Molten salt corrosion of SiC and Si3N4

Industrial systems such as heat engines and heat exchangers involve harsh environments. The structural materials are subjected to high temperatures as well as corrosive gases and condensed phases. Past experience with metal alloys has shown that these condensed phases can be particularly corrosive and are often the limiting factor in the operation of these systems. In a heat engine the most common condensed corrodent is Na2SO4 whereas in a heat exchanger an oxide slag may be present. The primary emphasis is on Na2SO4 induced corrosion, however, similarities and differences to oxide slag are also discussed. The extensive research on corrosion of metal alloys has led to understanding and controlling corrosion for these materials. Currently silicon based ceramics are prime candidates for the applications discussed. Therefore it is important to understand the effects of condensed phase deposits on this emerging class of high temperature materials. Both the thermodynamic and strength of the ceramic is also examined. Finally some control strategies for corrosion of silicon based ceramics are explored

IMPROVING SMART GRID SECURITY USING MERKLE TREES

Abstract—Presently nations worldwide are starting to convert their aging electrical power infrastructures into modern, dynamic power grids. Smart Grid offers much in the way of efficiencies and robustness to the electrical power grid, however its heavy reliance on communication networks will leave it more vulnerable to attack than present day grids. This paper looks at the threat to public key cryptography systems from a fully realized quantum computer and how this could impact the Smart Grid. We argue for the use of Merkle Trees in place of public key cryptography for authentication of devices in wireless mesh networks that are used in Smart Grid applications

Transformation of amorphous carbon clusters to fullerenes

Transformation of amorphous carbon clusters into fullerenes under high temperature is studied using molecular dynamics simulations at microsecond times. Based on the analysis of both structure and energy of the system, it is found that fullerene formation occurs in two stages. Firstly, fast transformation of the initial amorphous structure into a hollow sp$^2$ shell with a few chains attached occurs with a considerable decrease of the potential energy and the number of atoms belonging to chains and to the amorphous domain. Then, insertion of remaining carbon chains into the sp$^2$ network takes place at the same time with the fullerene shell formation. Two types of defects remaining after the formation of the fullerene shell are revealed: 7-membered rings and single one-coordinated atoms. One of the fullerene structures obtained contains no defects at all, which demonstrates that defect-free carbon cages can be occasionally formed from amorphous precursors directly without defect healing. No structural changes are observed after the fullerene formation, suggesting that defect healing is a slow process in comparison with the fullerene shell formation. The schemes of the revealed reactions of chain atoms insertion into the fullerene shell just before its completion are presented. The results of the performed simulations are summarized within the paradigm of fullerene formation due to selforganization of the carbon system.Comment: 35 pages, 9 figure

Collisions of inhomogeneous pre-planetesimals

In the framework of the coagulation scenario, kilometre-sized planetesimals form by subsequent collisions of pre-planetesimals of sizes from centimetre to hundreds of metres. Pre-planetesimals are fluffy, porous dust aggregates, which are inhomogeneous owing to their collisional history. Planetesimal growth can be prevented by catastrophic disruption in pre-planetesimal collisions above the destruction velocity threshold. We develop an inhomogeneity model based on the density distribution of dust aggregates, which is assumed to be a Gaussian distribution with a well-defined standard deviation. As a second input parameter, we consider the typical size of an inhomogeneous clump. These input parameters are easily accessible by laboratory experiments. For the simulation of the dust aggregates, we utilise a smoothed particle hydrodynamics (SPH) code with extensions for modelling porous solid bodies. The porosity model was previously calibrated for the simulation of silica dust, which commonly serves as an analogue for pre-planetesimal material. The inhomogeneity is imposed as an initial condition on the SPH particle distribution. We carry out collisions of centimetre-sized dust aggregates of intermediate porosity. We vary the standard deviation of the inhomogeneous distribution at fixed typical clump size. The collision outcome is categorised according to the four-population model. We show that inhomogeneous pre-planetesimals are more prone to destruction than homogeneous aggregates. Even slight inhomogeneities can lower the threshold for catastrophic disruption. For a fixed collision velocity, the sizes of the fragments decrease with increasing inhomogeneity. Pre-planetesimals with an active collisional history tend to be weaker. This is a possible obstacle to collisional growth and needs to be taken into account in future studies of the coagulation scenario.Comment: 12 pages, 9 figures, 4 table

Design of Self-Healing Key Distribution Schemes

A self-healing key distribution scheme enables dynamic groups of users of an unreliable network to establish group keys for secure communication. In such a scheme, a group manager, at the beginning of each session, in order to provide a key to each member of the group, sends packets over a broadcast channel. Every user, belonging to the group, computes the group key by using the packets and some private information. The group manager can start multiple sessions during a certain time-interval, by adding/removing users to/from the initial group. The main property of the scheme is that, if during a certain session some broadcasted packet gets lost, then users are still capable of recovering the group key for that session simply by using the packets they have received during a previous session and the packets they will receive at the beginning of a subsequent one, without requesting additional transmission from the group manager. Indeed, the only requirement that must be satisfied, in order for the user to recover the lost keys, is membership in the group both before and after the sessions in which the broadcast messages containing the keys are sent. This novel and appealing approach to key distribution is quite suitable in certain military applications and in several Internet-related settings, where high security requirements need to be satisfied. In this paper we continue the study of self-healing key distribution schemes, introduced by Staddon et al. [37]. We analyze some existing constructions: we show an attack that can be applied to one of these constructions, in order to recover session keys, and two problems in another construction. Then, we present a new mechanism for implementing the self-healing approach, and we present an efficient construction which is optimal in terms of user memory storage. Finally, we extend the self-healing approach to key distribution, and we present a scheme which enables a user to recover from a single broadcast message all keys associated with sessions in which he is member of the communication group

Mechanism of strength degradation for hot corrosion of alpha-SiC

Sintered alpha SiC was corroded by thin films of Na2SO4 and Na2CO3 molten salts at 1000%. This hot corrosion attack reduced room temperature strengths by as much as 50%. Strength degradation was porportional to the degree and uniformity of corrosion pitting attack as controlled by the chemistry of the molten salt. Extensive fractography identified corrosion pits as the most prevalent source of failure. A fracture mechanics treatment of the strength/pit depth relationship produced an average K sub IC equal to 2.6 MPa sub m 1/2, which is consistent with published values

A Biomimic Self-healing Shape Memory Polymer Based Syntactic Foam for Smart Structural Composites

This study explored the development of a new self-healing Polystyrene Shape Memory Polymer (PSMP) based syntactic foam for service life extension in structural polymeric composites. The objective was to self-heal structural-length scale damage in an autonomous, efficient, timely and repeatable manner at the molecular-length scale. Self-healing is achieved through a novel two step close-then-heal (CTH) self-healing scheme, designed to mimic the natural biological process of wound healing in humans. A new methodology to fabricate three-dimensional (3-D) fiber reinforced shape memory polymer syntactic foam for structural applications was developed. The effect of impact energy on the ability for the 3-D fiber reinforced PSMP syntactic foam (PSMP-SF) panels to seal cracks and mitigate impact was investigated in terms of the number of impacts to complete perforation. It was found that by restoring surface dents and closing internal crack, perforation was delayed (from 9 impacts to 16 impacts at 32 J impact energy) and (from 5 impacts to 7 impacts at 42 J impact energy). A new self-healing particulate composite was developed by incorporating co-polyester thermoplastic particles (6% by volume) within the PSMP matrix. The self-healing behavior of the composite was studied on single edge notched bend (SENB) specimens through three-point bending tests. Miscibility between the PSMP and the CP was validated through differential scanning calorimetric (DSC) analysis. It was found that the composite can heal structural-length scale damage at the molecular level in 20 minutes at 150 °C. Measured in terms of fracture load, a repeatable healing efficiency of 65% was obtained. The effect of thermoplastic content on self-healing efficiency and fracture toughness of the new self-healing particulate composite was investigated. It was found that the healing efficiency increased with thermoplastic content. However, the fracture toughness of the composite decreased in the same direction. The healing efficiencies at 3% and 9% CP volume fraction were respectively 50% and 75%. A new biomimetic self-healing syntactic foam was developed and shown to heal structural-length scale damage with a healing efficiency of 50% based on fracture load in three-point bending test. Repeated impact and self-healing tests revealed excellent impact tolerance and superior impact mitigation capabilities

NECESSITY TO SECURE WIRELESS SENSOR NETWORK

Wireless sensor networks are often deployed in hostile and unattended environments. The nodes will be failure by fault, intrusion and battery exhaustion. Node - failure tolerance is an acceptable method to improve the networks lifetime. In this paper, two key problems for topology control are presented: first, how to get a node - failure topology when there is intrusion from the nodes of hostile enemies? Secondly , how to sustain this node - failure topology with all deployed node s being exhausted ultimately? Here we suggest a novel approach for topology control and prove that it is node - failure tolerant. The approach contains three phases: topology discovery, topology update, and topology regeneration. A tricolor - based method is proposed to build architecture with high tolerance ability and some security protocols are employed to preclude the hostile nodes in discovery phase. In update and regeneration phases, the newly deployed nodes are regarded as renewable resource to fill in the consumed energy, enhance the debased node - failure tolerance ability, prolong network lifetime d . A security protocol with forward and backward secrecy is devised to adapt the topology changed by node failure and node joining. Some attributes of the presented method are shown by simulations, and differences a re given by comparison with related work

Interfacial strength development in thermoplastic resins and fiber-reinforced thermoplastic composites

An experimental program to develop test methods to be used to characterize interfacial (autohesive) strength development in polysulfone thermoplastic resin and graphite-polysulfone prepreg during processing is reported. Two test methods were used to examine interfacial strength development in neat resin samples. These included an interfacial tension test and a compact tension (CT) fracture toughness test. The interfacial tensile test proved to be very difficult to perform with a considerable amount of data scatter. Thus, the interfacial test was discarded in favor of the fracture toughness test. Interfacial strength development was observed by measuring the refracture toughness of precracked compact tension specimens that were rehealed at a given temperature and contact time. The measured refracture toughness was correlated with temperature and contact time. Interfacial strength development in graphite-polysulfone unidirectional composites was measured using a double cantilever beam (DCB) interlaminar fracture toughness test. The critical strain energy release rate of refractured composite specimens was measured as a function of healing temperature and contact time