21,824 research outputs found
Investigation of laser induced phosphorescence and fluorescence of acetone at low pressure for molecular tagging velocimetry in gas microflows
This paper was presented at the 4th Micro and Nano Flows Conference (MNF2014), which was held at University College, London, UK. The conference was organised by Brunel University and supported by the Italian Union of Thermofluiddynamics, IPEM, the Process Intensification Network, the Institution of Mechanical Engineers, the Heat Transfer Society, HEXAG - the Heat Exchange Action Group, and the Energy Institute, ASME Press, LCN London Centre for Nanotechnology, UCL University College London, UCL Engineering, the International NanoScience Community, www.nanopaprika.eu.Laser-induced fluorescence and phosphorescence properties of gaseous acetone in argon are
measured and analyzed in a pressure ranging from 10(5) to 10(2) Pa, with the aim of analyzing by molecular
tagging velocimetry gas microflows in rarefied regimes which requires operation at low pressure. Acetone is
excited at a wavelength of 266 nm and immediately emits short lifetime fluorescence rapidly followed by
long lifetime phosphorescence. At atmospheric pressure, the early phosphorescence intensity is more than
600 times lower than the fluorescence one. The phosphorescence signal is rapidly decreasing with time,
closely following a power law. Both fluorescence and phosphorescence signals are decreasing with pressure.
The systematic analysis of fluorescence and phosphorescence of acetone molecules shows that although the
signal is dramatically reduced at low pressure, the on-chip integration technique and the optimization of the
acquisition parameters provide an exploitable signal for molecular tagging velocimetry in rarefied
microflows, in a Knudsen number range corresponding to the early slip flow regime
Iridium complex, a phosphorescent light-emitting diode material, serves as a novel chemical probe for imaging hypoxic tumor tissues
Iridium complex, a promising organic light-emitting diode for next generation television displays, emits phosphorescence. Phosphorescence is quenched by oxygen. We used this oxygen-quenching feature for imaging tumor hypoxia. Red light-emitting iridium complex Ir(btp)~2~(acac) (BTP) presented hypoxia-dependent light emission in culture cell lines, whose intensity was in parallel with HIF-1[alpha] expression. BTP was further applied to imaging five tumors (four from human origin and one from mouse origin) transplanted in athymic mice. All tumors presented a bright BTP-emitting image even 5 min after the injection. The BTP-dependent tumor image peaked at 1 to 2 h after the injection, and was then cleared from tumors within 24 h. The minimal BTP image recognition size was 3 to 4 mm in diameter. Compared with ^18^F-FDG/PET images, BTP delineated a clearer image for a tumor profile. We suggest that iridium complex has a vast potential for imaging hypoxic lesions such as tumor tissues
Highly efficient, dual state emission from an organic semiconductor
We report highly efficient, simultaneous fluorescence and phosphorescence
(74% yield) at room temperature from a single molecule ensemble of (BzP)PB
dispersed into a polymer host. The slow phosphorescence (208 ms lifetime) is
very efficient (50%) at room temperature and only possible because the
non-radiative rate for the triplet state is extremely low. The ability of an
organic molecule to function as an efficient dual state emitter at room
temperature is unusual and opens new fields of applications including the use
as broadband down-conversion emitters, optical sensors and attenuators, exciton
probes, and spin-independent intermediates for F\"orster resonant energy
transfer
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Space charge induced luminescence in epoxy resin
Dielectric breakdown of epoxies is preceded by a light emission from the solid state material, so-called electroluminescence. Very little is known however on the luminescence properties of epoxy. The aim of this paper is to derive information that can be used as a basis to understand the nature of the excited states and their involvement in electrical degradation processes
Gas phase thermometry of hot turbulent jets using laser induced phosphorescence
This article is made available through the Brunel Open Access Publishing Fund. Copyright @ 2013 OSAThe temperature distributions of heated turbulent jets of air were determined using two dimensional (planar) laser induced phosphorescence. The jets were heated to specific temperature increments, ranging from 300 – 850 K and several Reynolds numbers were investigated at each temperature. The spectral ratio technique was used in conjunction with thermographic phosphors BAM and YAG:Dy, individually. Single shot and time averaged results are presented as two dimensional stacked images of turbulent jets. YAG:Dy did not produce a high enough signal for single shot measurements. The results allowed for a direct comparison between BAM and YAG:Dy, revealing that BAM is more suitable for relatively lower temperature, fast and turbulent regimes and that YAG:Dy is more suited to relatively higher temperature, steady flow situations
Coherent energy migration in solids: Determination of the average coherence length in one‐dimensional systems using tunable dye lasers
The coherent nature of energy propagation in solids at low temperatures was established from the time resolved response of the crystal to short optical pulses obtained from a dye laser (pumped by a nitrogen gas laser). The trapping and detrapping of the energy by shallow defects (x traps) was evident in the spectra and enabled us to extract the coherence length: l≳700 Å=186 molecules for the one‐dimensional triplet excitons of 1,2,4,5‐tetrachlorobenzene crystals at T<4.2° K. This length which clearly exceeds the stochastic random walk limit is related to the thermalization mechanisms in this coupled exciton–trap system, and its magnitude supports the notion that exciton–phonon coupling is responsible for the loss of coherence on very long molecular chains (trap concentration is 1/256 000)
Validation of phosphor thermometry for industrial surface temperature measurements
Surface temperature measurements are required by the aerospace and automotive industries to guarantee high-quality products and optimize production processes. Accurate and reliable measurement of surface temperature is very challenging in an industrial environment. Surface contact probes are widely used but poorly characterized, while non-contact infrared thermometry is severely hampered by the unknown emissivity of the surface and by problems caused by stray radiation from the background. An alternative approach to the above techniques is phosphor thermometry, used here in a hybrid contact/non-contact approach.
In this work, the development of a lifetime-based phosphor thermometer, its application to industrial surface temperature measurement and its validation are reported in a metrologically sound manner. The phosphor thermometer was initially calibrated by contact on a reference calibrator system at the Istituto Nazionale di Ricerca Metrologica to provide SI traceability to the measurements at the industrial level; the system was later validated by exploiting a metal phase-change method. The robustness of the approach against a strong radiative background was also investigated. A comprehensive uncertainty analysis was carried out, resulting in an expanded uncertainty (k = 2) lower than 1.4 °C over the temperature range from the ambient to 450 °C.
The phosphor-based thermometer was then tested at industrial manufacturing premises to measure the surface temperature of aluminium alloy billets during the pre-heating phase before forging. The phosphor-based approach was compared with radiation and contact thermometry in both static and dynamic measurement conditions. The experimental results proved that phosphor thermometry, besides being a valid alternative to conventional techniques, may offer better performance in an industrial setting
Correlative Microscopy of Morphology and Luminescence of Cu porphyrin aggregates
Transfer of energy and information through molecule aggregates requires as
one important building block anisotropic, cable-like structures. Knowledge on
the spatial correlation of luminescence and morphology represents a
prerequisite in the understanding of internal processes and will be important
for architecting suitable landscapes. In this context we study the morphology,
fluorescence and phosphorescence of molecule aggregate structures on surfaces
in a spatially correlative way. We consider as two morphologies, lengthy
strands and isotropic islands. It turns out that phosphorescence is quite
strong compared to fluorescence and the spatial variation of the observed
intensities is largely in line with the amount of dye. However in proportion,
the strands exhibit more fluorescence than the isotropic islands suggesting
weaker non-radiative channels. The ratio fluorescence to phosphorescence
appears to be correlated with the degree of aggregation or internal order. The
heights at which luminescence saturates is explained in the context of
attenuation and emission multireflection, inside the dye. This is supported by
correlative photoemission electron microscopy which is more sensitive to the
surface region. The lengthy structures exhibit a pronounced polarization
dependence of the luminescence with a relative dichroism up to about 60%,
revealing substantial perpendicular orientation preference of the molecules
with respect to the substrate and parallel with respect to the strands
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Photoluminescence, recombination induced luminescence and electroluminescence in epoxy resin
Dielectric breakdown of epoxies is preceded by light emission, or so-called electroluminescence, from the solid-state material. Very little is known about the luminescence properties of epoxies. The aim of this paper is to derive information that can be used as a basis to understand the nature of the excited states and their involvement in electrical degradation processes. Three different kinds of stimulation were used to excite the material luminescence. Photoluminescence was performed on the base resin, the hardener and the cured resin. Luminescence excited by a silent discharge has been analysed to identify which of the luminescent centres are optically active upon the recombination of electrical charges and could therefore act as charge traps. Finally, the electroluminescence spectrum has been acquired and compared with the previous ones. Although the identification of the origin of these emissions is far from being complete, it has been found that the photoluminescence from the cured resin is due to in-chain chromophores, which acts as trapping centres. The excited states involved in photoluminescence also seems to be involved in electroluminescence, but other components are detected as well, which could be due to the degradation of the resin molecule under the effect of the electric stress
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