A numerical study of one-patch colloidal particles: from square-well to Janus

We perform numerical simulations of a simple model of one-patch colloidal particles to investigate: (i) the behavior of the gas-liquid phase diagram on moving from a spherical attractive potential to a Janus potential and (ii) the collective structure of a system of Janus particles. We show that, for the case where one of the two hemispheres is attractive and one is repulsive, the system organizes into a dispersion of orientational ordered micelles and vesicles and, at low $T$, the system can be approximated as a fluid of such clusters, interacting essentially via excluded volume. The stability of this cluster phase generates a very peculiar shape of the gas and liquid coexisting densities, with a gas coexistence density which increases on cooling, approaching the liquid coexistence density at very low $T$.Comment: 9 pages, 10 figures, Phys. Chem. Chem. Phys. in press (2010

Polydisperse fluid mixtures of adhesive colloidal particles

We investigate polydispersity effects on the average structure factor of colloidal suspensions of neutral particles with surface adhesion. A sticky hard sphere model alternative to Baxter's one is considered. The choice of factorizable stickiness parameters in the potential allows a simple analytic solution, within the ``mean spherical approximation'', for any number of components and arbitrary stickiness distribution. Two particular cases are discussed: i) all particles have different sizes but equal stickiness (Model I), and ii) each particle has a stickiness proportional to its size (Model II). The interplay between attraction and polydispersity yields a markedly different behaviour for the two Models in regimes of strong coupling (i.e. strong adhesive forces and low temperature) and large polydispersity. These results are then exploited to reanalyze experimental scattering data on sterically stabilized silica particles.Comment: 9 pages, 2 figures (included), Physica A (2001) to appea

New insights on Anthracotherium monsvialense De Zigno, 1888 (Mammalia, Cetartiodactyla) from the lower Oligocene of Monteviale (Vicenza, northeastern Italy)

In Italy, anthracotheres are represented by a few fossils, most of them described during the XIX century and without a standardized scientific method. Anthracotherium monsvialense De Zigno, 1888 was originally erected from a fossil discovered in the site of Monteviale (Vicenza, northeastern Italy), whose Rupelian (MP21) lignitic beds yielded the richest lower Oligocene evidence of the genus Anthracotherium in Europe. A. monsvialense ranges from MP21 to MP23 and its small size has been interpreted as a consequence of the insular environment, at least at Monteviale. In this study, we summarize the long history of Italian findings providing new descriptions of dental and postcranial morphological features of A. monsvialense, and comparing such small anthracothere with its Asian and European relatives. Morphometric analyses are also performed on teeth, in order to verify the presence of evolutionary trends of the genus Anthracotherium

Influence of mismatch on the defects in relaxed epitaxial InGaAs/GaAs(100) films grown by molecular beam epitaxy

Thick (∼3 μm) films of InxGa1−xAs grown on GaAs(100) substrates, across the whole composition range, have been examined by transmission electron microscopy and double‐crystal x‐ray diffraction. The results were compared with the observed growth mode of the material determined by in situ reflection high‐energy electron diffraction in the molecular beam epitaxy growth system. The quality of the material degraded noticeably for compositions up to x∼0.5 associated with an increased density of dislocations and stacking faults. In contrast, improvements in quality as x approached 1.0 were correlated with the introduction of an increasingly more regular array of edge dislocations

The impact of air pollution on hospital admissions: Evidence from Italy

In this paper we study the impact of air pollution on hospital admissions for chronic obstructive pulmonary disease for 103 Italian provinces, over the period from 2004 to 2009. We use information on annual mean concentrations of carbon monoxide, nitrogen dioxide, particulate matter, and ozone measured at monitoring station level to build province-level indicators of pollution. Hence, we estimate a regression model for hospital admissions, where we allow our aggregate measures of pollution to be subject to measurement error and correlated with the error term. We also adopt standard errors for estimates that are robust to serial and spatial correlation in the error term, to allow for temporal persistence and geographical concentration of unobservable risk factors.We find that higher levels of particulate matter are associated with higher levels of hospitalisation for children, while ozone plays an important role in explaining hospital admissions of the elderly. Other factors that appear to have an effect on hospital admissions for chronic obstructive pulmonary disease are precipitation and provincial unemployment rate

Transforming Normal Programs by Replacement

The replacement transformation operation, already defined in [28], is studied wrt normal programs. We give applicability conditions able to ensure the correctness of the operation wrt Fitting's and Kunen's semantics. We show how replacement can mimic other transformation operations such as thinning, fattening and folding, thus producing applicability conditions for them too. Furthermore we characterize a transformation sequence for which the preservation of Fitting's and Kunen's semantics is ensured

A Numerical Test of a High-Penetrability Approximation for the One-Dimensional Penetrable-Square-Well Model

The one-dimensional penetrable-square-well fluid is studied using both analytical tools and specialized Monte Carlo simulations. The model consists of a penetrable core characterized by a finite repulsive energy combined with a short-range attractive well. This is a many-body one-dimensional problem, lacking an exact analytical solution, for which the usual van Hove theorem on the absence of phase transition does not apply. We determine a high-penetrability approximation complementing a similar low-penetrability approximation presented in previous work. This is shown to be equivalent to the usual Debye-H\"{u}ckel theory for simple charged fluids for which the virial and energy routes are identical. The internal thermodynamic consistency with the compressibility route and the validity of the approximation in describing the radial distribution function is assessed by a comparison against numerical simulations. The Fisher-Widom line separating the oscillatory and monotonic large-distance behavior of the radial distribution function is computed within the high-penetrability approximation and compared with the opposite regime, thus providing a strong indication of the location of the line in all possible regimes. The high-penetrability approximation predicts the existence of a critical point and a spinodal line, but this occurs outside the applicability domain of the theory. We investigate the possibility of a fluid-fluid transition by Gibbs ensemble Monte Carlo techniques, not finding any evidence of such a transition. Additional analytical arguments are given to support this claim. Finally, we find a clustering transition when Ruelle's stability criterion is not fulfilled. The consequences of these findings on the three-dimensional phase diagrams are also discussed.Comment: 17 pages, 12 figures; to be published in JC

A pseudo-spectral method for the Kardar-Parisi-Zhang equation

We discuss a numerical scheme to solve the continuum Kardar-Parisi-Zhang equation in generic spatial dimensions. It is based on a momentum-space discretization of the continuum equation and on a pseudo-spectral approximation of the non-linear term. The method is tested in (1+1)- and (2+1)- dimensions, where it is shown to reproduce the current most reliable estimates of the critical exponents based on Restricted Solid-on-Solid simulations. In particular it allows the computations of various correlation and structure functions with high degree of numerical accuracy. Some deficiencies which are common to all previously used finite-difference schemes are pointed out and the usefulness of the present approach in this respect is discussed.Comment: 12 pages, 13 .eps figures, revetx4. A few equations have been corrected. Erratum sent to Phys. Rev.

Real Space Renormalization Group for Langevin Dynamics in Absence of Translational Invariance

A novel exact dynamical real space renormalization group for a Langevin equation derivable from a Euclidean Gaussian action is presented. It is demonstrated rigorously that an algebraic temporal law holds for the Green function on arbitrary structures of infinite extent. In the case of fractals it is shown on specific examples that two different fixed points are found at variance with periodic structures. Connection with growth dynamics of interfaces is also discussed.Comment: 22 pages, RevTex 3.0, 5 figures available upon request from [email protected], to be published in J.Stat.Phy

The cost of space independence in P300-BCI spellers.

Background: Though non-invasive EEG-based Brain Computer Interfaces (BCI) have been researched extensively over the last two decades, most designs require control of spatial attention and/or gaze on the part of the user. Methods: In healthy adults, we compared the offline performance of a space-independent P300-based BCI for spelling words using Rapid Serial Visual Presentation (RSVP), to the well-known space-dependent Matrix P300 speller. Results: EEG classifiability with the RSVP speller was as good as with the Matrix speller. While the Matrix speller’s performance was significantly reliant on early, gaze-dependent Visual Evoked Potentials (VEPs), the RSVP speller depended only on the space-independent P300b. However, there was a cost to true spatial independence: the RSVP speller was less efficient in terms of spelling speed. Conclusions: The advantage of space independence in the RSVP speller was concomitant with a marked reduction in spelling efficiency. Nevertheless, with key improvements to the RSVP design, truly space-independent BCIs could approach efficiencies on par with the Matrix speller. With sufficiently high letter spelling rates fused with predictive language modelling, they would be viable for potential applications with patients unable to direct overt visual gaze or covert attentional focus