DEVELOPMENT OF TINB2O7 ANODE FOR LITHIUM ION BATTERY ANODES

I have received 1200 dollars research scholarship.With an increase in gasoline price and greenhouse gas emissions, hybrid electrical vehicles (HEV) and pure electric vehicles (EV) have been commercialized in auto market. Li-ion batteries have become the dominant power source for the EV applications because of many advantages such as high energy densities, less pollution, stable performance and long cycle life. However, the market for HEVs and EVs need to overcome many technical issues. For example, energy densities and cycle life of Li-ion batteries need to be improved at low temperature for electrical vehicle applications. TiNb2O7 (TNO) electrode-based battery can be a good choice in order to improve the energy densities and cycle life. The original anode-based batteries are Li4Ti5O12 (LTO) anode-based batteries. I have made a comparison between TNO anode and LTO anode for Li-ion batteries. The energy densities of TNO anode-based batteries are around 350Wh/L and the energy densities of LTO anode-based batteries are around 177Wh/L. It means that TNO anode-based batteries have a higher energy density than LTO anode-based batteries. In addition, TNO anode batteries have a longer cycle life and shorter charging time than LTO anode batteries. The purpose of this research is to identify whether the TNO anodes-based batteries have the advantage of high energy and power densities for Li-ion batteries application. First, I need to identify whether the TNO anode can be run in normal cycling battery by doing half-cell test. I have done the half-cell test which consist of TNO anode and metallic Li as a counter electrode. The voltage profile obtained from half-cell test fits well with TNO electrode. In addition, cycle life tendency corresponding to high-density TNO composite electrode which indicate the TNO electrode can be used in normal cycling battery. In the future research study, I will identify the important parameters that lead to poor performance in the low-temperature condition and demonstrate the performance of TiNb2O7 anodes-based batteries has been improved in the low temperature condition.College of Engineering Research OfficeNo embargoAcademic Major: Mechanical Engineerin

Flexible and stretchable power sources for wearable electronics.

Flexible and stretchable power sources represent a key technology for the realization of wearable electronics. Developing flexible and stretchable batteries with mechanical endurance that is on par with commercial standards and offer compliance while retaining safety remains a significant challenge. We present a unique approach that demonstrates mechanically robust, intrinsically safe silver-zinc batteries. This approach uses current collectors with enhanced mechanical design, such as helical springs and serpentines, as a structural support and backbone for all battery components. We show wire-shaped batteries based on helical band springs that are resilient to fatigue and retain electrochemical performance over 17,000 flexure cycles at a 0.5-cm bending radius. Serpentine-shaped batteries can be stretched with tunable degree and directionality while maintaining their specific capacity. Finally, the batteries are integrated, as a wearable device, with a photovoltaic module that enables recharging of the batteries

Design of master and slave modules on battery management system for electric vehicles

Nowadays, electric vehicle usage and the use of LiFePO4 batteries in electric vehicles gradually increase. However, there are important features to be considered to use these batteries safely and efficiently. Incorrect use of these batteries can lead to burning, explosion or shortening of the life of batteries. In this paper, a Battery Management System (BMS) for lithium based batteries is designed that operates more efficiently and communicates with UART between master and slave modules and can communicate via CAN protocol with external devices. Micro controller based control and protection equipment is designed that help to measure and monitor the voltage, temperature and current values of the batteries. They protect the battery cells from the conditions such as over charge, over discharge, high current, high temperature. BMS balances battery cell voltages during charging process with passive cell voltage balancing. In addition to the main controller module in the BMS, slave controller modules have been added to provide high resolution voltage and temperature tracking. A modular BMS has been devised which can be used in groups of batteries of different voltage values thanks to electrically isolated slave control modules

Fully Conjugated Phthalocyanine Copper Metal-Organic Frameworks for Sodium-Iodine Batteries with Long-Time-Cycling Durability

Rechargeable sodium-iodine (Na-I-2) batteries are attracting growing attention for grid-scale energy storage due to their abundant resources, low cost, environmental friendliness, high theoretical capacity (211 mAh g(-1)), and excellent electrochemical reversibility. Nevertheless, the practical application of Na-I-2 batteries is severely hindered by their poor cycle stability owing to the serious dissolution of polyiodide in the electrolyte during charge/discharge processes. Herein, the atomic modulation of metal-bis(dihydroxy) species in a fully conjugated phthalocyanine copper metal-organic framework (MOF) for suppression of polyiodide dissolution toward long-time cycling Na-I-2 batteries is demonstrated. The Fe-2[(2,3,9,10,16,17,23,24-octahydroxy phthalocyaninato)Cu] MOF composited with I-2 (Fe-2-O-8-PcCu/I-2) serves as a cathode for a Na-I-2 battery exhibiting a stable specific capacity of 150 mAh g(-1) after 3200 cycles and outperforming the state-of-the-art cathodes for Na-I-2 batteries. Operando spectroelectrochemical and electrochemical kinetics analyses together with density functional theory calculations reveal that the square planar iron-bis(dihydroxy) (Fe-O-4) species in Fe-2-O-8-PcCu are responsible for the binding of polyiodide to restrain its dissolution into electrolyte. Besides the monovalent Na-I-2 batteries in organic electrolytes, the Fe-2-O-8-PcCu/I-2 cathode also operates stably in other metal-I-2 batteries like aqueous multivalent Zn-I-2 batteries. Thus, this work offers a new strategy for designing stable cathode materials toward high-performance metal-iodine batteries

Ni-cd Battery Life Expectancy in Geosynchronous Orbit

The feasibility of using nickel cadmium batteries as an alternate if flight qualified NiH2 batteries are not available is explored. Battery life expectancy data being a key element of power system design, an attempt is made to review the literature, life test data and in orbit performance data to develop an up to date estimate of life expectancy for NiCd batteries in a geosynchronous orbit

Electric vehicle battery research and development

High energy battery technology for electric vehicles is reviewed. The state-of-the-art in conventional batteries, metal-gas batteries, alkali-metal high temperature batteries, and organic electrolyte batteries is reported

Results from the testing and analysis of LDEF batteries

Batteries were used on the Long Duration Exposure Facility (LDEF) to provide power to both the active experiments and the experiment support equipment such as the Experiment Initiative System, Experiment Power and Data System (data acquisition system), and the Environment Exposure Control Canisters. Three different types of batteries were used: lithium sulfur dioxide (LiSO2), lithium carbon monofluoride (LiCF), and nickel cadmium (NiCd). A total of 92 LiSO2, 10 LiCF, and 1 NiCd batteries were flown on the LDEF. In addition, approximately 20 LiSO2 batteries were kept in cold storage at NASA LaRC. The various investigations and post-flight analyses of the flight and control batteries are reviewed. The primary objectives of these studies was to identify degradation modes (if any) of the batteries and to provide information useful to future spacecraft missions. Systems SIG involvement in the post-flight evaluation of LDEF batteries was two-fold: (1) to fund SAFT (original manufacturer of the LiSO2 batteries) to perform characterization of 13 LiSO2 batteries (10 flight and 3 control batteries); and (2) to integrate investigator results

Experimental tests to recover the photovoltaic power by battery system

The uncertainty and variability of the Renewable Energy Sources (RES) power plants within the power grid is an open issue. The present study focuses on the use of batteries to overcome the limitations associated with the photovoltaic inverter operation, trying to maximize the global energy produced. A set of switches, was placed between a few photovoltaic modules and a commercial inverter, capable to change configuration of the plant dynamically. Such system stores the power that the inverter is not able to let into the grid inside batteries. At the base of this optimization, there is the achievement of two main configurations in which the batteries and the photovoltaic modules are electrically connected in an appropriate manner as a function of inverter efficiency and thus solar radiation. A control board and the relative program, to change the configuration, was designed and implemented, based on the value of the measured radiation, current, batteries voltage, and calculated inverter efficiency. Finally from the cost and impact analysis we can say that, today the technology of lithium batteries, for this application, is still too expensive in comparison with lead-acid batteries

Analysis Of The Cyclability Of Lithium-polymer Batteries

Comunicación y póster en congresoLithium ion batteries and similar energy storage devices have an increasing importance for the modern society as they are present in many portable electronic devices and have perspectives in the fields of electric vehicles and renewable energy accumulation. Herein, we present results from charge and discharge cycles on batteries under controlled conditions. The cyclability of commercial lithium-polymer pouch batteries under different charge/discharge rates and temperatures was studied. Based on the results, the relationship between the state of charge and the cell voltage was obtained, as well as degradation of the cells, i.e., the decrease of the energy capacity after a number of cycles. The experimental results were compared with simulations based on Newman's model for Lithium Ion Batteries, carried out using the COMSOL Multiphysics® software. The batteries and fuel cell and the heat transfer modules were use to couple between the temperature and the electrochemical interactions. The results show the correlation between temperature, C-rate and degradation in lithium ion batteries. It is specially remarkable the decrease of the apparent capacity of batteries at low temperatures, and the increase of the degradation at higher temperatures. These results are essential for the design of mechanisms that could prevent battery failure.The authors acknowledge the financial support from the European Union's Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement No. 778045, and the "Plan Propio de Investigación y Transferencia de la Universidad de Málaga", code: PPIT.UMA.B5.2018/17