Spatially detailed analysis of drill core samples with Laser-Induced Breakdown Spectroscopy: Detection, classification, and quantification of rare earth elements and lithium

In the transformation towards climate neutral consumption, electric alternatives rise in favour of fossil energy sources in a variety of different fields. Lithium and several elements from the group of Rare Earth Elements (REEs) are of particular importance for modern battery production and the supply of green energy, and therefore play a crucial role for this transformation. Their demand has increased constantly over the last years and an ongoing trend is expected for the future. New instruments and analytical methods for the geochemical investigation of drill cores can support mineral exploration and active mining and thereby help to cope with the growing demand. Laser-Induced Breakdown Spectroscopy (LIBS) is an analytical technique with many advantages for the analysis of drill core material. It has a high measurement speed, no sample preparation is needed, and major, minor as well as trace elements can be detected in a single spectrum under atmospheric conditions. Nevertheless, physical and chemical matrix effects prevent a straightforward analysis of heterogeneous material, which is especially relevant for spatially resolved investigations of drill core samples. This work displays novel methods that enable the analysis of LIBS mappings of large REE- and Li-bearing drill core samples by overcoming the problematic matrix effects with different un- semi- and supervised machine learning algorithms. In the first application, drill core samples of brecciated carbonatites were spatially investigated with LIBS to establish an intensity limit for La using the k-means clustering algorithm. Based on this intensity limit, REE enrichments were detected in the investigated sample. Afterwards, the REE content of the sample was estimated with mass balance calculations. For the second application, different Li-bearing drill core samples were mapped in high resolution with LIBS and a new classification model was developed. It combines Linear Discriminant Analysis (LDA) and One-Class Support Vector Machines (OC-SVM) to enable the classification of minerals that were covered by a train set, while also identifying LIBS matrices that are unknown to the model. The third application combined Laser Ablation – Inductively Coupled Plasma – Time of Flight Mass Spectrometry (LA-ICP-TOFMS) with LIBS measurements of the same sample. After image registration, this reference sample was used to create a Least-Square Support Vector Machine (LS-SVM) quantification model, which can be employed to convert LIBS intensities of similar material into element concentrations. The model allows a pixel-specific, spatially resolved quantification of multiple minerals with a single model. Each application displays possible solutions to minimize the influence of physical and chemical matrix effects on the spatial analysis of LIBS mappings of large drill core samples, which enables different kinds of analysis. Thereby, the great potential but also the challenges of LIBS as an analytical tool in geology and mining are highlighted

The Need for Accurate Pre-processing and Data Integration for the Application of Hyperspectral Imaging in Mineral Exploration

Die hyperspektrale Bildgebung stellt eine Schlüsseltechnologie in der nicht-invasiven Mineralanalyse dar, sei es im Labormaßstab oder als fernerkundliche Methode. Rasante Entwicklungen im Sensordesign und in der Computertechnik hinsichtlich Miniaturisierung, Bildauflösung und Datenqualität ermöglichen neue Einsatzgebiete in der Erkundung mineralischer Rohstoffe, wie die drohnen-gestützte Datenaufnahme oder digitale Aufschluss- und Bohrkernkartierung. Allgemeingültige Datenverarbeitungsroutinen fehlen jedoch meist und erschweren die Etablierung dieser vielversprechenden Ansätze. Besondere Herausforderungen bestehen hinsichtlich notwendiger radiometrischer und geometrischer Datenkorrekturen, der räumlichen Georeferenzierung sowie der Integration mit anderen Datenquellen. Die vorliegende Arbeit beschreibt innovative Arbeitsabläufe zur Lösung dieser Problemstellungen und demonstriert die Wichtigkeit der einzelnen Schritte. Sie zeigt das Potenzial entsprechend prozessierter spektraler Bilddaten für komplexe Aufgaben in Mineralexploration und Geowissenschaften.Hyperspectral imaging (HSI) is one of the key technologies in current non-invasive material analysis. Recent developments in sensor design and computer technology allow the acquisition and processing of high spectral and spatial resolution datasets. In contrast to active spectroscopic approaches such as X-ray fluorescence or laser-induced breakdown spectroscopy, passive hyperspectral reflectance measurements in the visible and infrared parts of the electromagnetic spectrum are considered rapid, non-destructive, and safe. Compared to true color or multi-spectral imagery, a much larger range and even small compositional changes of substances can be differentiated and analyzed. Applications of hyperspectral reflectance imaging can be found in a wide range of scientific and industrial fields, especially when physically inaccessible or sensitive samples and processes need to be analyzed. In geosciences, this method offers a possibility to obtain spatially continuous compositional information of samples, outcrops, or regions that might be otherwise inaccessible or too large, dangerous, or environmentally valuable for a traditional exploration at reasonable expenditure. Depending on the spectral range and resolution of the deployed sensor, HSI can provide information about the distribution of rock-forming and alteration minerals, specific chemical compounds and ions. Traditional operational applications comprise space-, airborne, and lab-scale measurements with a usually (near-)nadir viewing angle. The diversity of available sensors, in particular the ongoing miniaturization, enables their usage from a wide range of distances and viewing angles on a large variety of platforms. Many recent approaches focus on the application of hyperspectral sensors in an intermediate to close sensor-target distance (one to several hundred meters) between airborne and lab-scale, usually implying exceptional acquisition parameters. These comprise unusual viewing angles as for the imaging of vertical targets, specific geometric and radiometric distortions associated with the deployment of small moving platforms such as unmanned aerial systems (UAS), or extreme size and complexity of data created by large imaging campaigns. Accurate geometric and radiometric data corrections using established methods is often not possible. Another important challenge results from the overall variety of spatial scales, sensors, and viewing angles, which often impedes a combined interpretation of datasets, such as in a 2D geographic information system (GIS). Recent studies mostly referred to work with at least partly uncorrected data that is not able to set the results in a meaningful spatial context. These major unsolved challenges of hyperspectral imaging in mineral exploration initiated the motivation for this work. The core aim is the development of tools that bridge data acquisition and interpretation, by providing full image processing workflows from the acquisition of raw data in the field or lab, to fully corrected, validated and spatially registered at-target reflectance datasets, which are valuable for subsequent spectral analysis, image classification, or fusion in different operational environments at multiple scales. I focus on promising emerging HSI approaches, i.e.: (1) the use of lightweight UAS platforms, (2) mapping of inaccessible vertical outcrops, sometimes at up to several kilometers distance, (3) multi-sensor integration for versatile sample analysis in the near-field or lab-scale, and (4) the combination of reflectance HSI with other spectroscopic methods such as photoluminescence (PL) spectroscopy for the characterization of valuable elements in low-grade ores. In each topic, the state of the art is analyzed, tailored workflows are developed to meet key challenges and the potential of the resulting dataset is showcased on prominent mineral exploration related examples. Combined in a Python toolbox, the developed workflows aim to be versatile in regard to utilized sensors and desired applications

A probablistic framework for classification and fusion of remotely sensed hyperspectral data

Reliable and accurate material identification is a crucial component underlying higher-level autonomous tasks within the context of autonomous mining. Such tasks can include exploration, reconnaissance and guidance of machines (e.g. autonomous diggers and haul trucks) to mine sites. This thesis focuses on the problem of classification of materials (rocks and minerals) using high spatial and high spectral resolution (hyperspectral) imagery, collected remotely from mine faces in operational open pit mines. A new method is developed for the classification of hyperspectral data including field spectra and imagery using a probabilistic framework and Gaussian Process regression. The developed method uses, for the first time, the Observation Angle Dependent (OAD) covariance function to classify high-dimensional sets of data. The performance of the proposed method of classification is assessed and compared to standard methods used for the classification of hyperspectral data. This is done using a staged experimental framework. First, the proposed method is tested using high-resolution field spectrometer data acquired in the laboratory and in the field. Second, the method is extended to work on hyperspectral imagery acquired in the laboratory and its performance evaluated. Finally, the method is evaluated for imagery acquired from a mine face under natural illumination and the use of independent spectral libraries to classify imagery is explored. A probabilistic framework was selected because it best enables the integration of internal and external information from a variety of sensors. To demonstrate advantages of the proposed GP-OAD method over existing, deterministic methods, a new framework is proposed to fuse hyperspectral images using the classified probabilistic outputs from several different images acquired of the same mine face. This method maximises the amount of information but reduces the amount of data by condensing all available information into a single map. Thus, the proposed fusion framework removes the need to manually select a single classification among many individual classifications of a mine face as the `best' one and increases the classification performance by combining more information. The methods proposed in this thesis are steps forward towards an automated mine face inspection system that can be used within the existing autonomous mining framework to improve productivity and efficiency. Last but not least the proposed methods will also contribute to increased mine safety

Multispectral and Hyperspectral Remote Sensing Data for Mineral Exploration and Environmental Monitoring of Mined Areas

In recent decades, remote sensing technology has been incorporated in numerous mineral exploration projects in metallogenic provinces around the world. Multispectral and hyperspectral sensors play a significant role in affording unique data for mineral exploration and environmental hazard monitoring. This book covers the advances of remote sensing data processing algorithms in mineral exploration, and the technology can be used in monitoring and decision-making in relation to environmental mining hazard. This book presents state-of-the-art approaches on recent remote sensing and GIS-based mineral prospectivity modeling, offering excellent information to professional earth scientists, researchers, mineral exploration communities and mining companies

Drone-based Integration of Hyperspectral Imaging and Magnetics for Mineral Exploration

The advent of unoccupied aerial systems (UAS) as disruptive technology has a lasting impact on remote sensing, geophysics and most geosciences. Small, lightweight, and low-cost UAS enable researchers and surveyors to acquire earth observation data in higher spatial and spectral resolution as compared to airborne and satellite data. UAS-based applications range from rapid topographic mapping using photogrammetric techniques to hyperspectral and geophysical measurements of surface and subsurface geology. UAS surveys contribute to identifying metal deposits, monitoring of mine sites and can reveal arising environmental issues associated with mining. Further, affordable UAS technology will boost exploration data availability and expertise in the global south. This thesis investigates the application of UAS-based multi-sensor data for mineral exploration, in particular the integration of hyperspectral imagers, magnetometers and digital cameras (covering the visible red, green, blue light spectrum). UAS-based research is maturing, however the aforementioned methods are not unified effectively. RGB-based photogrammetry is used to investigate topography and surface texture. Image spectrometers measure mineral-specific surface signatures. Magnetometers detect geomagnetic field changes caused by magnetic minerals at surface and depth. The integration of such UAS sensor-based methods in this thesis augments exploration potential with non-invasive, high-resolution, safe, rapid and practical survey methods. UAS-based surveying acquired, processed and integrated data from three distinct test sites. The sites are located in Finland (Fe-Ti-V at Otanmäki; apatite at Siilinjärvi) and Greenland (Ni-Cu-PGE at Qullissat, Disko Island) and were chosen as geologically diverse areas in subarctic to arctic environments. Restricted accessibility, unfavourable atmospheric conditions, dark rocks, debris and vegetation cover and low solar illumination were common features. While the topography in Finland was moderately flat, a steep landscape challenged the Greenland field work. These restraints meant that acquisitions varied from site to site and how data was integrated and interpreted is dependent on the commodity of interest. Iron-based spectral absorption and magnetic mineral response were detected using hyperspectral and magnetic surveying in Otanmäki. Multi-sensor-based image feature detection and classification combined with magnetic forward modelling enabled seamless geologic mapping in Siilinjärvi. Detailed magnetic inversion and multispectral photogrammetry led to the construction of a comprehensive 3D model of magmatic exploration targets in Greenland. Ground truth at different intensity was employed to verify UAS-based data interpretations during all case studies. Laboratory analysis was applied when deemed necessary to acquire geologic-mineralogic validation (e.g., X-ray diffraction and optical microscopy for mineral identification to establish lithologic domains, magnetic susceptibility measurements for subsurface modelling), for example for trace amounts of magnetite in carbonatite (Siilinjärvi) and native iron occurrence in basalt (Qullissat). Technical achievements were the integration of a multicopter-based prototype fluxgate-magnetometer data from different survey altitudes with ground truth, and a feasibility study with a high-speed multispectral image system for fixed-wing UAS. The employed case studies transfer the experiences made towards general recommendations for UAS application-based multi-sensor integration. This thesis highlights the feasibility of UAS-based surveying at target scale (1–50 km2) and solidifies versatile survey approaches for multi-sensor integration.Ziel dieser Arbeit war es, das Potenzial einer Drohnen-basierten Mineralexploration mit Multisensor-Datenintegration unter Verwendung optisch-spektroskopischer und magnetischer Methoden zu untersuchen, um u. a. übertragbare Arbeitsabläufe zu erstellen. Die untersuchte Literatur legt nahe, dass Drohnen-basierte Bildspektroskopie und magnetische Sensoren ein ausgereiftes technologisches Niveau erreichen und erhebliches Potenzial für die Anwendungsentwicklung bieten, aber es noch keine ausreichende Synergie von hyperspektralen und magnetischen Methoden gibt. Diese Arbeit umfasste drei Fallstudien, bei denen die Drohnengestützte Vermessung von geologischen Zielen in subarktischen bis arktischen Regionen angewendet wurde. Eine Kombination von Drohnen-Technologie mit RGB, Multi- und Hyperspektralkameras und Magnetometern ist vorteilhaft und schuf die Grundlage für eine integrierte Modellierung in den Fallstudien. Die Untersuchungen wurden in einem Gelände mit flacher und zerklüfteter Topografie, verdeckten Zielen und unter oft schlechten Lichtverhältnissen durchgeführt. Unter diesen Bedingungen war es das Ziel, die Anwendbarkeit von Drohnen-basierten Multisensordaten in verschiedenen Explorationsumgebungen zu bewerten. Hochauflösende Oberflächenbilder und Untergrundinformationen aus der Magnetik wurden fusioniert und gemeinsam interpretiert, dabei war eine selektive Gesteinsprobennahme und Analyse ein wesentlicher Bestandteil dieser Arbeit und für die Validierung notwendig. Für eine Eisenerzlagerstätte wurde eine einfache Ressourcenschätzung durchgeführt, indem Magnetik, bildspektroskopisch-basierte Indizes und 2D-Strukturinterpretation integriert wurden. Fotogrammetrische 3D-Modellierung, magnetisches forward-modelling und hyperspektrale Klassifizierungen wurden für eine Karbonatit-Intrusion angewendet, um einen kompletten Explorationsabschnitt zu erfassen. Eine Vektorinversion von magnetischen Daten von Disko Island, Grönland, wurden genutzt, um großräumige 3D-Modelle von undifferenzierten Erdrutschblöcken zu erstellen, sowie diese zu identifizieren und zu vermessen. Die integrierte spektrale und magnetische Kartierung in komplexen Gebieten verbesserte die Erkennungsrate und räumliche Auflösung von Erkundungszielen und reduzierte Zeit, Aufwand und benötigtes Probenmaterial für eine komplexe Interpretation. Der Prototyp einer Multispektralkamera, gebaut für eine Starrflügler-Drohne für die schnelle Vermessung, wurde entwickelt, erfolgreich getestet und zum Teil ausgewertet. Die vorgelegte Arbeit zeigt die Vorteile und Potenziale von Multisensor-Drohnen als praktisches, leichtes, sicheres, schnelles und komfortabel einsetzbares geowissenschaftliches Werkzeug, um digitale Modelle für präzise Rohstofferkundung und geologische Kartierung zu erstellen

Advances in Computational Intelligence Applications in the Mining Industry

This book captures advancements in the applications of computational intelligence (artificial intelligence, machine learning, etc.) to problems in the mineral and mining industries. The papers present the state of the art in four broad categories: mine operations, mine planning, mine safety, and advances in the sciences, primarily in image processing applications. Authors in the book include both researchers and industry practitioners

GREENPEG – exploration for pegmatite minerals to feed the energy transition: first steps towards the Green Stone Age

This is the final version. Available on open access from the Geological Society via the DOI in this recordData availability: All data generated or analysed during this study are included in this published article.The GREENPEG project, which is funded by the European Commission Horizon 2020 ‘Climate action, environment, resource efficiency and raw materials’ programme, aims to develop multimethod exploration toolsets for the identification of European, buried, small-scale (0.01–5 million m3) pegmatite ore deposits of the Nb–Y–F (NYF) and Li–Cs–Ta (LCT) chemical types. The project is being coordinated by the Natural History Museum of the University of Oslo and involves four exploration services/mining operators, one geological survey, one non-profit helix association of administration, industry and academia, two consulting companies and five academic institutions from eight European countries. The target raw materials are Li, high-purity quartz for silica and metallic Si, ceramic feldspar, rare earth elements, Ta, Be and Cs, which are naturally concentrated in granitic pegmatites. Silicon and Li are two of the most sought-after green technology metals as they are essential for photovoltaics and Li-ion batteries for electric cars, respectively. GREENPEG will change the focus of exploration strategies from large-volume towards small-volume, high-quality ores and overcome the lack of exploration technologies for pegmatite ore deposits by developing toolsets tailored to these ore types. This contribution focuses on the methods applied in the GREENPEG project and as such provides a potential pathway towards the ‘Green Stone Age’ from the perspective of pegmatite-sourced minerals.European Union Horizon 2020FCT – Fundação para a Ciência e a TecnologiaScience Foundation IrelandEuropean Regional Development Fund (ERDF)Society of the Friendly Sons of St. Patrick for the Relief of Emigrants from Irelan

Interpretation of the Reflectance Spectra of Lithium (Li) Minerals and Pegmatites: A Case Study for Mineralogical and Lithological Identification in the Fregeneda-Almendra Area

Reflectance spectroscopy has been used to identify several deposit types. However, applications concerning lithium (Li)-pegmatites are still scarce. Reflectance spectroscopic studies complemented by microscopic and geochemical studies were employed in the Fregeneda-Almendra (Spain-Portugal) pegmatite field to analyze the spectral behavior of Li-minerals and field lithologies. The spectral similarity of the target class (Li-pegmatites) with other elements was also evaluated. Lepidolite was discriminated from other white micas and the remaining Li-minerals. No diagnostic feature of petalite and spodumene was identified, since their spectral curves are dominated by clays. Their presence was corroborated (by complementary techniques) in petalite relics and completely replaced crystals, although the clay-related absorption depths decrease with Li content. This implies that clays can be used as pathfinders only in areas where argillic alteration is not prevalent. All sampled lithologies present similar water and/or hydroxide features. The overall mineral assemblage is very distinct, with lepidolite, cookeite, and orthoclase exclusively identified in Li-pegmatite (being these minerals crucial targets for Li-pegmatite discrimination in real-life applications), while chlorite and biotite can occur in the remaining lithologies. Satellite data can be used to discriminate Li-pegmatites due to distinct reflectance magnitude and mineral assemblages, higher absorptions depths, and distinct Al-OH wavelength position. The potential use of multi- and hyperspectral data was evaluated; the main limitations and advantages were discussed. These new insights on the spectral behavior of Li-minerals and pegmatites may aid in new Li-pegmatite discoveries around the world

Bayesian gravitation based classification for hyperspectral images.

Integration of spectral and spatial information is extremely important for the classification of high-resolution hyperspectral images (HSIs). Gravitation describes interaction among celestial bodies which can be applied to measure similarity between data for image classification. However, gravitation is hard to combine with spatial information and rarely been applied in HSI classification. This paper proposes a Bayesian Gravitation based Classification (BGC) to integrate the spectral and spatial information of local neighbors and training samples. In the BGC method, each testing pixel is first assumed as a massive object with unit volume and a particular density, where the density is taken as the data mass in BGC. Specifically, the data mass is formulated as an exponential function of the spectral distribution of its neighbors and the spatial prior distribution of its surrounding training samples based on the Bayesian theorem. Then, a joint data gravitation model is developed as the classification measure, in which the data mass is taken to weigh the contribution of different neighbors in a local region. Four benchmark HSI datasets, i.e. the Indian Pines, Pavia University, Salinas, and Grss_dfc_2014, are tested to verify the BGC method. The experimental results are compared with that of several well-known HSI classification methods, including the support vector machines, sparse representation, and other eight state-of-the-art HSI classification methods. The BGC shows apparent superiority in the classification of high-resolution HSIs and also flexibility for HSIs with limited samples

Economic Geology Models #3. Geological Contributions to Geometallurgy: A Review

Geometallurgy is a cross-disciplinary science that addresses the problem of teasing out the features of the rock mass that significantly influence mining and processing. Rocks are complex composite mixtures for which the basic building blocks are grains of minerals. The properties of the minerals, how they are bound together, and many other aspects of rock texture affect the entire mining value chain from exploration, through mining and processing, waste and tailings disposal, to refining and sales. This review presents rock properties (e.g. strength, composition, mineralogy, texture) significant in geometallurgy and examples of test methods available to measure or predict these properties.   Geometallurgical data need to be quantitative and spatially constrained so they can be used in 3D modelling and mine planning. They also need to be obtainable relatively cheaply in order to be abundant enough to provide a statistically valid sample distribution for spatial modelling. Strong communication between different departments along the mining value chain is imperative so that data are produced and transferred in a useable form and duplication is avoided. The ultimate aim is to have 3D models that not only show the grade of valuable elements (or minerals), but also include rock properties that may influence mining and processing, so that decisions concerning mining and processing can be made holistically, i.e. the impacts of rock properties on all the cost centres in the mining process are taken into account. There are significant costs to improving ore deposit knowledge and it is very important to consider the cost-benefit curve when planning the level of geometallurgical effort that is appropriate in individual deposits.RÉSUMÉLa géométallurgie est une science interdisciplinaire qui s’intéresse aux caractéristiques de la masse rocheuse qui influent de manière significative sur l'exploitation minière et le traitement du minerai. Les roches sont des mélanges composites complexes dont les éléments structurant de base sont des grains de minéraux. Les propriétés des minéraux, la façon dont ils sont liés entre eux, et de nombreux autres aspects de la texture des roches déterminent l'ensemble de la chaîne de valeur minière, de l'exploration à l'extraction à la transformation, à l'élimination des déchets et des résidus, jusqu'au raffinage et à la vente. La présente étude passe en revue les propriétés significatives de la roche (par ex. sa cohésion, sa composition, sa minéralogie, sa texture) en géométallurgie ainsi que des exemples de méthodes d'essai disponibles pour mesurer ou prédire ces propriétés.   Les données géométallurgiques doivent être quantitatives et localisées spatialement afin qu'elles puissent être utilisées dans la modélisation 3D et la planification de la mine. Elles doivent également être peu couteuses afin d'être suffisamment nombreuses pour fournir une distribution d'échantillon statistiquement valide pour la modélisation spatiale. Une communication efficace entre les différents segments de la chaîne de valeur minière est impérative pour que les données soient produites et transférées sous une forme utilisable et que les duplications soient évitées. Le but ultime est d'avoir des modèles 3D qui montrent non seulement la qualité des éléments précieux (ou minéraux), mais aussi les propriétés de roche qui déterminent l'exploitation minière et le traitement du minerai, de sorte que les décisions concernant l'exploitation minière et le traitement du minerai peuvent être réalisées de façon holistique, c.-à-d. que l’impact des propriétés de roche sur tous les maillons de la chaîne des coûts du processus minier sont prises en compte. Les coûts d’amélioration des connaissances sur le gisement de minerai étant importants, il faut tenir compte de la courbe coûts-bénéfices lors de la planification du niveau d'investissement géométallurgique approprié pour le gisement considéré