3,549 research outputs found
Adsorption-controlled growth of La-doped BaSnO3 by molecular-beam epitaxy
Epitaxial La doped BaSnO3 films were grown in an adsorption controlled regime
by molecular beam epitaxy, where the excess volatile SnOx desorbs from the film
surface. A film grown on a (001) DyScO3 substrate exhibited a mobility of 183
cm^2 V^-1 s^-1 at room temperature and 400 cm^2 V^-1 s^-1 at 10 K, despite the
high concentration (1.2x10^11 cm^-2) of threading dislocations present. In
comparison to other reports, we observe a much lower concentration of (BaO)2
Ruddlesden Popper crystallographic shear faults. This suggests that in addition
to threading dislocations that other defects possibly (BaO)2 crystallographic
shear defects or point defects significantly reduce the electron mobility
Molecular-dynamics simulations of stacking-fault-induced dislocation annihilation in pre-strained ultrathin single-crystalline copper films
We report results of large-scale molecular-dynamics (MD) simulations of
dynamic deformation under biaxial tensile strain of pre-strained
single-crystalline nanometer-scale-thick face-centered cubic (fcc) copper
films. Our results show that stacking faults, which are abundantly present in
fcc metals, may play a significant role in the dissociation, cross-slip, and
eventual annihilation of dislocations in small-volume structures of fcc metals.
The underlying mechanisms are mediated by interactions within and between
extended dislocations that lead to annihilation of Shockley partial
dislocations or formation of perfect dislocations. Our findings demonstrate
dislocation starvation in small-volume structures with ultra-thin film
geometry, governed by a mechanism other than dislocation escape to free
surfaces, and underline the significant role of geometry in determining the
mechanical response of metallic small-volume structures.Comment: 28 pages, 3 figure
Critical boron-doping levels for generation of dislocations in synthetic diamond
Defects induced by boron doping in diamond layers were studied by transmission electron microscopy. The existence of a critical boron doping level above which defects are generated is reported. This level is found to be dependent on the CH4
/H2 molar ratios and on growth directions. The critical boron concentration lied in the 6.5–17.0 X 10 20 at/cm3 range in the direction and at 3.2 X 1021 at/cm
3 for the one. Strain related effects induced by the doping are shown not to
be responsible. From the location of dislocations and their Burger vectors, a model is proposed, together with their generation mechanism.6 page
Adsorption-controlled growth of La-doped BaSnO3 by molecular-beam epitaxy
Epitaxial La-doped BaSnO3 films were grown in an adsorption-controlled regime by molecular-beam epitaxy, where the excess volatile SnOx desorbs from the film surface. A film grown on a (001) DyScO3 substrate exhibited a mobility of 183 cm2 V-1 s-1 at room temperature and 400 cm2 V-1 s-1 at 10 K despite the high concentration (1.2 × 1011 cm-2) of threading dislocations present. In comparison to other reports, we observe a much lower concentration of (BaO)2 Ruddlesden-Popper crystallographic shear faults. This suggests that in addition to threading dislocations, other defects - possibly (BaO)2 crystallographic shear defects or point defects - significantly reduce the electron mobility
Toward defect-free semi-polar GaN templates on pre-structured sapphire
The microstructure of semi-polar (11–22) GaN templates grown on pre-structured r-plane sapphire by MOVPE has been characterized by TEM. Cross-sectional observations indicate that defects are generated in three regions of the layers: threading dislocations at the inclined GaN/sapphire interface, basal plane stacking faults (BSFs) at the c−-wing, BSFs and threading dislocations at the coalescence between neighboring GaN stripes. An in situ SiN interlayer deposited at an early stage of the growth is shown to be effective in blocking the propagation of dislocations, which is mainly attributed to SiN formed on the c-plane rather than on the (11–22) plane. Si-doped marker layers have been used to study the evolution of the growth front before coalescence as a function of temperature. A high growth temperature is associated with the formation of highly faceted GaN stripes. Dislocations originally running along the c-direction are bent to the [11–20] direction driven by a progressing (11–22) facet. An efficient defect reduction is realized as a result of terminating these dislocations at voids partially defined by the (11–20) facet
Localized thinning for strain concentration in suspended germanium membranes and optical method for precise thickness measurement
We deposited Ge layers on (001) Si substrates by molecular beam epitaxy and used them to fabricate suspended membranes with high uniaxial tensile strain. We demonstrate a CMOS-compatible fabrication strategy to increase strain concentration and to eliminate the Ge buffer layer near the Ge/Si hetero-interface deposited at low temperature. This is achieved by a two-steps patterning and selective etching process. First, a bridge and neck shape is patterned in the Ge membrane, then the neck is thinned from both top and bottom sides. Uniaxial tensile strain values higher than 3% were measured by Raman scattering in a Ge membrane of 76 nm thickness. For the challenging thickness measurement on micrometer-size membranes suspended far away from the substrate a characterization method based on pump-and-probe reflectivity measurements was applied, using an asynchronous optical sampling technique.EC/FP7/628197/EU/Heat Propagation and Thermal Conductivity in Nanomaterials for Nanoscale Energy Management/HEATPRONAN
Van der Waals epitaxy of Bi2Se3 on Si(111) vicinal surface: An approach to prepare high-quality thin films of topological insulator
Epitaxial growth of topological insulator Bi2Se3 thin films on nominally flat
and vicinal Si(111) substrates is studied. In order to achieve planner growth
front and better quality epifilms, a two-step growth method is adopted for the
van der Waal epitaxy of Bi2Se3 to proceed. By employing vicinal Si(111)
substrate surfaces, the in-pane growth rate anisotropy of Bi2Se3 is explored to
achieve single crystalline Bi2Se3 epifilms, in which threading defects and
twins are effectively suppressed. Optimization of the growth parameters has
resulted in vicinal Bi2Se3 films showing a carrier mobility of ~ 2000 cm2V-1s-1
and the background doping of ~ 3 x 1018 cm-3 of the as-grown layers. Such
samples not only show relatively high magnetoresistance but also a linear
dependence on magnetic field.Comment: 18 pages, 4 figure
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