Kalman-variant estimators for state of charge in lithium-sulfur batteries

Lithium-sulfur batteries are now commercially available, offering high specific energy density, low production costs and high safety. However, there is no commercially-available battery management system for them, and there are no published methods for determining state of charge in situ. This paper describes a study to address this gap. The properties and behaviours of lithium-sulfur are briefly introduced, and the applicability of ‘standard’ lithium-ion state-of-charge estimation methods is explored. Open-circuit voltage methods and ‘Coulomb counting’ are found to have a poor fit for lithium-sulfur, and model-based methods, particularly recursive Bayesian filters, are identified as showing strong promise. Three recursive Bayesian filters are implemented: an extended Kalman filter (EKF), an unscented Kalman filter (UKF) and a particle filter (PF). These estimators are tested through practical experimentation, considering both a pulse-discharge test and a test based on the New European Driving Cycle (NEDC). Experimentation is carried out at a constant temperature, mirroring the environment expected in the authors' target automotive application. It is shown that the estimators, which are based on a relatively simple equivalent-circuit–network model, can deliver useful results. If the three estimators implemented, the unscented Kalman filter gives the most robust and accurate performance, with an acceptable computational effort

A novel safety assurance method based on the compound equivalent modeling and iterate reduce particle‐adaptive Kalman filtering for the unmanned aerial vehicle lithium ion batteries.

The safety assurance is very important for the unmanned aerial vehicle lithium ion batteries, in which the state of charge estimation is the basis of its energy management and safety protection. A new equivalent modeling method is proposed for the mathematical expression of different structural characteristics, and an improved reduce particle-adaptive Kalman filtering model is designed and built, in which the incorporate multiple featured information is absorbed to explore the optimal representation by abandoning the redundant and abnormal information. And then, the multiple parameter identification is investigated that has the ability of adapting the current varying conditions, according to which the hybrid pulse power characterization test is accommodated. As can be known from the experimental results, the polynomial fitting treatment is carried out by conducting the curve fitting treatment and the maximum estimation error of the closed-circuit-voltage is 0.48% and its state of charge estimation error is lower than 0.30% in the hybrid pulse power characterization test, which is also within 2.00% under complex current varying working conditions. The iterate calculation process is conducted for the unmanned aerial vehicle lithium ion batteries together with the compound equivalent modeling, realizing its adaptive power state estimation and safety protection effectively

Two layer Markov model for prediction of future load and end of discharge time of batteries

To predict the remaining discharge energy of a battery, it is significant to have an accurate prediction of its end of discharge time (EoDT). In recent studies, the EoDT is predicted by assuming that the battery load profile (current or power) is a priori known. However, in real-world applications future load on a battery is typically unknown with high dynamics and transients. Therefore, predicting battery EoDT in an online manner can be very challenging. The purpose of this paper is to derive a load prediction method for capturing historical charge/discharge behaviour of a battery to generate the most probable future usage of it, enabling an accurate EoDT prediction. This method is based on a two layer Markov model for the load extrapolation and iterative model-based estimation. To develop the proposed concept, lithium-ion batteries are selected and the numerical simulation results show an improvement in terms of the accuracy of the EoDT prediction compared to methods presented in the literature

Data-driven nonparametric Li-ion battery ageing model aiming at learning from real operation data – Part A : storage operation

Conventional Li-ion battery ageing models, such as electrochemical, semi-empirical and empirical models, require a significant amount of time and experimental resources to provide accurate predictions under realistic operating conditions. At the same time, there is significant interest from industry in the introduction of new data collection telemetry technology. This implies the forthcoming availability of a significant amount of real-world battery operation data. In this context, the development of ageing models able to learn from in-field battery operation data is an interesting solution to mitigate the need for exhaustive laboratory testing

A novel mechanical analogy based battery model for SoC estimation using a multi-cell EKF

The future evolution of technological systems dedicated to improve energy efficiency will strongly depend on effective and reliable Energy Storage Systems, as key components for Smart Grids, microgrids and electric mobility. Besides possible improvements in chemical materials and cells design, the Battery Management System is the most important electronic device that improves the reliability of a battery pack. In fact, a precise State of Charge (SoC) estimation allows the energy flows controller to exploit better the full capacity of each cell. In this paper, we propose an alternative definition for the SoC, explaining the rationales by a mechanical analogy. We introduce a novel cell model, conceived as a series of three electric dipoles, together with a procedure for parameters estimation relying only on voltage measures and a given current profile. The three dipoles represent the quasi-stationary, the dynamics and the istantaneous components of voltage measures. An Extended Kalman Filer (EKF) is adopted as a nonlinear state estimator. Moreover, we propose a multi-cell EKF system based on a round-robin approach to allow the same processing block to keep track of many cells at the same time. Performance tests with a prototype battery pack composed by 18 A123 cells connected in series show encouraging results.Comment: 8 page, 12 figures, 1 tabl

State of power prediction for lithium-ion batteries in electric vehicles via Wavelet-Markov load analysis

Electric vehicle (EV) power demands come from its acceleration/braking as well as consumptions of the components. The power delivered to meet any demand is limited to the available power of the battery. This makes the battery state of available power (SoAP) a critical variable for battery management purposes. This paper presents a novel approach for long-term SoAP prediction by supervising the working conditions for prediction of future load. Firstly, a battery equivalent circuit model (ECM) coupled with a thermal model is established to accurately capture the battery dynamics. The battery model is then connected to an EV model in order to interpret the working conditions to battery power demand. By supervising the historical usage conditions, a long-term load prediction mechanism is designed based on wavelet analysis and Markov models. This facilitates the separation of low and high frequency load demands and addresses future uncertainties. Finally, the SoAP prediction is put forward along with a sensitivity analysis with respect to battery model and load prediction mechanism parameters. It is demonstrated that compared to the existing approaches for load and SoAP prediction, the developed method is more practical and accurate. Co-simulations via MATLAB and AMESim as well as experiments on a set of commercially available Lithium-ion (Li-ion) cylindrical cells under real-world drive cycles prove the given concept and validate the performance of the method

METHODOLOGY FOR ON-LINE BATTERY HEALTH MONITORING

The growing demand for electric vehicles and renewable energy sources has increased the need for safe, reliable, and cost-effective energy-storage systems, many of which include batteries. The reliability and efficiency of these battery-based systems can be significantly improved using intelligent energy-management systems that effectively indicate battery health in real time. On-line monitoring can be difficult, however, because batteries are non-linear and time-varying systems whose characteristics depend on temperature, usage history, and other factors. The key metrics of interest in a battery are its remaining capacity and health. Most of the current methods require off-line measurement, and even the available on-line methods are only good in laboratory conditions. This thesis provides an enhanced streamlined framework for on-line monitoring. In this methodology, a non-intrusive test signal is superimposed upon a battery load which causes transient dynamics inside the battery. The resulting voltage and current are used as test data and the estimation is done in two parts. First, a non-linear least-squares routine is used to estimate the electrical parameters of a battery model. Second, a state-estimation algorithm is used to estimate the open-circuit voltage. Experimental results obtained at consistent temperatures demonstrate that the open-circuit voltage and parameter values together can combine to provide capacity and health measurements. This approach requires minimal hardware and could form the basis for a robust on-line monitoring system

Contributions on DC microgrid supervision and control strategies for efficiency optimization through battery modeling, management, and balancing techniques

Aquesta tesi presenta equips, models i estratègies de control que han estat desenvolupats amb l'objectiu final de millorar el funcionament d'una microxarxa CC. Es proposen dues estratègies de control per a millorar l'eficiència dels convertidors CC-CC que interconnecten les unitats de potència de la microxarxa amb el bus CC. La primera estratègia, Control d'Optimització de Tensió de Bus centralitzat, administra la potència del Sistema d'Emmagatzematge d'Energia en Bateries de la microxarxa per aconseguir que la tensió del bus segueixi la referència dinàmica de tensió òptima que minimitza les pèrdues dels convertidors. La segona, Optimització en Temps Real de la Freqüència de Commutació, consisteix a operar localment cada convertidor a la seva freqüència de commutació òptima, minimitzant les seves pèrdues. A més, es proposa una nova topologia d'equilibrador actiu de bateries mitjançant un únic convertidor CC-CC i s'ha dissenyat la seva estratègia de control. El convertidor CC-CC transfereix càrrega cel·la a cel·la, emprant encaminament de potència a través d'un sistema d'interruptors controlats. L'estratègia de control de l'equalitzador aconsegueix un ràpid equilibrat del SOC evitant sobrecompensar el desequilibri. Finalment, es proposa un model simple de degradació d'una cel·la NMC amb elèctrode negatiu de grafit. El model combina la simplicitat d'un model de circuit equivalent, que explica la dinàmica ràpida de la cel·la, amb un model físic del creixement de la capa Interfase Sòlid-Electròlit (SEI), que prediu la pèrdua de capacitat i l'augment de la resistència interna a llarg termini. El model proposat quantifica la incorporació de liti al rang de liti ciclable necessària per a aconseguir els límits de OCV després de la pèrdua de liti ciclable en la reacció secundària. El model de degradació SEI pot emprar-se per a realitzar un control predictiu de bateries orientat a estendre la seva vida útil.Aquesta tesi presenta equips, models i estratègies de control que han estat desenvolupats amb l'objectiu final de millorar el funcionament d'una microxarxa CC. Es proposen dues estratègies de control per a millorar l'eficiència dels convertidors CC-CC que interconnecten les unitats de potència de la microxarxa amb el bus CC. La primera estratègia, Control d'Optimització de Tensió de Bus centralitzat, administra la potència del Sistema d'Emmagatzematge d'Energia en Bateries de la microxarxa per aconseguir que la tensió del bus segueixi la referència dinàmica de tensió òptima que minimitza les pèrdues dels convertidors. La segona, Optimització en Temps Real de la Freqüència de Commutació, consisteix a operar localment cada convertidor a la seva freqüència de commutació òptima, minimitzant les seves pèrdues. A més, es proposa una nova topologia d'equilibrador actiu de bateries mitjançant un únic convertidor CC-CC i s'ha dissenyat la seva estratègia de control. El convertidor CC-CC transfereix càrrega cel·la a cel·la, emprant encaminament de potència a través d'un sistema d'interruptors controlats. L'estratègia de control de l'equalitzador aconsegueix un ràpid equilibrat del SOC evitant sobrecompensar el desequilibri. Finalment, es proposa un model simple de degradació d'una cel·la NMC amb elèctrode negatiu de grafit. El model combina la simplicitat d'un model de circuit equivalent, que explica la dinàmica ràpida de la cel·la, amb un model físic del creixement de la capa Interfase Sòlid-Electròlit (SEI), que prediu la pèrdua de capacitat i l'augment de la resistència interna a llarg termini. El model proposat quantifica la incorporació de liti al rang de liti ciclable necessària per a aconseguir els límits de OCV després de la pèrdua de liti ciclable en la reacció secundària. El model de degradació SEI pot emprar-se per a realitzar un control predictiu de bateries orientat a estendre la seva vida útil.This dissertation presents a set of equipment, models and control strategies, that have been developed with the final goal of improving the operation of a DC microgrid. Two control strategies are proposed to improve the efficiency of the DC-DC converters that interface the microgrid’s power units with the DC bus. The first strategy is centralized Bus Voltage Optimization Control, which manages the power of the microgrid’s Battery Energy Storage System to make the bus voltage follow the optimum voltage dynamic reference that minimizes the converters’ losses. The second control strategy is Online Optimization of Switching Frequency, which consists in locally operating each converter at its optimum switching frequency, again minimizing power losses. The two proposed optimization strategies have been validated in simulations. Moreover, a new converter-based active balancing topology has been proposed and its control strategy has been designed. This equalizer topology consists of a single DC-DC converter that performs cell-to-cell charge transfer employing power routing via controlled switches. The control strategy of the equalizer has been designed to achieve rapid SOC balancing while avoiding imbalance overcompensation. Its performance has been validated in simulation. Finally, a simple degradation model of an NMC battery cell with graphite negative electrode is proposed. The model combines the simplicity of an equivalent circuit model, which explains the fast dynamics of the cell, with a physical model of the Solid-Electrolyte Interphase (SEI) layer growth process, which predicts the capacity loss and the internal resistance rise in the long term. The proposed model fine-tunes the capacity loss prediction by accounting for the incorporation of unused lithium reserves of both electrodes into the cyclable lithium range to reach the OCV limits after the side reaction has consumed cyclable lithium. The SEI degradation model can be used to perform predictive control of batteries oriented toward extending their lifetime