montane cloud forest of the eastern Andean flank of Ecuador provides evidence of the role of non- climate drivers of vegetation change (volcanic events, fire regime and herbivory) during the late-Pleistocene. Multiproxy analysis (pollen, non-pollen palynomorphs, charcoal, geochemistry and carbon content) of the se- diments, radiocarbon dated to ca. 45–42 ka, provide a snap shot of the depositional environment, vegetation community and non-climate drivers of ecosystem dynamics. The geomorphology of the Vinillos study area, along with the organic‐carbon content, and aquatic remains suggest deposition took place near a valley floor in a swamp or shallow water environment. The pollen assemblage initially composed primarily of herbaceous types (Poaceae-Asteraceae-Solanaceae) is replaced by assemblages characterised by Andean forest taxa, (first Melastomataceae-Weinmannia-Ilex, and later, Alnus-Hedyosmum-Myrica). The pollen assemblages have no modern analogues in the tropical montane cloud forest of Ecuador. High micro-charcoal and rare macro-charcoal abundances co-occur with volcanic tephra deposits suggesting transportation from extra-local regions and that volcanic eruptions were an important source of ignition in the wider glacial landscape. The presence of the coprophilous fungi Sporormiella reveals the occurrence of herbivores in the glacial montane forest landscape. Pollen analysis indicates a stable regional vegetation community, with changes in vegetation population co- varying with large volcanic tephra deposits suggesting that the structure of glacial vegetation at Vinillos was driven by volcanic activity
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