19 research outputs found

    Annual Report 2016 Institute of Resource Ecology

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    The Institute of Resource Ecology (IRE) is one of the eight institutes of the Helmholtz-Zentrum Dresden – Rossendorf (HZDR). The research activities are mainly integrated into the program “Nuclear Waste Management, Safety and Radiation Research (NUSAFE)” of the Helmholtz Association (HGF) and focused on the topics “Safety of Nuclear Waste Disposal” and “Safety Research for Nuclear Reactors”..

    The effect of extensional flow on shear viscosity

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    Shear rheology is conventionally studied under pure shearing flows, rather than more realistic mixed flows. Moving parallel surfaces and capillary rheometery are examples of the former, whilst the latter occurs whenever a flow accelerates or decelerates creating an additional component of extension, e.g. on passing through an industrial extrusion die. We postulate and gather supporting evidence that shear rheology is a function of not only shear, but both shear and extension rate, a factor with important consequences for fibre spinning and extrusion operations. The direction, as well as rate, of extensional deformation is important. A novel two-phase flow, planar extension experiment is developed and the surface coatings necessary to control the interface structure identified. Shear viscosity evolution is monitored, in-situ, under extensional flow, by optically measuring shear rates either side of a test fluid – reference fluid interface; issues due to optical refraction are critically addressed. Preliminary evidence is shown for a 1.2wt% 4x10^6 MW PEO solution that parallel (+ve) extensional flow, on the order of 11.5s-1 , causes a reduction in shear viscosity, and perpendicular (-ve) causes an increase in shear viscosity, supporting the hypothesis. A framework for a comparison experiment, with the same shear history but without extension, is presented. As part of this work, design criteria for planar hyperbolic extensional channels are critically assessed. In particular, expanding a hyperbola entrance region would maximise total Hencky strain, yet this region is almost never given rationalised consideration in literature. In this region the basis for the hyperbolic profile breaks down, and a new profiling strategy and channel form are presented, which is found to only differ significantly in this inlet region. A useful design limit of 130 degrees on channel inlet angle is identified. The new profile is compared to a hyperbolic profile through the use of CFD for wall slip flow, and a slight improvement in extension rate uniformity along the centreline found. Deviations are contrasted against assumptions made in the profiling strategy: comments are made with regards the possibility for “internal” shear to occur, and non-uniform extension rates are accordingly found to exist between streamlines in these channels despite the use of full wall slip in the simulations

    Single-molecule techniques in biophysics : a review of the progress in methods and applications

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    Single-molecule biophysics has transformed our understanding of the fundamental molecular processes involved in living biological systems, but also of the fascinating physics of life. Far more exotic than a collection of exemplars of soft matter behaviour, active biological matter lives far from thermal equilibrium, and typically covers multiple length scales from the nanometre level of single molecules up several orders of magnitude to longer length scales in emergent structures of cells, tissues and organisms. Biological molecules are often characterized by an underlying instability, in that multiple metastable free energy states exist which are separated by energy levels of typically just a few multiples of the thermal energy scale of kBT, where kB is the Boltzmann constant and T the absolute temperature, implying complex, dynamic inter-conversion kinetics across this bumpy free energy landscape in the relatively hot, wet environment of real, living biological matter. The key utility of single-molecule biophysics lies in its ability to probe the underlying heterogeneity of free energy states across a population of molecules, which in general is too challenging for conventional ensemble level approaches which measure mean average properties. Parallel developments in both experimental and theoretical techniques have been key to the latest insights and are enabling the development of highly-multiplexed, correlative techniques to tackle previously intractable biological problems. Experimentally, technological developments in the sensitivity and speed of biomolecular detectors, the stability and efficiency of light sources, probes and microfluidics, have enabled and driven the study of heterogeneous behaviours both in vitro and in vivo that were previously undetectable by ensemble methods..

    Provable security for lightweight message authentication and encryption

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    The birthday bound often limits the security of a cryptographic scheme to half of the block size or internal state size. This implies that cryptographic schemes require a block size or internal state size that is twice the security level, resulting in larger and more resource-intensive designs. In this thesis, we introduce abstract constructions for message authentication codes and stream ciphers that we demonstrate to be secure beyond the birthday bound. Our message authentication codes were inspired by previous work, specifically the message authentication code EWCDM by Cogliati and Seurin, as well as the work by Mennink and Neves, which demonstrates easy proofs of security for the sum of permutations and an improved bound for EWCDM. We enhance the sum of permutations by incorporating a hash value and a nonce in our stateful design, and in our stateless design, we utilize two hash values. One advantage over EWCDM is that the permutation calls, or block cipher calls, can be parallelized, whereas in EWCDM they must be performed sequentially. We demonstrate that our constructions provide a security level of 2n/3 bits in the nonce-respecting setting. Subsequently, this bound was further improved to 3n/4 bits of security. Additionally, it was later discovered that security degrades gracefully with nonce repetitions, unlike EWCDM, where the security drops to the birthday bound with a single nonce repetition. Contemporary stream cipher designs aim to minimize the hardware module's resource requirements by incorporating an externally available resource, all while maintaining a high level of security. The security level is typically measured in relation to the size of the volatile internal state, i.e., the state cells within the cipher's hardware module. Several designs have been proposed that continuously access the externally available non-volatile secret key during keystream generation. However, there exists a generic distinguishing attack with birthday bound complexity. We propose schemes that continuously access the externally available non-volatile initial value. For all constructions, conventional or contemporary, we provide proofs of security against generic attacks in the random oracle model. Notably, stream ciphers that use the non-volatile initial value during keystream generation offer security beyond the birthday bound. Based on these findings, we propose a new stream cipher design called DRACO
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