Impact of the earthworm Lumbricus terrestris (L.) on As, Cu, Pb and Zn mobility and speciation in contaminated soils

To assess the risks that contaminated soils pose to the environment properly a greater understanding of how soil biota influence the mobility of metal(loid)s in soils is required. Lumbricus terrestris L. were incubated in three soils contaminated with As, Cu, Pb and Zn. The concentration and speciation of metal(loid)s in pore waters and the mobility and partitioning in casts were compared with earthworm-free soil. Generally the concentrations of water extractable metal(loid)s in earthworm casts were greater than in earthworm-free soil. The impact of the earthworms on concentration and speciation in pore waters was soil and metal specific and could be explained either by earthworm induced changes in soil pH or soluble organic carbon. The mobilisation of metal(loid)s in the environment by earthworm activity may allow for leaching or uptake into biota

Impact of the earthworm Lumbricus terrestris (L.) on As, Cu, Pb and Zn mobility and speciation in contaminated soils

To assess the risks that contaminated soils pose to the environment properly a greater understanding of how soil biota influence the mobility of metal(loid)s in soils is required. Lumbricus terrestris L. were incubated in three soils contaminated with As, Cu, Pb and Zn. The concentration and speciation of metal(loid)s in pore waters and the mobility and partitioning in casts were compared with earthworm-free soil. Generally the concentrations of water extractable metal(loid)s in earthworm casts were greater than in earthworm-free soil. The impact of the earthworms on concentration and speciation in pore waters was soil and metal specific and could be explained either by earthworm induced changes in soil pH or soluble organic carbon. The mobilisation of metal(loid)s in the environment by earthworm activity may allow for leaching or uptake into biota

Corrosion resistant coating

A method of coating a substrate with an amorphous metal is described. A solid piece of the metal is bombarded with ions of an inert gas in the presence of a magnetic field to provide a vapor of the metal which is deposited on the substrate at a sufficiently low gas pressure so that there is formed on the substrate a thin, uniformly thick, essentially pinhole-free film of the metal

Impacts of epigeic, anecic and endogeic earthworms on metal and metalloid mobility and availability

The introduction of earthworms into soils contaminated with metals and metalloids has been suggested to aid restoration practices. Eisenia veneta (epigeic), Lumbricus terrestris (anecic) and Allolobophora chlorotica (endogeic) earthworms were cultivated in columns containing 900 g soil with 1130, 345, 113 and 131 mg kg1 of As, Cu, Pb and Zn, respectively, for up to 112 days, in parallel with earthworm-free columns. Leachate was produced by pouring water on the soil surface to saturate the soil and generate downflow. Ryegrass was grown on the top of columns to assess metal uptake into biota. Different ecological groups affected metals in the same way by increasing concentrations and free ion activities in leachate, but anecic L. terrestris had the greatest effect by increasing leachate concentrations of As by 267%, Cu by 393%, Pb by 190%, and Zn by 429% compared to earthworm-free columns. Ryegrass grown in earthworm-bearing soil accumulated more metal and the soil microbial community exhibited greater stress. Results are consistent with earthworm enhanced degradation of organic matter leading to release of organically bound elements. The degradation of organic matter also releases organic acids which decrease the soil pH. The earthworms do not appear to carry out a unique process, but increase the rate of a process that is already occurring. The impact of earthworms on metal mobility and availability should therefore be considered when inoculating earthworms into contaminated soils as new pathways to receptors may be created or the flow of metals and metalloids to receptors may be elevated

Efficiency evaluation of food waste materials for the removal of metals and metalloids from complex multi-element solutions

Recent studies have shown the potential of food waste materials as low cost adsorbents for the removal of heavy metals and toxic elements from wastewater. However, the adsorption experiments have been performed in heterogeneous conditions, consequently it is difficult to compare the efficiency of the individual adsorbents. In this study, the adsorption capacities of 12 food waste materials were evaluated by comparing the adsorbents' efficiency for the removal of 23 elements from complex multi-element solutions, maintaining homogeneous experimental conditions. The examined materials resulted to be extremely efficient for the adsorption of many elements from synthetic multi-element solutions as well as from a heavy metal wastewater. The 12 adsorbent surfaces were analyzed by Fourier transform infrared spectroscopy and showed different types and amounts of functional groups, which demonstrated to act as adsorption active sites for various elements. By multivariate statistical computations of the obtained data, the 12 food waste materials were grouped in five clusters characterized by different elements' removal efficiency which resulted to be in correlation with the specific adsorbents' chemical structures. Banana peel, watermelon peel and grape waste resulted the least selective and the most efficient food waste materials for the removal of most of the elements

Food waste materials appear efficient and low-cost adsorbents for the removal of organic and inorganic pollutants from wastewater

In recent studies, the adsorption capacity of several food waste materials has been assessed by performing adsorption experiments in heterogeneous operating conditions. In a latest study, the efficiency of such food waste materials for the removal of metals and metalloids from complex multi-element solutions was evaluated in homogeneous experimental conditions, which allowed comparing the adsorption capacities of the individual adsorbents. Considering the high efficiency of the examined low-cost adsorbents for the removal of inorganic pollutants, preliminary studies were conducted in our lab for assessing the potential of the investigated food waste materials to adsorb volatile organic compounds from a real polluted matrix of leachate. Some recent studies have shown the efficiency of low cost materials for the removal of industrial organic dyes, polycyclic aromatic hydrocarbons and phenolic compounds. However, the food waste adsorbents’ efficiency for the removal of volatile organic compounds was not investigated. Our preliminary studies showed good adsorption capacities of the examined food waste materials for aliphatic and aromatic hydrocarbons. Therefore, it is worth to carry out further studies about volatile organic compounds’ removal by food waste adsorbents

Bioavailability in soils

The consumption of locally-produced vegetables by humans may be an important exposure pathway for soil contaminants in many urban settings and for agricultural land use. Hence, prediction of metal and metalloid uptake by vegetables from contaminated soils is an important part of the Human Health Risk Assessment procedure. The behaviour of metals (cadmium, chromium, cobalt, copper, mercury, molybdenum, nickel, lead and zinc) and metalloids (arsenic, boron and selenium) in contaminated soils depends to a large extent on the intrinsic charge, valence and speciation of the contaminant ion, and soil properties such as pH, redox status and contents of clay and/or organic matter. However, chemistry and behaviour of the contaminant in soil alone cannot predict soil-to-plant transfer. Root uptake, root selectivity, ion interactions, rhizosphere processes, leaf uptake from the atmosphere, and plant partitioning are important processes that ultimately govern the accumulation ofmetals and metalloids in edible vegetable tissues. Mechanistic models to accurately describe all these processes have not yet been developed, let alone validated under field conditions. Hence, to estimate risks by vegetable consumption, empirical models have been used to correlate concentrations of metals and metalloids in contaminated soils, soil physico-chemical characteristics, and concentrations of elements in vegetable tissues. These models should only be used within the bounds of their calibration, and often need to be re-calibrated or validated using local soil and environmental conditions on a regional or site-specific basis.Mike J. McLaughlin, Erik Smolders, Fien Degryse, and Rene Rietr

Electronic stress tensor analysis of molecules in gas phase of CVD process for GeSbTe alloy

We analyze the electronic structure of molecules which may exist in gas phase of chemical vapor deposition process for GeSbTe alloy using the electronic stress tensor, with special focus on the chemical bonds between Ge, Sb and Te atoms. We find that, from the viewpoint of the electronic stress tensor, they have intermediate properties between alkali metals and hydrocarbon molecules. We also study the correlation between the bond order which is defined based on the electronic stress tensor, and energy-related quantities. We find that the correlation with the bond dissociation energy is not so strong while one with the force constant is very strong. We interpret these results in terms of the energy density on the "Lagrange surface", which is considered to define the boundary surface of atoms in a molecule in the framework of the electronic stress tensor analysis.Comment: 32 pages, 9 figure

Recognition of Trace Element Contamination Using Ficus macrophylla Leaves in Urban Environment

Urban areas are characterized by numerous pollutants emitted by anthropic sources both in the form of solid and gaseous particulates. Biomonitoring is an easy, economical, and accessible approach for the determination of atmospheric pollutants. In this study, we used the leaves of Ficusmacrophylla Desf. ex Pers., collected in the city of Palermo (Italy), to determine major and trace elements. Geogenic elements exhibited the highest concentrations, making up 99% of the weight of the analyzed elements (Ca, K, Mg, P, S, Na, Fe, and Al); they range 21,400 (Ca) to 122 µg g-1 (Al). The remaining elements showed median concentrations in the range 47.5-0.05 µg g-1 in the following order of abundance: Sr > Cu > Mn > Zn > Br > Rb > Ba > Pb > Cr > Sb > As > Mo = Sc. Cluster analysis, with Spearman's coefficient to measure sample similarity, identified five main groups, namely, three clusters related to the geogenic background and marine spray; one cluster linked to elements essential to plants, and a final group attributed to the influence of traffic emissions. Calculated enrichment factors (EF) showed that the enrichments found for P and K were linked to plant metabolism; Na and Mg confirmed the role of sea spray; Cu and Zn underlined the contribution linked to anthropic processes and the role of micronutrients in plants.. As, Cr, and Mo had EF values ranging from 10 and 20, and Sb had EF > 90. From geochemical distribution maps of As, Cr, Mo, and Sb it was observed that metal and metalloid concentrations were higher in urban areas and immediately decreased as one moved away from these areas. Local pollution sources play a great role in trace element concentrations in airborne particulate matter. The present study confirms that Ficusmacrophylla leaves are suitable for screening an urban environment to identify concentrations of inorganic chemicals, since they have high tolerance to pollution

A NEW “FERROVUM” SPECIES IN A SCHWERTMANNITE-PRODUCING PLANT FOR MINE WATER TREATMENT

Mining activities for metals or coal often result in the development of acid mine drainage due to the oxidation of sulfidic minerals which get exposed to oxygen. The acidic mine waters are characterized by low pH, high concentrations of sulfate and ferrous iron, and possibly dissolved heavy metals or metalloids. Conventional treatment comprises neutralization and oxidation yielding a sludge of iron oxides/hydroxides