Electrostatically driven vacuum-encapsulated polysilicon resonators part I. design and fabrication

Basic design issues and a fabrication process based on surface-micromachining techniques for electrostatically driven vacuum-encapsulated polysilicon resonators are presented. A novel freeze-drying method that does not require vacuum equipment is presented. Reactive sealing with LPCVD silicon nitride is used to create the evacuated cavity, resulting in cavity pressures close to the deposition pressure. Design issues regarding choice of materials, technology and layout are discussed. First experimental results, including an admittance plot of the one-port resonator and a plot indicating the dependence of the Q-factor on the resonator geometry and ambient pressure, are presented

Stability of martensite with pulsed electric current in dual-phase steels

Softening frequently occurs in dual-phase steels under isothermal tempering of martensite. Recently, non-isothermal tempering is implemented to decrease the softening process in dual-phase steels. Here, we have discovered using high power electropulsing treatment can significantly enhance the strengthening effects via the formation of ultrafine-grained ferrite with nano-cementite particles in tempered martensitic-ferritic steels. To the best our knowledge, electropulsing treatment is a proper candidate to retard even to recovery the softening problems in the tempering of martensite in comparison with other isothermal and non-isothermal tempering methods

Creep monitoring using permanently installed potential drop sensors

Creep is the primary life limiting mechanism of static high temperature, high pressure power station components. Creep state evaluation is currently achieved by surface inspection of microstructure during infrequent outages; a methodology which is laborious, time consuming and considered inadequate. The objective of this work is to develop a monitoring technique that is capable of on-load creep damage monitoring. A continuous update of component integrity will enable better informed, targeted inspections and outage maintenance providing increased power generation availability. A low-frequency, permanently installed potential drop system has been previously developed and will be the focus of this thesis. The use of a quasi-DC inspection frequency suppresses the influence of the electromagnetic skin effect that would otherwise undermine the stability of the measurement in the ferromagnetic materials of interest; the use of even low frequency measurements allows phase sensitive detection and greatly enhanced noise performance. By permanently installing the electrodes to the surface of the component the resistance measurement is sensitive to strain. A resistance - strain inversion is derived and validated experimentally; the use of the potential drop sensor as a robust, high temperature strain gauge is therefore demonstrated. The strain rate of a component is known to be an expression of the creep state of the component. This concept was adopted to develop an interpretive framework for inferring the creep state of a component. It is possible to monitor the accumulation of creep damage through the symptomatic relative increase in strain rate. By taking the ratio of two orthogonal strain measurements, instability and drift common to both measurements can be effectively eliminated; an important attribute considering the necessity to monitor very low strain rates over decades in time in a harsh environment. A preliminary study of using the potential drop technique for monitoring creep damage at a weld has been conducted. Welds provide a site for preferential creep damage accumulation and therefore will frequently be the life limiting feature of power station components. The potential drop technique will be sensitive to both the localised strain that is understood to act as precursor to creep damage at a weld and also the initiation and growth of a crack. Through the course of this project, two site trials have been conducted in power stations. A measurement system and high temperature hardware that is suitable for the power station environment has been developed. The focus of this thesis is the effective transfer of the technique to industry; the realisation of this is detailed in the final chapter.Open Acces

Comparative study of evolution of residual stress state by local mechanical tensioning and laser processing of ferritic and austenitic structural steel welds.

Complex thermal stresses generated in welded structures are undesirable but inevitable in fusion welding. The presence of residual stresses can be detrimental to the integrity of a welded joint. In this research, redistribution of residual stress magnitude and profile was studied and compared in two multi-pass welded structural alloys (API X100 and 304L stainless steel) after cold rolling and laser processing. The residual stress field was studied by neutron diffraction using the SALSA strain scanner at their reactor neutron source at ILL, Grenoble. In addition to a complex distribution of residual stress state, multi-pass welds also forms dendritic grain structure, which are repeatedly heated, resulting in segregation of alloying elements. Dendritic grain structure is weaker and segregation of alloying elements may result in formation of corrosion microcells as well as reduction in overall corrosion prevention due to depletion of alloying elements in certain areas. The modification of as-welded residual stress state was done by cold rolling which was followed by laser processing to create a recrystallized microstructure to minimise segregation. The main objective of this study is to understand the suitability of this novel manufacturing technique to create a stress free weldment with recrystallised grain structure. Hardness evolution in the welded structures was scanned following welding, post weld cold rolling and cold rolling followed by laser processing. Hardness distribution in both the structural alloys showed a significant evidence of plastic deformation near the cap pass of the weld metal. Residual stress redistribution was observed up to 4 mm from the capping pass for ferritic steel, while in austenitic steel weld, post weld cold rolling was effective in modifying the residual stress redistribution throughout the entire thickness. Laser processing in both cases reinstated the as-welded residual stress distribution and resulted in softening of the strained area

Effect of high-pressure rolling followed by laser processing on mechanical properties, microstructure and residual stress distribution in multi-pass welds of 304L stainless steel

Multi-pass fusion welding by a filler material (wire) is normally carried out to join thick steel sections used in most engineering applications. Multiple thermal cycles from a multi-pass weld resulted in a variable distribution of residual stress field across the weld and through the thickness. Presence of tensile residual stresses can be detrimental to the integrity and the service behaviour of the welded joint. In addition to a complex distribution of residual stress state, multi-pass welds also form dendritic grain structure, which are repeatedly heated, resulting in segregation of alloying elements. In this research, microstructural refinement with modification of residual stress state was attempted by applying post-weld cold rolling followed by laser processing and then cold rolling. The residual stress was determined non-destructively by using neutron diffraction. Post-weld cold rolling followed by laser processing was carried out to induce recrystallization of the cold rolled grains. Microstructural characterisation indicates a significant grain refinement near the capping pass. However, post-weld cold rolling followed by laser processing reinstates the lock-in stress. In this study, it was demonstrated that a complete recrystallized microstructure with compressive state of stress can be formed when a further cold rolling is applied on the laser processed, recrystallized microstructure

Validation of in situ applicable measuring techniques for analysis of the water adsorption by stone

As the water adsorbing behaviour (WAB) of stone is a key factor for most degradation processes, its analysis is a decisive aspect when monitoring deterioration and past conservation treatments, or when selecting a proper conservation treatment. In this study the performance of various non-destructive methods for measuring the WAB are compared, with the focus on the effect of the variable factors of the methods caused by their specific design. The methods under study are the contact-sponge method (CSM), the Karsten tube (KT) and the Mirowski pipe (MIR). Their performance is compared with the standardized capillary rise method (CR) and the results are analysed in relation to the open porosity of different lithotypes. Furthermore the effect of practical encumbrances which could limit the application of these methods was valuated. It was found that KT and CSM have complementary fields of investigation, where CSM is capable of measuring the initial water uptake of less porous materials with a high precision, while KT was found commodious for measuring longer contact times for more porous lithotypes. MIR showed too many discommodities, leading to unreliable results. To adequately compare the results of the different methods, the size of the contact area appears to be the most influential factor, whereas the contact material and pressure on the surface do not indicate a significant influence on the results. The study of these factors is currently being extended by visualization of the water adsorption process via X-ray and neutron radiography in combination with physico-mathematical models describing the WAB

Characterization of vertically aligned carbon nanotube forests grown on stainless steel surfaces

Vertically aligned carbon nanotube (CNT) forests are a particularly interesting class of nanomaterials, because they combine multifunctional properties, such as high energy absorption, compressive strength, recoverability and super-hydrophobicity with light weight. These characteristics make them suitable for application as coating, protective layers and antifouling substrates for metallic pipelines and blades. Direct growth of CNT forests on metals offers the possibility to transfer the tunable CNT functionalities directly onto the desired substrates. Here, we focus on characterizing the structure and mechanical properties, as well as wettability and adhesion of CNT forests grown on different types of stainless steel. We investigate the correlations between composition and morphology of the steel substrates with the micro-structure of the CNTs, and reveal how the latter ultimately controls the mechanical and wetting properties of the CNT forest. Additionally, we study the influence of substrate morphology on the adhesion of CNTs to their substrate. We highlight that the same structure-property relationships govern the mechanical performance of CNT forests grown on steels and on Si