An algorithm to schedule water delivery in pressurized irrigation networks

This study presents a deterministic constrained optimisation algorithm developed for using in a pressurized irrigation network. In irrigation networks —or water networks supplied by a head tank— utility managers can fully adapt the delivery times to suit their needs. The program provides a strategy for scheduling water delivery at a constant flow rate (opening and closing of hydrants, units, and subunits) to minimise energy consumption. This technique improves on earlier approaches by employing a deterministic method with little computing time. This method has been tested in the University of Alicante pressurized irrigation network, where decision-makers have identified the need to diminish the energy expenditure for watering University’s gardens.This work was supported by the research project “DESENREDA” through the 2021 call “Estancias de movilidad en el extranjero Jose Castillejo” of the Ministerio de Universidades (CAS21/00085) and for the project “Hi-Edu Carbon” Erasmus Plus Programme, Key Action KA22021, action type (2021-1-SK01-KA220-HED-000023274

Thermography methods to assess stomatal behaviour in a dynamic environment.

Although thermography allows rapid, non-invasive measurements of large numbers of plants, it has not been used extensively due to the difficulty in deriving biologically relevant information such as leaf transpiration (E) and stomatal conductance (gsw) from thermograms. Methods normalizing leaf temperature using temperatures from reference materials (e.g. with and without evaporative flux) to generate stress indices are generally preferred due to their ease of use to assess plant water status. Here, a simplified method to solve dynamic energy balance equations is presented, which enables the calculation of 'wet' and 'dry' leaf temperatures in order to derive stress indices, whilst providing accurate estimates of E and gsw. Comparing stress indices and gas exchange parameters highlights the limitation of stress indices in a dynamic environment and how this problem can be overcome using artificial leaf references with known conductance. Additionally, applying the equations for each pixel of a thermogram to derive the rapidity of stomatal response over the leaf lamina in wheat revealed the spatial heterogeneity of stomatal behaviour. Rapidity of stomatal movements is an important determinant of water use efficiency, and our results showed 'patchy' responses that were linked to both the spatial and temporal response of gsw

Comparison of stationary and mobile canopy sensing systems for irrigation management of maize and soybean in Nebraska

Accurate knowledge of plant and field characteristics is crucial for irrigation management. Irrigation can potentially be better managed by utilizing data collected from various sensors installed on different platforms. The accuracy and repeatability of each data source are important considerations when selecting a sensing system suitable for irrigation management. The objective of this study was to compare data from multispectral (red and near-infrared bands) and thermal (long wave thermal infrared band) sensors mounted on different platforms to investigate their comparative usability and accuracy. The different sensor platforms included stationary posts fixed on the ground, the lateral of a center pivot irrigation system, unmanned aircraft systems (UAS), and Planet (PlanetScope multispectral imager, Planet Labs, Inc., San Francisco, Calif.) satellites. The surface reflectance data from multispectral (MS) sensors were used to compute the Normalized Difference Vegetation Index (NDVI) and Soil Adjusted Vegetation Index (SAVI). The experimental plots were managed with rainfed and irrigated treatments. Irrigation was applied according to a spatial evapotranspiration model informed with Planet satellite imagery. The NDVI and SAVI curves computed from the different sensing systems exhibited similar patterns and were able to capture differences between the rainfed and irrigated treatments when the crops were approaching senescence. Strong correlations were observed for canopy temperature measurements between the stationary and pivot-mounted infrared thermometer (IRT) sensors (p-value of less than 0.01 for the correlations) when canopy were scanned with no irrigation application (dry scans). The best correlation was obtained for the irrigated maize, which yielded r2 of 0.99, RMSE of 0.4°C, and MAE of 0.3°C. The correlation for the canopy temperature data collected during dry scan between UAS and pivot-mounted thermal sensors was weak with r2 = 0.26 to 0.28, larger RMSE values of 3.7°C and MAE values of 3.4°C. Secondary analysis between thermal data from stationary and pivot-mounted IRTs collected during wet scans (during an irrigation event) demonstrated reduced canopy temperature from pivot-mounted IRTs by approximately 2°C for irrigated soybean due to wetting of the canopy by the irrigation. Understanding the performance of these sensor systems is valuable in configuring practical design and operational considerations when using sensor feedback for irrigation management

Automatic Irrigation Scheduling on a Hedgerow Olive Orchard Using an Algorithm of Water Balance Readjusted with Soil Moisture Sensors

Recent technological advances have made possible automated irrigation scheduling using decision-support tools. These tools help farmers to make better decisions in the management of their irrigation system, thus increasing yields while preserving water resources. The aim of this study is to evaluate in a commercial plot an automated irrigation system combined with remote-sensing techniques and soil mapping that allows the establishment of regulated deficit irrigation (RDI) strategies. The study was carried out over 3 years (2015–2017) in a commercial hedgerow olive orchard of the variety ‘Arbequina’ located in Alvarado (Extremadura, Spain). An apparent electrical conductivity (ECa) map and a normalized difference vegetation index (NDVI) map were generated to characterize the spatial variability of the plot and classify the zones in homogeneous areas. Then, reference points were selected to monitor the different irrigation sectors. In 2015, the plot was irrigated according to the farmer’s technical criteria throughout the plot. In 2016 and 2017, two different areas of the plot were irrigated applying an RDI strategy, one under expert supervision and the other automatically. The results show that in a heterogeneous plot the use of new technologies can be useful to establish the ideal location for an automatic irrigation system. Furthermore, automatic irrigation scheduling made it possible to establish an RDI strategy recommended by an expert, resulting in the homogenization of production throughout the plot without the need for human intervention.info:eu-repo/semantics/publishedVersio

Toward automated irrigation management with integrated crop water stress index and spatial soil water balance

Decision support systems intended for precision irrigation aim at reducing irrigation applications while optimizing crop yield to achieve maximum crop water productivity (CWP). These systems incorporate on-site sensor data, remote sensing inputs, and advanced algorithms with spatial and temporal characteristics to compute precise crop water needs. The availability of variable rate irrigation (VRI) systems enables irrigation applications at a sub-field scale. The combination of an appropriate VRI system along with a precise decision support system would be ideal for improved CWP. The objective of this study was to compare and evaluate two decision support systems in terms of seasonal applied irrigation, crop yield, and CWP. This study implemented the Spatial EvapoTranspiration Modeling Interface (SETMI) model and the Irrigation Scheduling Supervisory Control and Data Acquisition (ISSCADA) system for management of a center pivot irrigation system in a 58-ha maize-soybean field during the 2020 and 2021 growing seasons. The irrigation scheduling methods included: ISSCADA plant feedback, ISSCADA hybrid, common practice, and SETMI. These methods were applied at irrigation levels of 0, 50, 100, and 150% of the full irrigation prescribed by the respective irrigation scheduling method. Data from infrared thermometers (IRTs), soil water sensors, weather stations, and satellites were used in the irrigation methods. Mean seasonal irrigation prescribed was different among the irrigation levels and methods for the 2 years. The ISSCADA plant feedback prescribed the least irrigation among the methods for majority of the cases. The common practice prescribed the largest seasonal irrigation depth among the methods for three crop-year cases. The maize yield in rainfed was found to be significantly lower than the irrigated levels in 2020 since 2020 was a dry year. No significant differences were observed in crop yield among the different irrigation methods for both years. The CWP among the different irrigation methods ranged between 2.72 and 3.15 kg m−3 for 2020 maize, 1.03 and 1.13 kg m−3 for 2020 soybean, 3.57 and 4.24 kg m−3 for 2021 maize, and 1.19 and 1.48 kg m−3 for 2021 soybean. Deficit level (50%) had the largest irrigation water productivity in all crop-year cases in this study. The ISSCADA and SETMI systems were found to reduce irrigation applications as compared to the common practice while maintaining crop yield. This study was the first to implement the newly developed integrated crop water stress index (iCWSI) thresholds and the ISSCADA system for site-specific irrigation of maize and soybean in Nebraska

Crop response to thermal stress without yield loss in irrigated maize and soybean in Nebraska

Thermal sensing provides rapid and accurate estimation of crop water stress through canopy temperature data. Canopy temperature is highly dependent on the transpiration rate of the leaves. It is usually assumed that any reduction in crop evapotranspiration (ET) leads to crop yield loss. As a result, an increase in canopy temperature due to a decrease in crop ET would indicate crop yield loss. This research evaluated the hypothesis that crop water stress could be detected using canopy temperature measurements (increased leaf temperature) from infrared thermometers (IRTs) before incurring crop yield loss. This would be possible in a narrow range when the photosynthesis rate (and carbon assimilation) is limited by solar radiation (energy-limiting water stress) while the leaf has abundant carbon dioxide for photosynthesis. Once photosynthesis becomes limited by carbon dioxide (carbon-dioxide-limiting water stress), then yield reduction would occur. In this field experiment, measured response variables included the integrated crop water stress index (iCWSI), ET, and crop yield for maize and soybean during the 2020 and 2021 growing seasons. The irrigation was applied at four different refill levels: rainfed (0%), deficit (50%), full (100%), and over (150%). The irrigation depth was prescribed using four different irrigation methods. The field was irrigated with a center pivot irrigation system, which was also used as a platform to mount IRT sensors. The iCWSI thresholds required for irrigation management were determined using the iCWSI dataset collected in 2020. The low, medium, and high iCWSI thresholds were 120, 150, and 180, respectively for maize and 110, 130, and 150, respectively for soybean. These thresholds should be updated with iCWSI data from future studies in this region to increase the credibility of the thresholds for irrigation management. The mean iCWSI values for consecutive days after a wetting event substantially increased with time for each irrigation level and a larger range in iCWSI values was observed among the irrigation levels after three days from a wetting event. The seasonal iCWSI for different levels were found to be negatively correlated with seasonal evapotranspiration for both years. The correlations between seasonal ET and crop yield were significant with the rainfed and deficit levels for maize (p-value \u3c 0.001) and soybean (p-value = 0.04) in 2020. The iCWSI and yield data for the fully watered plots indicated that thermal stress was detected using the sensing system without incurring yield loss (i.e., energy-limiting water stress). The ET and yield data for 2021 indicated that reduction in seasonal crop ET did not result in yield loss which also supported the hypothesis. Future studies should investigate whether this phenomenon of detecting crop water stress in an early stage without yield loss is observed in other climates and locations

Toward automated irrigation management with integrated crop water stress index and spatial soil water balance

Decision support systems intended for precision irrigation aim at reducing irrigation applications while optimizing crop yield to achieve maximum crop water productivity (CWP). These systems incorporate on-site sensor data, remote sensing inputs, and advanced algorithms with spatial and temporal characteristics to compute precise crop water needs. The availability of variable rate irrigation (VRI) systems enables irrigation applications at a sub-field scale. The combination of an appropriate VRI system along with a precise decision support system would be ideal for improved CWP. The objective of this study was to compare and evaluate two decision support systems in terms of seasonal applied irrigation, crop yield, and CWP. This study implemented the Spatial EvapoTranspiration Modeling Interface (SETMI) model and the Irrigation Scheduling Supervisory Control and Data Acquisition (ISSCADA) system for management of a center pivot irrigation system in a 58-ha maize-soybean field during the 2020 and 2021 growing seasons. The irrigation scheduling methods included: ISSCADA plant feedback, ISSCADA hybrid, common practice, and SETMI. These methods were applied at irrigation levels of 0, 50, 100, and 150% of the full irrigation prescribed by the respective irrigation scheduling method. Data from infrared thermometers (IRTs), soil water sensors, weather stations, and satellites were used in the irrigation methods. Mean seasonal irrigation prescribed was different among the irrigation levels and methods for the 2 years. The ISSCADA plant feedback prescribed the least irrigation among the methods for majority of the cases. The common practice prescribed the largest seasonal irrigation depth among the methods for three crop-year cases. The maize yield in rainfed was found to be significantly lower than the irrigated levels in 2020 since 2020 was a dry year. No significant differences were observed in crop yield among the different irrigation methods for both years. The CWP among the different irrigation methods ranged between 2.72 and 3.15 kg m−3 for 2020 maize, 1.03 and 1.13 kg m−3 for 2020 soybean, 3.57 and 4.24 kg m−3 for 2021 maize, and 1.19 and 1.48 kg m−3 for 2021 soybean. Deficit level (50%) had the largest irrigation water productivity in all crop-year cases in this study. The ISSCADA and SETMI systems were found to reduce irrigation applications as compared to the common practice while maintaining crop yield. This study was the first to implement the newly developed integrated crop water stress index (iCWSI) thresholds and the ISSCADA system for site-specific irrigation of maize and soybean in Nebraska

개별 이온 및 작물 생육 센싱 기반의 정밀 수경재배 양액 관리 시스템

학위논문 (박사) -- 서울대학교 대학원 : 농업생명과학대학 바이오시스템·소재학부(바이오시스템공학), 2020. 8. 김학진.In current closed hydroponics, the nutrient solution monitoring and replenishment are conducted based on the electrical conductivity (EC) and pH, and the fertigation is carried out with the constant time without considering the plant status. However, the EC-based management is unable to detect the dynamic changes in the individual nutrient ion concentrations so the ion imbalance occurs during the iterative replenishment, thereby leading to the frequent discard of the nutrient solution. The constant time-based fertigation inevitably induces over- or under-supply of the nutrient solution for the growing plants. The approaches are two of the main causes of decreasing water and nutrient use efficiencies in closed hydroponics. Regarding the issues, the precision nutrient solution management that variably controls the fertigation volume and corrects the deficient nutrient ions individually would allow both improved efficiencies of fertilizer and water use and increased lifespan of the nutrient solution. The objectives of this study were to establish the precision nutrient solution management system that can automatically and variably control the fertigation volume based on the plant-growth information and supply the individual nutrient fertilizers in appropriate amounts to reach the optimal compositions as nutrient solutions for growing plants. To achieve the goal, the sensing technologies for the varying requirements of water and nutrients were investigated and validated. Firstly, an on-the-go monitoring system was constructed to monitor the lettuces grown under the closed hydroponics based on the nutrient film technique for the entire bed. The region of the lettuces was segmented by the excess green (ExG) and Otsu method to obtain the canopy cover (CC). The feasibility of the image processing for assessing the canopy (CC) was validated by comparing the computed CC values with the manually analyzed CC values. From the validation, it was confirmed the image monitoring and processing for the CC measurements were feasible for the lettuces before harvest. Then, a transpiration rate model using the modified Penman-Monteith equation was fitted based on the obtained CC, radiation, air temperature, and relative humidity to estimate the water need of the growing lettuces. Regarding the individual ion concentration measurements, two-point normalization, artificial neural network, and a hybrid signal processing consisting of the two-point normalization and artificial neural network were compared to select an effective method for the ion-selective electrodes (ISEs) application in continuous and autonomous monitoring of ions in hydroponic solutions. The hybrid signal processing showed the most accuracy in sample measurements, but the vulnerability to the sensor malfunction made the two-point normalization method with the most precision would be appropriate for the long-term monitoring of the nutrient solution. In order to determine the optimal injection amounts of the fertilizer salts and water for the given target individual ion concentrations, a decision tree-based dosing algorithm was designed. The feasibility of the dosing algorithm was validated with the stepwise and varying target focusing replenishments. From the results, the ion-specific replenishments formulated the compositions of the nutrient solution successfully according to the given target values. Finally, the proposed sensing and control techniques were integrated to implement the precision nutrient solution management, and the performance was verified by a closed lettuce cultivation test. From the application test, the fertigation volume was reduced by 57.4% and the growth of the lettuces was promoted in comparison with the constant timer-based fertigation strategy. Furthermore, the system successfully maintained the nutrient balance in the recycled solution during the cultivation with the coefficients of variance of 4.9%, 1.4%, 3.2%, 5.2%, and 14.9%, which were generally less than the EC-based replenishment with the CVs of 6.9%, 4.9%, 23.7%, 8.6%, and 8.3% for the NO3, K, Ca, Mg, and P concentrations, respectively. These results implied the developed precision nutrient solution management system could provide more efficient supply and management of water and nutrients than the conventional methods, thereby allowing more improved water and nutrient use efficiencies and crop productivity.현재의 순환식 수경재배 시스템에서 양액의 분석과 보충은 전기전도도 (EC, electrical conductivity) 및 pH를 기반으로 수행되고 있으며, 양액의 공급은 작물의 생육 상태에 대한 고려 없이 항상 일정한 시간 동안 펌프가 동작하여 공급되는 형태이다. 그러나 EC 기반의 양액 관리는 개별 이온 농도의 동적인 변화를 감지할 수 없어 반복되는 보충 중 불균형이 발생하게 되어 양액의 폐기를 야기하며, 고정된 시간 동안의 양액 공급은 작물에 대해 과잉 또는 불충분한 물 공급으로 이어져 물 사용 효율의 저하를 일으킨다. 이러한 문제들에 대해, 개별 이온 농도에 대해 부족한 성분만을 선택적으로 보충하고, 작물의 생육 정도에 기반하여 필요한 수준에 맞게 양액을 공급하는 정밀 농업에 기반한 양액 관리를 수행하면 물과 비료 사용 효율의 향상과 양액의 재사용 기간 증진을 기대할 수 있다. 본 연구의 목적은 자동으로, 그리고 가변적으로 작물 생육 정보에 기반하여 양액 공급량을 제어하고, 작물 생장에 적합한 조성에 맞게 현재 양액의 이온 농도 센싱에 기반하여 적절한 수준만큼의 물과 개별 양분 비료를 보충할 수 있는 정밀 수경재배 양액 관리 시스템을 개발하는 것이다. 해당 목표를 달성하기 위해, 변이하는 물과 양분 요구량을 측정할 수 있는 모니터링 기술들을 분석하고 각 모니터링 기술들에 대한 검증을 수행하였다. 먼저, 작물의 물 요구량을 실시간으로 관측할 수 있는 영상 기반 측정 기술을 조사하였다. 영상 기반 분석 활용을 위해 박막경 기반의 순환식 수경재배 환경에서 자라는 상추의 이미지들을 전체 베드에 대해 수집할 수 있는 영상 모니터링 시스템을 구성하였고, 수집한 영상 중 상추 부분만을 excess green (ExG)과 Otsu 방법을 통해 분리하여 투영작물면적 (CC, canopy cover)을 획득하였다. 영상 처리 기술의 적용성 평가를 위해 직접 분석한 투영작물면적 값과 이를 비교하였다. 비교 검증 결과에서 투영작물면적 측정을 위한 영상 수집 및 분석이 수확 전까지의 상추에 대해 적용 가능함을 확인하였다. 이후 수집한 투영작물면적과 기온, 상대습도, 일사량을 기반으로 생육 중인 상추들이 요구하는 물의 양을 예측하기 위해 Penman-Monteith 방정식 기반의 증산량 예측 모델을 구성하였으며 실제 증산량과 비교하였을 때 높은 일치도를 확인하였다. 개별 이온 농도 측정과 관련하여서는, 이온선택성전극 (ISE, ion-selective electrode)를 이용한 수경재배 양액 내 이온의 연속적이고 자율적인 모니터링 수행을 위해 2점 정규화, 인공신경망, 그리고 이 둘을 복합적으로 구성한 하이브리드 신호 처리 기법의 성능을 비교하여 분석하였다. 분석 결과, 하이브리드 신호 처리 방식이 가장 높은 정확성을 보였으나, 센서 고장에 취약한 신경망 구조로 인해 장기간 모니터링 안정성에 있어서는 가장 높은 정밀도를 가진 2점 정규화 방식을 센서 어레이에 적용하는 것이 적합할 것으로 판단하였다. 또한, 주어진 개별 이온 농도 목표값에 맞는 비료 염 및 물의 최적 주입량을 결정하기 위해 의사결정트리 구조의 비료 투입 알고리즘을 제시하였다. 제시한 비료 투입 알고리즘의 효과에 대해서는 순차적인 목표에 대한 보충 및 특정 성분에 대해 집중적인 변화를 부여한 보충 수행 실험을 통해 검증하였으며, 그 결과 제시한 알고리즘은 주어진 목표값들에 따라 성공적으로 양액을 조성하였음을 확인하였다. 마지막으로, 제시되었던 센싱 및 제어 기술들을 통합하여 NFT 기반의 순환식 수경재배 배드에 상추 재배를 수행하여 실증하였다. 실증 실험에서, 종래의 고정 시간 양액 공급 대비 57.4%의 양액 공급량 감소와 상추 생육의 촉진을 확인하였다. 동시에, 개발 시스템은 NO3, K, Ca, Mg, 그리고 P에 대해 각각 4.9%, 1.4%, 3.2%, 5.2%, 그리고 14.9% 수준의 변동계수 수준을 보여 EC기반 보충 방식에서 나타난 변동계수 6.9%, 4.9%, 23.7%, 8.6%, 그리고 8.3%보다 대체적으로 우수한 이온 균형 유지 성능을 보였다. 이러한 결과들을 통해 개발 정밀 관비 시스템이 기존보다 효율적인 양액의 공급과 관리를 통해 양액 이용 효율성과 생산성의 증진에 기여할 수 있을 것으로 판단되었다.CHAPTER 1. INTRODUCTION 1 BACKGROUND 1 Nutrient Imbalance 2 Fertigation Scheduling 3 OBJECTIVES 7 ORGANIZATION OF THE DISSERTATION 8 CHAPTER 2. LITERATURE REVIEW 10 VARIABILITY OF NUTRIENT SOLUTIONS IN HYDROPONICS 10 LIMITATIONS OF CURRENT NUTRIENT SOLUTION MANAGEMENT IN CLOSED HYDROPONIC SYSTEM 11 ION-SPECIFIC NUTRIENT MONITORING AND MANAGEMENT IN CLOSED HYDROPONICS 13 REMOTE SENSING TECHNIQUES FOR PLANT MONITORING 17 FERTIGATION CONTROL METHODS BASED ON REMOTE SENSING 19 CHAPTER 3. ON-THE-GO CROP MONITORING SYSTEM FOR ESTIMATION OF THE CROP WATER NEED 21 ABSTRACT 21 INTRODUCTION 21 MATERIALS AND METHODS 23 Hydroponic Growth Chamber 23 Construction of an On-the-go Crop Monitoring System 25 Image Processing for Canopy Cover Estimation 29 Evaluation of the CC Calculation Performance 32 Estimation Model for Transpiration Rate 32 Determination of the Parameters of the Transpiration Rate Model 33 RESULTS AND DISCUSSION 35 Performance of the CC Measurement by the Image Monitoring System 35 Plant Growth Monitoring in Closed Hydroponics 39 Evaluation of the Crop Water Need Estimation 42 CONCLUSIONS 46 CHAPTER 4. HYBRID SIGNAL-PROCESSING METHOD BASED ON NEURAL NETWORK FOR PREDICTION OF NO3, K, CA, AND MG IONS IN HYDROPONIC SOLUTIONS USING AN ARRAY OF ION-SELECTIVE ELECTRODES 48 ABSTRACT 48 INTRODUCTION 49 MATERIALS AND METHODS 52 Preparation of the Sensor Array 52 Construction and Evaluation of Data-Processing Methods 53 Preparation of Samples 57 Procedure of Sample Measurements 59 RESULTS AND DISCUSSION 63 Determination of the Artificial Neural Network (ANN) Structure 63 Evaluation of the Processing Methods in Training Samples 64 Application of the Processing Methods in Real Hydroponic Samples 67 CONCLUSIONS 72 CHAPTER 5. DECISION TREE-BASED ION-SPECIFIC NUTRIENT MANAGEMENT ALGORITHM FOR CLOSED HYDROPONICS 74 ABSTRACT 74 INTRODUCTION 75 MATERIALS AND METHODS 77 Decision Tree-based Dosing Algorithm 77 Development of an Ion-Specific Nutrient Management System 82 Implementation of Ion-Specific Nutrient Management with Closed-Loop Control 87 System Validation Tests 89 RESULTS AND DISCUSSION 91 Five-stepwise Replenishment Test 91 Replenishment Test Focused on The Ca 97 CONCLUSIONS 99 CHAPTER 6. ION-SPECIFIC AND CROP GROWTH SENSING BASED NUTRIENT SOLUTION MANAGEMENT SYSTEM FOR CLOSED HYDROPONICS 101 ABSTRACT 101 INTRODUCTION 102 MATERIALS AND METHODS 103 System Integration 103 Implementation of the Precision Nutrient Solution Management System 106 Application of the Precision Nutrient Solution Management System to Closed Lettuce Soilless Cultivation 112 RESULTS AND DISCUSSION 113 Evaluation of the Plant Growth-based Fertigation in the Closed Lettuce Cultivation 113 Evaluation of the Ion-Specific Management in the Closed Lettuce Cultivation 118 CONCLUSIONS 128 CHAPTER 7. CONCLUSIONS 130 CONCLUSIONS OF THE STUDY 130 SUGGESTIONS FOR FUTURE STUDY 134 LIST OF REFERENCES 136 APPENDIX 146 A1. Python Code for Controlling the Image Monitoring and CC Calculation 146 A2. Ion Concentrations of the Solutions used in Chapter 4 (Unit: mg∙L−1) 149 A3. Block Diagrams of the LabVIEW Program used in Chapter 4 150 A4. Ion Concentrations of the Solutions used in Chapters 5 and 6 (Unit: mg∙L−1) 154 A5. Block Diagrams of the LabVIEW Program used in the Chapters 5 and 6 155 ABSTRACT IN KOREAN 160Docto